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中国物理学会期刊

87Sr原子5s2 1S0和5s5p 3P0态极化性质的研究

Theoretical study on the polarizabilities of 5s2 1S0 and 5s5p 3P0 states of 87Sr atom

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  • 本文利用相对论组态相互作用结合多体微扰理论方法(RCI+MBPT),对 87Sr 原子的能级和电偶极跃迁矩阵元、 5s2 1S0、 5s5p 3P0 态的极化率、幻零波长及 5s2 1S0→5s5p 3P0 钟跃迁魔幻波长进行了计算,得到的结果与实验测量值及其他理论计算结果符合的很好。并进一步计算了 87Sr 原子的超精细结构常数和超精细相互作用能,详细研究了超精细相互作用对5s2 1S0 和 5s5p 3P0 态的极化率、幻零波长以及 5s2 1S0→5s5p 3P0 钟跃迁魔幻波长的影响,与不考虑超精细相互作用的结果进行了对比,发现超精细相互作用对 5s2 1S0和 5s5p 3P0 态的极化率的影响在 10−4a.u.量级,对 5s21S0→5s5p 3P0 钟跃迁魔幻波长的影响在 0.001 nm 量级,这些理论计算结果为进一步发展高精度的 87Sr 原子光钟提供参考。

     

    We employed the relativistic configuration interaction plus second-order many-body perturbation theory (RCI+MBPT) method to calculate the energy levels, wave functions, and electric-dipole transition matrix elements for the 87Sr atom. Within the sum-over-states framework, we systematically evaluated both static and dynamic electric-dipole polarizabilities for the ground-state 5s2 1S0 and the metastable clock state 5s5p 3P0 under the fine level approximation. We compare our calculated fine-structure energy levels, reduced matrix elements, static polarizabilities, magic-zero wavelengths, and magic wavelengths with available theoretical and experimental data, and good agreement is achieved.
    Subsequently, both magnetic dipole and electric quadrupole hyperfine interaction effects are incorporated. This allows us to obtain hyperfinesublevel-resolved polarizabilities, hyperfine-shifted magic-zero wavelengths for the two target states, and hyperfine-dependent magic wavelengths for the 5s2 1S0→5s5p 3P0 clock transition. Our calculations confirm that hyperfine coupling induces non-vanishing tensor polarizabilities for both states. The hyperfine corrections to static and dynamic polarizabilities are on the order of 10-4 a.u.. Due to hyperfine interactions, the magic-zero wavelengths of these two states change by about 10-3-10-4 nm. For the well-known 814-nm magic wavelength of the clock transition, the largest hyperfine-induced shift is about 10-3 nm.

     

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