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界面自组装的金/氧化石墨烯复合材料的表面增强拉曼散射行为研究

汤建 刘爱萍 李培刚 沈静琴 唐为华

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界面自组装的金/氧化石墨烯复合材料的表面增强拉曼散射行为研究

汤建, 刘爱萍, 李培刚, 沈静琴, 唐为华

Surface-enhanced Raman scattering of gold/graphene oxide composite materials fabricated by interface self-assembling

Tang Jian, Liu Ai-Ping, Li Pei-Gang, Shen Jing-Qin, Tang Wei-Hua
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  • 采用Frens法制备金纳米粒子溶胶,通过界面自组装技术在掺磷的非晶碳衬底表面构筑三维的金/氧化石墨烯/金复合结构. 以罗丹明B为探针分子,考察金/氧化石墨烯/金复合材料的表面增强拉曼散射活性. 结果表明,由于氧化石墨烯的化学增强和金纳米粒子的电磁场增强的协同作用,在该三维复合材料上获得了很强的罗丹明B拉曼信号. 所设计的三维金/氧化石墨烯/金复合材料在生物分析、环境监测、疾病防控、食品安全等领域具有潜在的应用价值.
    The colloidal gold nanoparticles (AuNP) are synthesized by the classic Frens' method, and the sandwich-structured AuNP/graphene oxide/AuNP (AuNP/GO/AuNP) composite materials are constructed on the phosphorus doped diamond-like carbon film by the interface self-assembling. The surface enhanced Raman scattering behaviors of the AuNP/GO/AuNP composites are investigated by using the rhodamine B (RhB) as the probe molecules. Our results indicate that the Raman intensity of RhB obtained from the AuNP/GO/AuNP composites shows a 16.5-fold increase over that from the AuNP monolayer due to the coupled effect of chemical enhancement of GO and localized electromagnetic field enhancement of plasmonic gold. The designed composite materials with metal/GO/metal sandwich configuration exhibit great potential applications in biochemical analysis, environmental monitoring, disease controlling, and food safety.
    • 基金项目: 国家自然科学基金(批准号:51272237,61274017,51172208)、浙江理工大学521人才培养计划(批准号:20132)、教育部留学回国人员科研启动基金(批准号:2013693)和浙江省留学人员科技活动择优计划(批准号:2012323)资助的课题.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51272237, 61274017, 51172208), the 521 Talents Training Program of Zhejiang Sci-Tech University, China (Grant No. 20132), the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars of Ministry of Education, China (Grant No. 2013693), and the Selected Scientific Research Program for Overseas Chinese Scholar of Zhejiang Province, China (Grant No. 2012323).
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    Ren W, Fang Y X, Wang E K 2011 ACS Nano 5 6425

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    Sun Z H, Wang H Y, Wang H, Zhang Z D, Zhang Z Y 2012 Acta Phys. Sin. 61 125202 (in Chinese) [孙中华, 王红艳, 王辉, 张志东, 张中月 2012 物理学报 61 125202]

    [20]

    Wu M C, Yi C, Chuang C M, Hsu C P, Lin J F, Chen Y F, Su Y F 2009 ACS Appl. Mater. Interfaces 1 2848

    [21]

    Wu Q S, Zhao Y, Zhang C B, Li F 2005 Acta Phys. Sin. 54 1452 (in Chinese) [吴青松, 赵岩, 张彩碚, 李峰 2005 物理学报 54 1452]

    [22]

    Ramon A P, Cui B, Pablo J B V, Teodor V, Fenniri H 2007 J. Phys. Chem. 111 6720

    [23]

    Li Z Y, William M T, William F S, David L N, Williams R S 2007 Langmuir 23 5315

    [24]

    Huh S, Park J, Kim Y S, Kim K S, Hong B H, Nam J M 2011 ACS Nano 5 9799

    [25]

    Xu W G, Ling X, Xiao J Q, Dresselhaus M S, Kong J, Xu H X, Liu Z F, Zhang J 2012 PNAS 109 9281

