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在石英界面处液态水的冲击结构相变

王军国 刘福生 李永宏 张明建 张宁超 薛学东

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在石英界面处液态水的冲击结构相变

王军国, 刘福生, 李永宏, 张明建, 张宁超, 薛学东

The structural transition of water at quartz/water interfaces under shock compression in phase region of liquid

Wang Jun-Guo, Liu Fu-Sheng, Li Yong-Hong, Zhang Ming-Jian, Zhang Ning-Chao, Xue Xue-Dong
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  • 利用轻气炮加载技术和光透射测量技术, 观测了冲击加载过程中水/石英界面处的水结构变化.实验发现,冲击条件(0.5—2 GPa, 335—375 K)下水在液相区内能够发生结构改变且起始于水/石英界面,结构改变的速率和程度与石英界面的特性有关.证实在固/液相边界一定区域内的液态水,在经历高温高压状态的变化中表现出特殊的相转变现象.同时,研究表明液态水结构转变的过程区分为明显的四个动力学阶段.
    We investigate the structural transformations of water at the water/quartz interface under shock compression in ranges from 0.5 to 2 GPa and from 335 to 375 K by techniques of a gas-gun and light transmission tests. The results show that the structural transformation of water occurs in the region of liquid phase, which starts from water/quartz interface at high pressures and temperatures. The transformation rate is related to the property of quartz interface. This structural evolution indicates that a lager number of water molecules undergone transitions in equilibrium behavior. The kinetic process of liquid water structure can be divided into four stages while the structure continues growing to saturation. This new mechanism of structural transformation has immediate implications for water structure transformation in diverse natural environments.
    • 基金项目: 国家自然科学基金(批准号: 10874141, 10974160)资助的课题.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 10874141, 10974160).
    [1]

    Abramson E H 2007 Phys. Rev. E 76 051203

    [2]

    Bridgman P W 1935 J. Chem. Phys. 3 597

    [3]

    Du Q, Freysz E, Shen Y R 1994 Phys. Rev. Lett. 72 238

    [4]

    Du Q, Freysz E, Shen Y R 1994 Sci. 264 826

    [5]

    Eftekhari-Bafrooei A, Borguet E 2009 J. Am. Chem. Soc. 131 12034

    [6]

    Kim J, Kim G, Cremer P S 2001 Langmuir 17 7255

    [7]

    Hassanali A A, Singer S J 2007 J. Phys. Chem. B 111 11181

    [8]

    Ostroverkhov V, Waychunas G A, Shen Y R 2005 Phys. Rev. Lett. 94 46102

    [9]

    Hass K C, Schneider W F, Curioni A, Andreoni W 1998 Sci. 282 265

    [10]

    Ye S, Nihonyanagi S, Uosaki K 2001 Phys. Chem. Chem. Phys. 3 3463

    [11]

    Lipkowski J, Ross P N 1992 Adsorption of molecules at metal electrodes (1st Ed.) (New York: VCH) p224

    [12]

    Fleischmann M, Hendra P J, Hill I, Pemble M 1981 J. Electroanal. Chem. Int. Electrochem. 117 243

    [13]

    Pettinger B, Philpott M R, Gordon II J G 1981 J. Chem. Phys. 74 934

    [14]

    Ataka K, Yotsuyanagi T, Osawa M 1996 J. Phys. Chem. 100 10664

    [15]

    Toney M F, Howard J N, Richer J, Borges G L, Gordon J G, Melroy O R, Wiesler D G, Yee D, Sorensen L B 1995 Surf. Sci. 335 326

    [16]

    Gragson D E, Richmond G L 1998J. Phys. Chem. B 102 3847

    [17]

    Gragson D E, McCarty B M, Richmond G L 1997 J. Amer. Chem. Soc. 119 6144

    [18]

    chnitzer C, Baldelli S, Campbell D J, Shultz M J 1999 J. Phys. Chem. A 103 6383

    [19]

    Shultz M J, Schnitzer C, Simonelli D, Baldelli S 2000 Int. Rev. Phys. Chem. 19 123

    [20]

    Dolan D H, Gupta Y M 2003 Chem. Phys. Lett. 374 608

    [21]

    Dolan D H, Gupta Y M 2004 J. Chem. Phys. 121 9050

    [22]

    Dolan D H, Johnson J N, Gupta Y M 2005 J. Chem. Phys. 123 064702

    [23]

    Dolan D H, Knudson M D, Hall C A, Deeney C 2007 Nat. Phys. 3 339

    [24]

    Li Y H 2011 Ph. D. Dissertation (Chengdu: Southwest Jiaotong University) (in Chinese) [李永宏 2011 博士学位论文 (成都:西南交通大学)]

    [25]

    Jing F Q 1999 Introduction to Experimental Equation of State (Beijing: Science Press) p224 (in Chinese) [经福谦 1999 实验物态方程导引 (北京: 科学出版社) 第 64 页]

    [26]

    Li Y H, Liu F S, Cheng X L, Zhang M J, Xue X D 2011 Acta Phys. Sin. 60 126202 (in Chinese)[李永宏, 刘福生, 程小理, 张明建, 薛学东 2011 物理学报 60 12202]

    [27]

    Goldman N, Reed E J, Kuo I F W, Fried L E, Mundy C J, Curioni A 2009 J. Chem. Phys. 130 124517

    [28]

    Ostroverkhov V, Waychunas G A, Shen Y R 2004 Chem. Phys. Lett. 386 144

    [29]

    Saitta A M, Datchi F 2003 Phys. Rev. E 67 020201

    [30]

    Canpolat M, Starr F W, Scala A, Sadr-Lahijany M R, Mishima O, Havlin S, Stanley H E 1998 Chem. Phys. Lett. 294 9

