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中国物理学会期刊

稀土三角晶格自旋系统中的量子自旋液体基态

Quantum Spin Liquid Ground States in Rare-Earth Triangular-Lattice Spin Systems

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  • 量子自旋液体是阻挫磁体中一种在零温极限下仍不发生常规磁有序的量子多体态,其主要特征包括长程量子纠缠、分数化激发和涌现规范结构。三角晶格是研究量子自旋液体的经典平台,但长期理论与实验研究表明,最简单的自旋1/2最近邻Heisenberg三角晶格模型的基态并非自旋液体,而是120° Néel有序态。因此,真实材料中三角晶格量子自旋液体的实现通常依赖次近邻交换、XXZ各向异性以及强自旋—轨道耦合诱导的各向异性交换等机制。本文综述稀土三角晶格量子自旋液体的理论基础、候选材料与实验进展。在众多稀土Kramers离子中,Yb3+基化合物因其有效赝自旋1/2描述的简洁性以及高质量单晶样品的可获得性,成为目前实验进展最为充分的体系,也是本文的讨论重点。围绕Yb基三角晶格材料,本文重点讨论YbMgGaO4体系中的无序争议,以及NaYbCh2Ch=O,S,Se)家族在结构完整性和低能激发性质方面展现出的优势,并结合KYbO2、KYbSe2和CsYbSe2等有序同系物对有效哈密顿量的定量约束进行比较。现有研究表明,NaYbCh2家族是当前最具前景的稀土三角晶格量子自旋液体候选平台之一。

     

    Quantum spin liquids (QSLs) are exotic quantum many-body states in frustrated magnets that evade conventional magnetic order down to absolute zero temperature, featuring long-range quantum entanglement, fractionalized excitations, and emergent gauge structures. The triangular lattice serves as a canonical platform for studying QSLs; however, the simplest spin-1/2 nearest-neighbor Heisenberg triangularlattice antiferromagnet possesses a 120◦ Néel ordered ground state rather than a spin liquid. Realizing QSLs in real triangular-lattice materials therefore relies on additional mechanisms such as next-nearestneighbor exchange, XXZ exchange anisotropy, and bond-dependent anisotropic interactions induced by strong spin-orbit coupling. This article reviews the theoretical foundations, candidate materials, and recent experimental progress on rare-earth triangular-lattice QSLs, with a focus on Yb3+-based compounds whose effective pseudospin-1/2 description and high-quality single-crystal availability make them the most extensively studied systems to date. We first examine YbMgGaO4, where inelastic neutron scattering revealed broad continuum excitations suggestive of fractionalization, but Mg2+/Ga3+ site disorder and spin-glass-like behavior in the sister compound YbZnGaO4 have cast doubt on its intrinsic QSL candidacy. We then turn to the NaYbCh2 (Ch = O, S, Se) family, which eliminates such mixed-valence disorder at the structural level. Thermodynamic and local-probe measurements consistently show the absence of long-range order and spin freezing; single-crystal inelastic neutron scattering on NaYbSe2 has identified spinon-type continuum excitations in a structurally clean setting. The chemical substitution O → S → Se provides a clean tuning pathway across different exchange regimes. Comparisons with magnetically ordered analogues KYbO2, KYbSe2, and CsYbSe2 through spin-wave fitting supply quantitative constraints on the effective Hamiltonians. Current evidence indicates that the NaYbCh2 family represents one of the most promising rare-earth triangular-lattice QSL candidate platforms to date.

     

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