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本文以最子力学计算一直线式不对称三原分子之振动能及振动与转动之相互作用。由所得之公式可从势能函数,计算转动谱线之收敛系数;反之由实验所得后者之值,亦一由所得公式计算前者。此文之理论应用于HCN分子之结果极为良好。The problem of the vibration-rotational spectrum of the linear asymmetrical triatomic moleenle has been worked out, by the perturbation method of wave mechanics,and the expresaions for the energy of vibration and the convergence factors of the rotational lines of the bands are obtained in terms of the anharmonie potontial constanta.The results are applied to the HON molecule with satisfactory result.
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