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中国物理学会期刊

Cr掺杂致Ge2Sb2Te5平缓相变现象及其应用研究

Study on Cr-doping induced gentle phase transition effect in Ge2Sb2Te5 and its potential applications

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  • 在诸多相变材料中,锗锑碲硫系玻璃(Ge2Sb2Te5, GST),因其较大的折射率对比度和非易失的相变效应,是动态显示领域尤为理想的调控材料。对GST进行元素掺杂,因其提高了结晶温度,是提高其热稳定性的常用方法。然而,在掺杂的GST中存在一种平缓相变(Gentle phase transition, GPT)效应,此前尚未得到充分关注和探索。GPT效应将随退火温度升高而“突变”的相变改写为“平缓”过程,可能成为该领域未来有潜力的研究课题。因此,本文对Cr掺杂GST中的GPT效应开展了系统的研究,探索了其在高精度结构色控制和非接触温度检测中的潜在应用。首先,Cr掺杂GST薄膜的R-T响应表明,Cr掺杂浓度的提高可以增强GPT效应。然后,通过研究Cr9.5(GST)90.5(CrGST)薄膜光学参数的相变变化,验证了光学参数GPT效应的存在。最后,制备了基于CrGST的结构色器件,实现了结构色的高精度相变调控。此外,设计了温度检测装置,初步实现了温度信号-电信号的线性转化的原理验证。该工作将为高精度结构色调控和非接触温度检测领域开辟一条新路径。

     

    Phase change materials (PCMs) provide a compelling platform for active nanophotonics. Among them, the PCMs, the chalcogenide glass Ge2Sb2Te5 (GST) is particularly attractive for dynamic display applications, owing to its large refractive-index contrast and non-volatile phase-change behavior. In addition to this, elemental doping of GST is commonly employed to increase its thermal stability due to the increase in crystallization temperature. However, there exists a gentle phase transition (GPT) effect in doped GST that has not received adequate attention. The GPT effect transforms the abrupt phase transition (typically occurs as the annealing temperature increases) into a gradual process, which remains unexplored and could be the subject of further research in this field. Therefore in this work, we conduct a systematical study of optical GPT effect in Cr-doped GST and its related devices, exploring potential applications in high-precision structural-color control and non-contact temperature recording. The resistance-temperature (R-T) responses of Cr-doped GST reveal that the GPT effect can be promoted by higher Cr-doping concentration. The optical GPT effect of Cr-doped GST is validated by temperature dependent (n, k) of Cr9.5(GST)90.5 (CrGST) film. Based on the optical GPT effect, we fabricated the CrGST-based Fabry-Perot color manipulation device that exhibits a gentle color change around the phase transition temperature range. The color gamut and temperature sensitivity can be controlled by adjusting the geometric parameters of the device, and the colour saturation can be adjusted by changing the annealing temperature of the device. The CrGST device also possesses the potential of temperature recording. Based on the CrGST device, we designed a temperature-voltage conversion system to validate the principle of temperature recording. By adjusting the incident angle and laser wavelength, a large and linear V-T response can be acquired. We believe our work opens a new route in the area of high precision color control and non-contact temperature recording.

     

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