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中国物理学会期刊

高熵氧化物磁性的研究进展

Research Progress in the Magnetic Properties of High-Entropy Oxides

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  • 高熵氧化物作为多主元材料体系的重要分支,凭借其极大的构型熵为晶体结构稳定化与磁性功能定制提供了广阔的自由度。自2015年首次报道以来,高熵氧化物内部极度的化学无序与复杂的金属—氧—金属复杂的多组元磁交换相互作用,诱导出长程反铁磁序、亚铁磁性及低温自旋玻璃态等丰富的磁有序行为,展现出迥异于传统单一氧化物的磁学特征。本文系统综述了岩盐、萤石、尖晶石、钙钛矿及系列衍生结构高熵氧化物在磁性研究领域的最新进展,深入探讨了组分多样性、局部点阵畸变及元素占位对磁转变温度、饱和磁化强度及各向异性等核心物理指标的调控规律。同时,重点分析了应变场、磁离子学及电化学手段在磁性能动态改性中的关键作用。最后,本文对高熵体系中局域短程有序的精确表征、量子自旋液体态的探索以及高性能磁致冷应用等前沿挑战进行了展望,旨在为新型磁性高熵功能材料的设计提供理论支撑。

     

    High entropy oxides (HEOs) have emerged as a unique platform in magnetism research, where maximized configurational entropy stabilizes single phase solid solutions despite extreme chemical disorder. This review systematically summarizes recent advances in the magnetic properties of HEOs across various crystal structures, including rocksalt, fluorite, spinel, perovskite, and several derivative structures. We first discuss the fundamental magnetic interactions in HEOs, emphasizing the competition among superexchange, double exchange, and antisymmetric exchange, all of which are strongly modulated by local lattice distortions and cation randomness. Then, we present a structure dependent analysis of magnetic behaviors. Rocksalt HEOs exhibit robust long-range antiferromagnetic order. Spinel HEOs show high temperature ferrimagnetism with strong tunability. Perovskite HEOs display complex spin glass behavior, exchange bias effects, and rare earth transition metal coupling. Fluorite HEOs host geometrically frustrated magnetism and short-range magnetic correlations. Key modulation strategies are evaluated, including composition engineering, epitaxial strain, magnetoionics, and electrochemical ion insertion. These approaches enable continuous control of magnetic transition temperature, saturation magnetization, and anisotropy. A central finding is that long range magnetic order can robustly coexist with local chemical randomness in HEOs, leading to unconventional states such as spin canting, non collinear spin textures, and reentrant spin glass behavior. The core innovation lies in decoupling key magnetic parameters from the constraints of conventional binary oxides, allowing property by design in a single-phase lattice. Future challenges include atomic scale characterization of short-range order, exploration of quantum spin liquid states in frustrated HEO lattices, and development of high performance magnetocaloric materials. This review provides valuable insights for entropy driven magnetic functional materials.

     

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