In this paper, we calculate the energy levels of configuration 3d-94s4p (J=1/2;3/2,Nth=1—4;1—7) for copper-like sequence ions from GeⅣ—RuⅩⅥ by HXR method. With the important effects, such as correlation effect, quantum electrodynamics (QED) effects and the other effects taken into account, we have made a systemisitic fit calculation for energy levels of ions mentioned above. We predict here the energy levels of configuration 3d-94s4p(J=1/2;3/2,Nth=1—4;1—7) for ions MoⅩⅣ—RuⅩⅥ.The wavelengths, oscillator strengths and probabilities of transition 3d-104s—3d-94s4p(J=1/2; 3/2,Nth=1—4; 1—7) are computed too.