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中国物理学会期刊

重费米子超导体CeCoIn5与CeCu2Si2的非弹性中子散射研究

Inelastic neutron scattering studies of the heavy fermion superconductors CeCoIn5 and CeCu2Si2

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  • 重费米子超导体是探索非常规超导机制的重要平台,其超导配对通常被认为源于磁涨落。非弹性中子散射可以在动量-能量空间对磁涨落进行探测,因此在重费米子超导体磁激发的测量及对超导机理的理解中具有不可替代的作用。本文综述了两个典型Ce基重费米子超导体——CeCoIn5 (Tc ≈ 2.3 K)与CeCu2Si2 (Tc ≈ 0.6 K)的中子散射研究。CeCoIn5的磁激发在超导态中表现出显著的自旋共振模,该模式的色散表明其难以用弱耦合图像下的自旋激子(spin exciton)描述,而更类似于CeRhIn5中自旋波的顺磁态激发。该模式的Ising各向异性、磁场下的二重劈裂以及低能偏离奈尔波矢等特征,表明其与CeCoIn5磁场下出现的Q相密切相关。CeCu2Si2天然邻近磁性量子临界点,其正常态磁激发表现出传统磁性量子临界点的E/T3/2标度行为,而超导态的自旋共振模则为其非常规超导配对提供了重要证据。相较于具有显著色散的低能激发,CeCu2Si2中高能磁激发的动量依赖不随能量显著变化,表明其可能源自重费米子态与传导电子态间的散射。CeCoIn5和CeCu2Si2中的中子散射研究揭示了其中丰富且易于调控的基态与磁激发,为理解非常规超导机理提供了重要借鉴。

     

    Heavy fermion superconductors offer an ideal setting for exploring mechanisms of unconventional superconductivity, as their superconducting pairing is generally believed to originate from magnetic fluctuations. Inelastic neutron scattering (INS) enables the detection of magnetic fluctuations in momentum-energy space, thus playing an irreplaceable role in measuring magnetic excitations in heavy fermion superconductors and in understanding their superconducting mechanisms. This article reviews neutron scattering studies on two archetypal Ce-based heavy fermion superconductors—CeCoIn5 (Tc ≈ 2.3 K) and CeCu2Si2 (Tc ≈ 0.6 K). Both compounds have been investigated with high-resolution triple-axis and time-of-flight spectrometers, using polarized neutrons and applied magnetic fields, which together resolve how their magnetic excitations evolve with temperature, momentum, energy, magnetic field and chemical substitution. In CeCoIn5, magnetic excitations exhibit a prominent spin resonance mode at Er ≈ 0.6 meV (≈ 3kBTc) in the superconducting state, the upward dispersion of which defies a spin-exciton description in the weak-coupling limit and instead closely resembles that of the spin waves in the antiferromagnetically ordered CeRhIn5. The spin resonance mode in CeCoIn5 exhibits an Ising anisotropy, a double splitting under applied magnetic field, and a deviation from the Néel wave vector at low energies, suggesting that this mode is closely related to the field-induced Q-phase. Chemical substitution reveals that Er and Tc decrease in tandem upon La or Yb substitution while Er/kBTc stays nearly constant, whereas hole doping with Hg, Cd or Zn induces commensurate antiferromagnetic order and removes the spin resonance mode. CeCu2Si2 is naturally proximate to a magnetic quantum critical point, and its normal-state magnetic excitations exhibit the E/T3/2 scaling expected for an itinerant three-dimensional spin-density-wave quantum critical point. A spin resonance mode at Er ≈ 0.2 meV (≈ 4kBTc) develops in the superconducting state, providing crucial evidence for unconventional superconducting pairing. In contrast to the low-energy excitations that show significant dispersion, the momentum dependence of the high-energy magnetic excitations in CeCu2Si2 does not vary significantly with energy, suggesting that they may originate from scattering between the heavy fermion states and conduction-electron states. The reviewed neutron scattering studies on CeCoIn5 and CeCu2Si2 reveal that these systems host versatile ground states and readily tunable magnetic excitations, providing key insights into the mechanisms of unconventional superconductivity.

     

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