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On the Approximate Partition Function in the Statistical Theory of Adsorption

C. F. Ying

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On the Approximate Partition Function in the Statistical Theory of Adsorption

C. F. Ying

On the Approximate Partition Function in the Statistical Theory of Adsorption

C. F. Ying
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  • Wang's theory for determining the approximate configurational partition function of the adsorbed layer is modified in two different ways. One is to assume that the configurational energy should be corrected; the other to advocate that the deficiency due to a wrong expression for the a priori probability of the central site is more significant. The configurational partition function is evaluated in both methods and the adsorption isotherm and the heat of adsorption computed for the case of quadratic lattice with dipole interaction. Values for the last two quantities when a uniform continuous distribution of the distant adsorbed particles is assumed are further given for comparison. The second method, which surpasses the first, is compared with Kirkwood's method in the case of hexagonal lattice with neighbour interaction. Numerical work is also carried out in this case.
    Wang's theory for determining the approximate configurational partition function of the adsorbed layer is modified in two different ways. One is to assume that the configurational energy should be corrected; the other to advocate that the deficiency due to a wrong expression for the a priori probability of the central site is more significant. The configurational partition function is evaluated in both methods and the adsorption isotherm and the heat of adsorption computed for the case of quadratic lattice with dipole interaction. Values for the last two quantities when a uniform continuous distribution of the distant adsorbed particles is assumed are further given for comparison. The second method, which surpasses the first, is compared with Kirkwood's method in the case of hexagonal lattice with neighbour interaction. Numerical work is also carried out in this case.
  • [1] 张国藩. A KINETIC THEORY OF TURBULENCE. 物理学报, 1948, 7(3): 62-77. doi: 10.7498/aps.7.62-3
    [2] T. T. Kou, Ta-You Wu. Hylleraasian Wave Function of 2s2 1S of Helium. 物理学报, 1945, 6(1): 50-58. doi: 10.7498/aps.6.50
    [3] T. Z. Ku. Separable Wave Function of the Ground State of Helium Constructed from Hylleraas' Wave Function. 物理学报, 1945, 6(1): 21-26. doi: 10.7498/aps.6.21
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