掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁

陈晓波; 廖红波; 张春林; 于春雷; 潘伟; 胡丽丽; 吴正龙

doi:10.7498/aps.59.5091

摘要

研究了掺铒的纳米相氟氧化物玻璃陶瓷(Er(3):FOV)的红外量子剪裁现象,测量了红外和可见的Er(3):FOV的荧光光谱.结果发现光激发2H11/2能级的4 I13/2→4I15/2荧光跃迁的近似量子剪裁效率已达约186.28%.计算了有关的无辐射弛豫速率、自发辐射速率和能量传递速率,分析了有关的能量传递动力学过程,发现

关键词:

The article reports the infrared quantum cutting phenomenon of the Er-doped nanophase oxyfluoride vitroceramics (Er(3):FOV). The infrared and visible fluorescence spectra of Er(3):FOV are measured carefully. It is found that the approximate quantum cutting efficiency of the 1543.0 nm 4I13/2→4I15/2 fluorescence, when the 2H11/2 levels are excited, is about 186.28%. The relative nonradiative relaxation rate and spontaneous emission rate and energy transfer rate are calculated. The relative energy transfer dynamics is analyzed. It is found that the {2H11/2→4I9/2, 4I15/2→4I13/2} energy transfer channel, with the rate of 371000 s-1, is the main reason for 2H11/2 energy level to have high quantum cutting efficiency. To our best knowledge, the present article for the first time reports Er(3):FOV to have an effective three-photon infrared quantum cutting excited by visible light and a four-photon infrared quantum cutting excited by near-violet light.

Keywords:

infrared quantum cutting /
solar cell /
Er-doped nanophase oxyfluoride vitroceramics

作者及机构信息

(1)北京大学化学与分子工程学院,北京 100871; (2)北京师范大学应用光学北京市重点实验室,北京 100875; (3)中国科学院上海高功率激光玻璃研究中心,上海 201800; (4)中国科学院上海高功率激光玻璃研究中心,上海 201800; 中国科学院上海光学精密机械研究所,上海 201800; (5)中国科学院物理研究所,北京 100190

基金项目: 国家自然科学基金 (批准号:10674019)资助的课题.

Authors and contacts

(1)College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China; (2)Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China; (3)Key Laboratory of Applied Optics of Beijing, Beijing Normal University, Beijing 100875, China; (4)Shanghai Research Center of High Power Laser Glass, Chinese Academy of Sciences, Shanghai 201800, China; (5)Shanghai Research Center of High Power Laser Glass, Chinese Academy of Sciences, Shanghai 201800, China; Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China

参考文献

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[2]	Wegh R T, Donker H, Oskam K D, Meijerink A 1999 Science 283 663
[3]	Yang M D, Liu Y K, Wu C H, Shen J L, Lin C A, Chang W H, Wang H H, Yeh H I, Chan W H, Parak W J 2008 Opt. Express 16 15754
[4]	Presting H, Konle J, Kibbel H, Thonke K, Sauer R 2001 Proc. SPIE 4293 63
[5]	Bitnar B 2003 Semicond. Sci. Technol. 18 S221
[6]	Wegh R T, Donker H, Oskam K D, Meijerink A 1999 J. Lumin. 82 93
[7]	Chen D Q, Wang Y S, Yu Y L, Huang P, Weng F Y 2008 Opt. Lett. 33 1884
[8]	Ye S, Luo J, Chen J X, Zhu B, Lakshminarayana G, Qiu J R 2008 Opt. Express 16 8989
[9]	Richards B S 2006 Sol. Energy Mater. Sol. Cells 90 1189
[10]	Vergeer P, Vlugt T J H, Kox M H F, den Hertog M I, van der Eerden J P J M, Meijerink A 2005 Phys. Rev. B 71 014119
[11]	Lee T J, Luo L Y, Diau E W G, Chen T M, Cheng B M, Tung C Y 2006 Appl. Phys. Lett. 89 131121
[12]	Tzeng H Y, Cheng B M, Chen T M 2007 J. Lumin. 122-123 917
[13]	Carnall W T, Fieldd R, Rajnank K T 1968 J. Chem. Phys. 49 4424
[14]	Zhang Q Y, Yang C H, Pan Y X 2007 Appl. Phys. Lett. 90 021107
[15]	Vergeer P, van den P E, Meijerink A 2006 J. Lumin. 121 456
[16]	Reisfeld R 1977 Lasers and Excited States of Rare-Earth (New York: Springer-Verlag)
[17]	Chen X Y, Luo Z D 1998 Chin. Phys. 7 773
[18]	Chen X B, Song Z F 2001 Chin. Phys. 10 1163
[19]	Xiao S G, Yang X L, Ding J W 2009 Acta Phys. Sin. 58 3812 (in Chinese) [肖思国、阳效良、丁建文 2009 物理学报 58 3812]
[20]	Auzel F 2004 Chem. Rev. 104 139
[21]	Nie Y X, Chen Y, Li Y J 2002 Acta Phys.Sin. 51 578 (in Chinese)[聂玉昕、陈煜、李云静 2002 物理学报 51 578]
[22]	Wang N Y, Zhang L 2001 Acta Phys. Sin. 50 693(in Chinese)[王乃彦、张路 2001 物理学报 50 693]
[23]	Yang H G, Dai Z W, Zu N N 2007 Chin. Phys. 16 1650
[24]	Su F N, Deng Z D 2006 Chin. Phys. 15 1096
[25]	Biswas A, Maciel G S, Friend C S, Prasad P N 2003 J. Non-Cryst. Solids 316 393
[26]	Kushida T 1973 J. Phys. Soc. Jpn. 34 1318
[27]	Chen X B, Wang C, Salamo G J, Sawanobori N, Kang D G, Ohtsuka M, Yang G J, Peng F L 2009 Chin. Phys. B18 5523