    [26]

    Kim Y K, Han S W, Min D H 2012 ACS Appl. Mater. Interfaces 4 6545

    [27]

    Liu A P, Xu T, Ren Q H, Yuan M, Dong W J, Tang W H 2012 Electrochem. Commun. 25 74

    [28]

    Lin S T, Franklin M T, Kenneth J K 1986 Langmuir 2 259

    [29]

    Liu A P, Ren Q H, Xu T, Yuan M, Tang W H 2012 Sens. Actuators. B 162 135

    [30]

    Hummers W S, Offema R E 1958 J. Am. Chem. Soc. 80 1339

    [31]

    Wang Z L, Mohamed M B, Link S, El-Sayed M A 1999 Surf. Sci. 440 L809

    [32]

    Uosaki K, Shen Y, Kondo T 1995 J. Phys. Chem. 99 14117

    [33]

    Shigeru W, Hideki S, Katsuhira Y, Kouichi K, Tsugio T, Hisayoshi S 2005 Tetra. Lett. 46 8827

    [34]

    Zhang J T, Li X L, Sun X M, Li Y D 2005 J. Phys. Chem. B 109 12544

  • [1]

    Ling X, Xie L M, Fang Y, Xu H, Zhang H L, Kong J, Dresselhaus M S, Zhang J, Liu Z F 2010 Nano Lett. 10 553

    [2]

    He S J, Liu K K, Su S, Yan J, Mao X H, Wang D F, He Y, Li L J, Song S P, Fan C H 2012 Anal. Chem. 84 4622

    [3]

    Chon H, Lee S, Yoon S Y, Chang S I, Lim D W, Choo J 2011 Chem. Commun. 47 12515

    [4]

    Fang C, Wu G Z 2011 Acta Phys. Sin. 60 033301 (in Chinese) [房超, 吴国祯 2011 物理学报 60 033301]

    [5]

    Huang Q, Xiong S Z, Zhao Y, Zhang X D 2012 Acta Phys. Sin. 61 157801 (in Chinese) [黄茜, 熊绍珍, 赵颖, 张晓丹 2012 物理学报 61 157801]

    [6]

    Xu H X, Bjerneld E J, Käll M, Börjesson L 1999 Phys. Rev. Lett. 83 4357

    [7]

    Xu H X, Aizpurua J, Käll M, Apell P 2000 Phys. Rev. E 62 4318

    [8]

    Tong L M, Xu H X 2012 Physics 41 582 (in Chinese) [童廉明, 徐红星 2012 物理 41 582]

    [9]

    Wei H, Xu H X 2013 Nanoscale 5 10794

    [10]

    Chen L, Wei H, Chen K Q, Xu H X 2014 Chin. Phys. B 23 027303

    [11]

    Zhou X, Fang J S, Yang D W, Liao X P 2012 Chin. Phys. B 21 084202

    [12]

    Deng C Y, Zhang G L, Zou B, Shi H L, Liang Y J, Li Y C, Fu J X, Wang W Z 2013 Chin. Phys. B 22 106102

    [13]

    Yu X X, Cai H B, Zhang W H, Li X J, Pan N, Luo Y, Wang X P, Hou J G 2011 ACS Nano 5 952

    [14]

    Zhang R, Xiao X Z, L C, Luo Y, Xu Y 2014 Acta Phys. Sin. 63 014206 (in Chinese) [张然, 肖鑫泽, 吕超, 骆杨, 徐颖 2014 物理学报 63 014206]

    [15]

    Zhang L, Lang X Y, Hirata A, Chen M W 2011 ACS Nano 5 4407

    [16]

    Ren W, Fang Y X, Wang E K 2011 ACS Nano 5 6425

    [17]

    Xie H N, Larmour I A, Smith W E, Faulds K, Graham D 2012 J. Phys. Chem. 116 8338

    [18]

