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中国物理学会期刊

熔体快淬法制备CeCo5纳米磁体的晶体织构及磁各向异性

Crystallographic Texture and Magnetic Anisotropy of CeCo5 Nanomagnets with Functional Gradient Prepared via a Simple Melt-Spinning Route

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  • CeCo5 结构化合物是一类重要的稀土永磁材料,在减少关键稀土元素用量并提升其磁性能具有重要的应用价值。为实现低稀土依赖型高性能永磁体的可控制备,本工作通过高速熔体快淬工艺直接合成出具有显著晶体织构与本征功能梯度的单相 CeCo5 纳米磁体。利用多种表征手段系统研究了材料的晶体结构、微观形貌、织构特征与磁性能演化规律。X 射线衍射结果表明,样品贴辊面存在平行于薄带平面的c轴择优取向,而自由面则呈现近各向同性的晶粒取向分布,这种非对称织构直接诱发了显著的磁各向异性。在辊轮线速度为 40m/s 条件下制备的薄带,其面内剩磁比明显高于面外数值。洛伦兹透射电镜观测证实样品具有纳米尺度的晶粒尺寸与清晰的磁畴结构,中子衍射精修结果确定其具有 CaCu5 型晶体结构。研究表明,非对称冷却导致的定向凝固行为是形成贴辊面织构梯度的主要原因。所制备的功能梯度薄带磁体展现出优良的磁各向异性,在降低关键稀土元素依赖的新型永磁材料体系中具有良好的应用前景。

     

    CeCo5 is an attractive light-rare-earth 1:5 permanent-magnet compound because Ce is abundant and cost-effective, yet its practical development has been hindered by the difficulty of simultaneously controlling phase purity, crystallographic texture, microstructure, and magnetic anisotropy. In this work, single-phase CeCo5 nanomagnets with a self-organized functional gradient were prepared directly by a simple high-speed melt-spinning route. The precursor ingots were fabricated by arc melting high-purity Ce and Co, followed by melt spinning at wheel speeds of 40 and 50 m/s. Surface-resolved X-ray diffraction reveals that the wheel-side surface develops a pronounced c-axis texture with the magnetic easy axis preferentially aligned parallel to the ribbon plane, whereas the free side retains a nearly random grain orientation. This asymmetric crystallographic texture gives rise to clear macroscopic magnetic anisotropy. For the ribbon prepared at 40 m/s, the in-plane remanence ratio reaches Mr/Ms = 0.60, markedly higher than the out-of-plane value of 0.38; the corresponding values for the 50 m/s ribbon are 0.58 and 0.33, respectively. Neutron diffraction refinement at 293 K confirms the CaCu5-type hexagonal structure with space group P6/mmm, lattice parameters a = 4.952(1) Å and c = 3.979(1) Å, and a ferromagnetic structure with propagation vector k = (0, 0, 0). TEM-based grain-size statistics show that increasing the wheel speed refines the grains from approximately 400 nm at 40 m/s to approximately 300 nm at 50 m/s. Lorentz transmission electron microscopy further reveals the evolution of magnetic domains from weakly contrasted quasi-single-domain features to clear ripple-like and labyrinthine multidomain structures, indicating enhanced exchange coupling and domain-wall pinning in the finer-grained ribbons. The intrinsic functional gradient is attributed to directional solidification induced by rapid heat extraction at the wheel interface and slower cooling near the free surface. These results demonstrate that melt spinning can integrate phase formation, texture engineering, and functional-gradient design in CeCo5, providing a scalable route toward low-cost, rare-earth-lean permanent magnets with reduced dependence on critical rare-earth elements.

     

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