施引文献

[1]	Yang G Z et al 1995 Optical Physics (Beijing: Science Press) (in Chinese) [杨国桢等 1995 光物理科学 (北京:科学出版社)]
[2]	Wegh R T, Donker H, Oskam K D, Meijerink A 1999 Science 283 663
[3]	Yang M D, Liu Y K, Wu C H, Shen J L, Lin C A, Chang W H, Wang H H, Yeh H I, Chan W H, Parak W J 2008 Opt. Express 16 15754
[4]	Presting H, Konle J, Kibbel H, Thonke K, Sauer R 2001 Proc. SPIE 4293 63
[5]	Bitnar B 2003 Semicond. Sci. Technol. 18 S221
[6]	Wegh R T, Donker H, Oskam K D, Meijerink A 1999 J. Lumin. 82 93
[7]	Chen D Q, Wang Y S, Yu Y L, Huang P, Weng F Y 2008 Opt. Lett. 33 1884
[8]	Ye S, Luo J, Chen J X, Zhu B, Lakshminarayana G, Qiu J R 2008 Opt. Express 16 8989
[9]	Richards B S 2006 Sol. Energy Mater. Sol. Cells 90 1189
[10]	Vergeer P, Vlugt T J H, Kox M H F, den Hertog M I, van der Eerden J P J M, Meijerink A 2005 Phys. Rev. B 71 014119
[11]	Lee T J, Luo L Y, Diau E W G, Chen T M, Cheng B M, Tung C Y 2006 Appl. Phys. Lett. 89 131121
[12]	Tzeng H Y, Cheng B M, Chen T M 2007 J. Lumin. 122-123 917
[13]	Carnall W T, Fieldd R, Rajnank K T 1968 J. Chem. Phys. 49 4424
[14]	Zhang Q Y, Yang C H, Pan Y X 2007 Appl. Phys. Lett. 90 021107
[15]	Vergeer P, van den P E, Meijerink A 2006 J. Lumin. 121 456
[16]	Reisfeld R 1977 Lasers and Excited States of Rare-Earth (New York: Springer-Verlag)
[17]	Chen X Y, Luo Z D 1998 Chin. Phys. 7 773
[18]	Chen X B, Song Z F 2001 Chin. Phys. 10 1163
[19]	Xiao S G, Yang X L, Ding J W 2009 Acta Phys. Sin. 58 3812 (in Chinese) [肖思国、阳效良、丁建文 2009 物理学报 58 3812]
[20]	Auzel F 2004 Chem. Rev. 104 139
[21]	Nie Y X, Chen Y, Li Y J 2002 Acta Phys.Sin. 51 578 (in Chinese)[聂玉昕、陈煜、李云静 2002 物理学报 51 578]
[22]	Wang N Y, Zhang L 2001 Acta Phys. Sin. 50 693(in Chinese)[王乃彦、张路 2001 物理学报 50 693]
[23]	Yang H G, Dai Z W, Zu N N 2007 Chin. Phys. 16 1650
[24]	Su F N, Deng Z D 2006 Chin. Phys. 15 1096
[25]	Biswas A, Maciel G S, Friend C S, Prasad P N 2003 J. Non-Cryst. Solids 316 393
[26]	Kushida T 1973 J. Phys. Soc. Jpn. 34 1318
[27]	Chen X B, Wang C, Salamo G J, Sawanobori N, Kang D G, Ohtsuka M, Yang G J, Peng F L 2009 Chin. Phys. B18 5523

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