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(Bi, La)4Ti3O12-Sr(Bi, La)4Ti4O15共生结构铁电材料性能研究

朱 骏 卢网平 刘秋朝 毛翔宇 惠 荣 陈小兵

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(Bi, La)4Ti3O12-Sr(Bi, La)4Ti4O15共生结构铁电材料性能研究

朱 骏, 卢网平, 刘秋朝, 毛翔宇, 惠 荣, 陈小兵

A study on the properties of (Bi, La)4Ti3O12- Sr(Bi, La)4Ti4O15 intergrowth ferroelectrics

Zhu Jun, Lu Wang-Ping, Liu Qiu-Chao, Mao Xiang-Yu, Hui Rong, Chen Xiao-Bing
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  • 采用固相烧结工艺,制备了不同La掺杂量(x=0.00,0.25,0.50,0.75,1.00,1.25和1.50) 的(Bi, La)4Ti3O12-Sr(Bi, La)4Ti4O15 (SrBi8-xLaxT i7O27)共生结构铁电陶瓷样品.用x射线衍射对其进行微结构分析 ,并测量铁
    Lanthanum_doped intergrowth ferroelectrics: (Bi,La)4Ti3O 12-Sr(Bi,La)4Ti4O15 (SrBi8-xLaxTi7O27) (x=0.00, 0.25, 0.50, 0.75, 1.00, 1.25, 1.50) ceramic samples have been prepared by solid_state reaction m ethod. Their structure was analyzed by x_ray diffraction, and their dielectricit y and ferroelectricity were measured. It is found that La doping does not change the crystal structure of Bi4Ti3O12-SrBi4Ti4O15. The coerciv e field (EC) of SrBi8-xLaxTi7O2 7 increases slightly and the remnant polarization (2Pr) increases at first, then decreases with th e increas e of La content. The 2Pr reaches a maximum value of 25.6 μC·cm-2, whe n x is 0.50. The 2Pr increases nearly 60%, but the EC incr eases only about 10%, compared with those of SrBi8Ti7O27. Their temperatures of phase t ransition (TC) decrease with La doping. The TC of SrBi7.5La0.50Ti7O27 is 556 ℃ and shows good thermal stability. As x becomes 1.50, the SrBi7.5La0.50Ti7O27 exhibits a characteristic of relaxor ferroelectrics.
    • 基金项目: 国家自然科学基金(批准号:10274066)和江苏省教育厅自然科学基金(批准号:01KJB140011 )资助的课题.
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  • 文章访问数:  6579
  • PDF下载量:  601
  • 被引次数: 0
出版历程
  • 收稿日期:  2003-01-08
  • 修回日期:  2003-01-29
  • 刊出日期:  2003-05-05

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