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中国物理学会期刊

三维超声场调控(FeCoNiCrMn)92Mo8高熵合金组织演变与力学性能

CSTR: 32037.14.aps.74.20250657

Three-dimensional ultrasounds modulated solidification microstructure and mechanical property of (FeCoNiCrMn)92Mo8 high-entropy alloy

CSTR: 32037.14.aps.74.20250657
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  • 本文在三维超声场中实现了(FeCoNiCrMn)92Mo8高熵合金的动态凝固过程, 并对其组织演变规律和力学性能提升机制进行研究. 静态凝固组织由FCC结构的初生γ相枝晶与四方结构的条状σ相组成. 随着超声振幅的增大, 瞬态空化大幅提升了初生γ相的形核率, 使其晶粒发生显著细化. 声流效应加速了固/液界面前沿溶质原子扩散, 导致初生γ相中Cr和Mo元素含量降低, 由此引发液相成分改变和(γ + σ)共晶组织形成. 液相中Cr元素的进一步富集使凝固组织中出现了亚稳μ相. 超声凝固条件下, 合金压缩屈服强度最高可达876.2 MPa, 比静态下提高了近2倍, 同时保持了33.2%的变形量, (γ + σ)共晶组织形成及其体积分数增大是合金屈服强度提升的主导因素.

     

    Three-dimensional ultrasonic waves with amplitudes of 14, 18, and 22 μm, respectively, are used during the solidification of (FeCoNiCrMn)92Mo8 high-entropy alloy, and its microstructural evolution and mechanical property are investigated in this work. Under static condition, the solidification microstructure is composed of primary γ phase dendrites with FCC structure and stripe-shaped σ phase with tetragonal structure. As the ultrasonic amplitude increases, the mean transient cavitation intensity rises to trigger off a significant nucleation rate increase of the primary γ phase to 5.6 × 1012 m–3·s–1, leading to the remarkable grain size reduction by two orders of magnitude. The maximum and the average acoustic streaming velocity increase simultaneously, which accelerates atomic diffusion at the liquid/solid interface, reducing Cr content in the primary γ phase from 18.6% to 13.1% and Mo content from 6.8% to 3.4% (atomic percent). This atomic redistribution subsequently causes the liquid composition to approach the eutectic point and facilitate the formation of (γ + σ) eutectic, which accounts for more than 50% volume fraction. The two eutectic phases exhibit a semi-coherent interface relationship characterized by 110γ//110σ and (1\bar1\bar 1) γ//(\overline110) σ. Furthermore, due to the gradual enrichment of Cr atoms in the remaining liquid phase, a small quantity of metastable μ phases with Cr content up to 62.3% form in the final microstructure. The maximum compressive yield strength of the ultrasonically solidified microstructure reaches 876.2 MPa, almost twice that of static solidification microstructure, and the compressive strain reaches 33.2%. The formation of (γ + σ) eutectic is the main factor that increases the yield strength of alloy by 527.1 MPa.

     

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