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中国物理学会期刊

I型范德华异质结增强的黑磷近红外激子发光

Type-I van der Waals Heterostructure Enhanced Near-Infrared Exciton Emission in black phosphorus

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  • 二维半导体激子发光及其范德华异质结调控是低维光电物理领域研究前沿。目前研究主要集中在过渡金属硫族化合物可见光波段的发光现象,亟需开发新材料平台以拓展发光波段。三层黑磷(3L BP)具有激子主导的近红外通信波段发光特性,为硅基片上光源的构筑提供了契机,然而其本征发光强度受限,实际应用受到制约。本研究设计并制备了具有Ⅰ型能带排列的3L BP/双层硒化钨(2L WSe2)范德华异质结。与单独的3L BP相比,异质结通过界面电荷转移,在室温下实现了约1450 nm处近红外发光的显著增强。变温光谱研究表明,异质结的发光强度呈现反常的温度依赖性,即随温度升高而增强,这与BP本征的发光趋势相反。此外,通过栅压调控载流子状态,进一步优化了器件的发光效率。本工作揭示了BP/WSe2异质结中近红外激子发光的增强机理,为开发面向室温工作的范德华集成近红外光源提供了新思路。

     

    The design of van der Waals heterojunctions for modulating excitonic photoluminescence (PL) in two-dimensional (2D) semiconductors has become a major research focus in low-dimensional photonics. While previous studies have predominantly explored charge- and energy-transfer processes in transition metal dichalcogenides with emission wavelengths mostly in the visible range, there remains an urgent need to develop new heterojunction material platforms that extend emission into the near-infrared (NIR) telecommunication band for silicon-based on-chip light sources. Trilayer black phosphorus (3L BP) exhibits exciton-dominated NIR emission within the telecommunication window; however, the intrinsic emission intensity of BP at room temperature is limited, which constrains its practical applications. Type-I band-aligned heterojunctions, which confine carriers within the narrow-bandgap emitting layer, provide an effective strategy to enhance radiative recombination and consequently light emission in narrow-bandgap 2D semiconductors. In this work, we fabricated a type-I van der Waals heterostructure composed of direct-bandgap 3L BP and indirect-bandgap bilayer tungsten diselenide (2L WSe2). Compared with the isolated 3L BP and 2L WSe2 regions, the heterostructure exhibits significantly enhanced NIR emission and suppressed visible emission at room temperature. Notably, unlike isolated BP, the heterostructure exhibits anomalous temperature-dependent PL behavior, with the emission intensity increasing as the temperature rises. This phenomenon indicates that enhanced lattice vibrations at higher temperatures promote thermal activation and carrier transfer from WSe2 to BP, while simultaneously reducing the carrier capture efficiency of nonradiative recombination centers. Furthermore, the gate-voltage-dependent PL of the 3L BP/2L WSe2 heterostructure differs from that of isolated 3L BP. Under positive gate bias, the charge imbalance in p-type 2L WSe2 is alleviated, boosting carrier injection from WSe2 to BP and enabling tunability and enhanced radiative recombination. These findings demonstrate enhanced NIR excitonic emission in the type-I BP/WSe2 heterostructure and provide a promising strategy for designing tunable, efficient room-temperature light-emitting devices operating in the NIR telecommunication band.

     

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