    Chandra M, Dowgiallo A M, Knappenberger K L 2010 J. Am. Chem. Soc. 132 15782

    [19]

    Sun Z H, Wang H Y, Wang H, Zhang Z D, Zhang Z Y 2012 Acta Phys. Sin. 61 125202 (in Chinese) [孙中华, 王红艳, 王辉, 张志东, 张中月 2012 物理学报 61 125202]

    [20]

    Wu M C, Yi C, Chuang C M, Hsu C P, Lin J F, Chen Y F, Su Y F 2009 ACS Appl. Mater. Interfaces 1 2848

    [21]

    Wu Q S, Zhao Y, Zhang C B, Li F 2005 Acta Phys. Sin. 54 1452 (in Chinese) [吴青松, 赵岩, 张彩碚, 李峰 2005 物理学报 54 1452]

    [22]

    Ramon A P, Cui B, Pablo J B V, Teodor V, Fenniri H 2007 J. Phys. Chem. 111 6720

    [23]

    Li Z Y, William M T, William F S, David L N, Williams R S 2007 Langmuir 23 5315

    [24]

    Huh S, Park J, Kim Y S, Kim K S, Hong B H, Nam J M 2011 ACS Nano 5 9799

    [25]

    Xu W G, Ling X, Xiao J Q, Dresselhaus M S, Kong J, Xu H X, Liu Z F, Zhang J 2012 PNAS 109 9281

    [26]

    Kim Y K, Han S W, Min D H 2012 ACS Appl. Mater. Interfaces 4 6545

    [27]

    Liu A P, Xu T, Ren Q H, Yuan M, Dong W J, Tang W H 2012 Electrochem. Commun. 25 74

    [28]

    Lin S T, Franklin M T, Kenneth J K 1986 Langmuir 2 259

    [29]

    Liu A P, Ren Q H, Xu T, Yuan M, Tang W H 2012 Sens. Actuators. B 162 135

    [30]

    Hummers W S, Offema R E 1958 J. Am. Chem. Soc. 80 1339

    [31]

    Wang Z L, Mohamed M B, Link S, El-Sayed M A 1999 Surf. Sci. 440 L809

    [32]

    Uosaki K, Shen Y, Kondo T 1995 J. Phys. Chem. 99 14117

    [33]

    Shigeru W, Hideki S, Katsuhira Y, Kouichi K, Tsugio T, Hisayoshi S 2005 Tetra. Lett. 46 8827

    [34]

    Zhang J T, Li X L, Sun X M, Li Y D 2005 J. Phys. Chem. B 109 12544

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出版历程
  • 收稿日期:  2013-12-27
  • 修回日期:  2014-02-08
  • 刊出日期:  2014-05-05

界面自组装的金/氧化石墨烯复合材料的表面增强拉曼散射行为研究

  • 1. 浙江理工大学物理系, 光电材料与器件中心, 杭州 310018;
  • 2. 北京邮电大学理学院, 信息光子学与光通信国家重点实验室, 北京 100876
    基金项目: 

    国家自然科学基金(批准号:51272237,61274017,51172208)、浙江理工大学521人才培养计划(批准号:20132)、教育部留学回国人员科研启动基金(批准号:2013693)和浙江省留学人员科技活动择优计划(批准号:2012323)资助的课题.

摘要: 采用Frens法制备金纳米粒子溶胶,通过界面自组装技术在掺磷的非晶碳衬底表面构筑三维的金/氧化石墨烯/金复合结构. 以罗丹明B为探针分子,考察金/氧化石墨烯/金复合材料的表面增强拉曼散射活性. 结果表明,由于氧化石墨烯的化学增强和金纳米粒子的电磁场增强的协同作用,在该三维复合材料上获得了很强的罗丹明B拉曼信号. 所设计的三维金/氧化石墨烯/金复合材料在生物分析、环境监测、疾病防控、食品安全等领域具有潜在的应用价值.

English Abstract

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