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中国物理学会期刊

基于结构优化的固体氧化物燃料电池裂纹扩展分析

Analysis of crack propagation in solid oxide fuel cell based on structural optimization

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  • 为提高固体氧化物燃料电池(SOFC)的结构可靠性,本研究建立了包含阳极功能层的平板型与波纹型SOFC有限元模型,同时将波纹振幅参数化,对比研究不同模型冷却后的电池力学性能和界面失效行为,并结合虚拟裂纹闭合法评估电解质-阳极界面预裂纹的扩展与能量释放率。结果表明,引入波纹界面可显著降低界面最大主应力并抑制裂纹扩展,但同时会在几何起伏区域引入局部应力集中。阳极功能层对波纹型峰值应力的降低作用弱于平板型,但可大幅缓解波峰、波谷处的局部应力集中。参数化分析显示,波纹型SOFC随波纹振幅增大,界面最大主应力逐渐降低,裂纹扩展长度逐渐减小,但其增强了波峰与波谷局部区域的应力集中。本研究为SOFC的结构优化设计提供了一定的理论依据。

     

    During thermal cycling, mismatches in the coefficients of thermal expansion and mechanical properties among the constituent layers of solid oxide fuel cell (SOFC) generate interfacial thermal stresses, which may induce crack propagation and delamination, thereby compromising long-term durability and hindering their large-scale commercialization. Corrugated interfaces and an anode functional layer (AFL) are potential structural strategies for improving thermal stress distribution. Therefore, to enhance the structural reliability of SOFC, finite element models of planar and corrugated SOFC with and without an AFL are developed. The thermomechanical responses of the four configurations during the cooling process from 1400 ℃ to 25 ℃ are comparatively investigated. Besides, a pre-crack with an initial length of 0.2 mm is introduced at the electrolyte-anode interface to analyze the propagation behavior using the virtual crack closure technique and the energy release rate (ERR). In addition, a parametric analysis is performed by varying the amplitude of the interface from 0 to 0.1875 mm based on a fixed wavelength.
    The results show that the corrugated interface effectively redistributes thermal mismatch stresses and reduces the maximum principal stress at the interface. Compared with the planar configuration, the maximum principal stress along the electrolyte lower surface reduces by 22.65% for the typical corrugated structure. The AFL reduces the peak stress more effectively in the planar configuration, whereas in the corrugated configuration, it mainly alleviates local stress concentrations in the crest and trough regions. Crack propagation analysis further indicates that the corrugated interface markedly suppresses interfacial crack propagation. As the corrugation amplitude increases from 0 to 0.1875 mm, the maximum interfacial stress decreases by up to 36.90%, while the crack propagation length decreases from 3.29 to 0.23 mm. However, increasing the corrugation amplitude also intensifies stress concentrations in the crest and trough regions.
    Moreover, the ERR curves of the corrugated SOFC exhibit a characteristic local decrease during the early stage of crack propagation, and this reduction becomes more pronounced with increasing amplitude. This characteristic ERR drop reveals the local weakening effect of the corrugated geometry on the crack-driving force. These results demonstrate that the coordinated design of interfacial morphology and AFL can effectively regulate thermal stress transfer and crack propagation, providing a theoretical basis for the structural optimization and reliability-oriented design of SOFC.

     

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