    [31]

    Li F L, Cui Q L, He Z, Cui T, Zhang J, Zhou Q, Zou G T 2005 J. Chem. Phys. 123 174511

    [32]

    Kawamoto T, Ochiai S, Kagi H 2004 J. Chem. Phys. 120 5867

    [33]

    Matsumoto M, Saito S, Ohmine I 2002 Nat. 416 409

  • [1]

    Abramson E H 2007 Phys. Rev. E 76 051203

    [2]

    Bridgman P W 1935 J. Chem. Phys. 3 597

    [3]

    Du Q, Freysz E, Shen Y R 1994 Phys. Rev. Lett. 72 238

    [4]

    Du Q, Freysz E, Shen Y R 1994 Sci. 264 826

    [5]

    Eftekhari-Bafrooei A, Borguet E 2009 J. Am. Chem. Soc. 131 12034

    [6]

    Kim J, Kim G, Cremer P S 2001 Langmuir 17 7255

    [7]

    Hassanali A A, Singer S J 2007 J. Phys. Chem. B 111 11181

    [8]

    Ostroverkhov V, Waychunas G A, Shen Y R 2005 Phys. Rev. Lett. 94 46102

    [9]

    Hass K C, Schneider W F, Curioni A, Andreoni W 1998 Sci. 282 265

    [10]

    Ye S, Nihonyanagi S, Uosaki K 2001 Phys. Chem. Chem. Phys. 3 3463

    [11]

    Lipkowski J, Ross P N 1992 Adsorption of molecules at metal electrodes (1st Ed.) (New York: VCH) p224

    [12]

    Fleischmann M, Hendra P J, Hill I, Pemble M 1981 J. Electroanal. Chem. Int. Electrochem. 117 243

    [13]

    Pettinger B, Philpott M R, Gordon II J G 1981 J. Chem. Phys. 74 934

    [14]

    Ataka K, Yotsuyanagi T, Osawa M 1996 J. Phys. Chem. 100 10664

    [15]

    Toney M F, Howard J N, Richer J, Borges G L, Gordon J G, Melroy O R, Wiesler D G, Yee D, Sorensen L B 1995 Surf. Sci. 335 326

    [16]

    Gragson D E, Richmond G L 1998J. Phys. Chem. B 102 3847

    [17]

    Gragson D E, McCarty B M, Richmond G L 1997 J. Amer. Chem. Soc. 119 6144

    [18]

    chnitzer C, Baldelli S, Campbell D J, Shultz M J 1999 J. Phys. Chem. A 103 6383

    [19]

    Shultz M J, Schnitzer C, Simonelli D, Baldelli S 2000 Int. Rev. Phys. Chem. 19 123

    [20]

    Dolan D H, Gupta Y M 2003 Chem. Phys. Lett. 374 608

    [21]

    Dolan D H, Gupta Y M 2004 J. Chem. Phys. 121 9050

    [22]

    Dolan D H, Johnson J N, Gupta Y M 2005 J. Chem. Phys. 123 064702

    [23]

    Dolan D H, Knudson M D, Hall C A, Deeney C 2007 Nat. Phys. 3 339

    [24]

    Li Y H 2011 Ph. D. Dissertation (Chengdu: Southwest Jiaotong University) (in Chinese) [李永宏 2011 博士学位论文 (成都:西南交通大学)]

    [25]

    Jing F Q 1999 Introduction to Experimental Equation of State (Beijing: Science Press) p224 (in Chinese) [经福谦 1999 实验物态方程导引 (北京: 科学出版社) 第 64 页]

    [26]

    Li Y H, Liu F S, Cheng X L, Zhang M J, Xue X D 2011 Acta Phys. Sin. 60 126202 (in Chinese)[李永宏, 刘福生, 程小理, 张明建, 薛学东 2011 物理学报 60 12202]

    [27]

    Goldman N, Reed E J, Kuo I F W, Fried L E, Mundy C J, Curioni A 2009 J. Chem. Phys. 130 124517

    [28]

    Ostroverkhov V, Waychunas G A, Shen Y R 2004 Chem. Phys. Lett. 386 144

    [29]

    Saitta A M, Datchi F 2003 Phys. Rev. E 67 020201

    [30]

    Canpolat M, Starr F W, Scala A, Sadr-Lahijany M R, Mishima O, Havlin S, Stanley H E 1998 Chem. Phys. Lett. 294 9

    [31]

    Li F L, Cui Q L, He Z, Cui T, Zhang J, Zhou Q, Zou G T 2005 J. Chem. Phys. 123 174511

    [32]

    Kawamoto T, Ochiai S, Kagi H 2004 J. Chem. Phys. 120 5867

    [33]

    Matsumoto M, Saito S, Ohmine I 2002 Nat. 416 409

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  • PDF下载量:  368
  • 被引次数: 0
出版历程
  • 收稿日期:  2011-12-22
  • 修回日期:  2012-03-22

在石英界面处液态水的冲击结构相变

  • 1. 西南交通大学高压科学与技术实验室,成都 610031;
  • 2. 运城学院物理与电子工程系, 运城 044000
    基金项目: 国家自然科学基金(批准号: 10874141, 10974160)资助的课题.

摘要: 利用轻气炮加载技术和光透射测量技术, 观测了冲击加载过程中水/石英界面处的水结构变化.实验发现,冲击条件(0.5—2 GPa, 335—375 K)下水在液相区内能够发生结构改变且起始于水/石英界面,结构改变的速率和程度与石英界面的特性有关.证实在固/液相边界一定区域内的液态水,在经历高温高压状态的变化中表现出特殊的相转变现象.同时,研究表明液态水结构转变的过程区分为明显的四个动力学阶段.

English Abstract

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