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RhXⅢ,PdXⅣ和AgXV离子4s24p3—4s24p25s跃迁的扩展分析

牟致栋 魏琦瑛 陈涤缨

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RhXⅢ,PdXⅣ和AgXV离子4s24p3—4s24p25s跃迁的扩展分析

牟致栋, 魏琦瑛, 陈涤缨

Extensive analysis of 4s24p3—4s24p25s transition for RhXⅢ,PdXⅣ and AgXV

Mu Zhi-Dong, Wei Qi-Ying, Chen Di-Ying
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  • 用相对论Hartree-Fock方法对YⅦ—AgⅩⅤ离子4s24p3和4s24p25s组态的能级结构进行了系统的理论计算.通过分析能级结构的Slater径向积分参数沿等电子序列的变化规律,运用参数拟合外推(或内插)的方法计算了上述离子组态的能级结构参数.在此基础上,计算了Rh,Pd和AgⅩⅤ离子4s24p3(4S3/2,
    Extensive analysis of fine-structure energy levels of configurations 4s24p3(4S3/2,2P1/2,3/2, 2D1/2,3/2)and 4s24p25s(4P1/2,3/2,5/2,2P1/2,3/2, 2D3/2,5/2,2S1/2) are made for arsenic isoelectronic sequence of ions from YⅦ to AgⅩⅤ by Hartree-Fock method with relativistic corrections (HFR) using the Cowan code. The Slater parameters of fine-structure level are obtained by least-square-fit for ions mentioned above with the available experimental data, and the unknown parameters are calculated by the generalized-least-square-fit with the extra-(inter)polation method. With these new parameter values, the fine-structure energy levels of 4s24p3, 4s24p25s are computed. All of the 35 electronic-dipole transition wavelengths and its associated oscillator strengths between configurations 4s24p3 and 4s24p25s are calculated for Rh,Pd and AgⅩⅤ. The wavelength uncertainties with the available experimental values for Rh are mostly within 0.003nm. All results of Pd and AgⅩⅤ are predicted values currently anavailable in experiment.
    • 基金项目: 中国矿业大学科技基金(批准号:OK4522)资助的课题.
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  • 文章访问数:  7716
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  • 被引次数: 0
出版历程
  • 收稿日期:  2005-11-15
  • 修回日期:  2006-03-17
  • 刊出日期:  2006-04-05

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