Study on the crossover of static dielectric constants of liquids with temperature and the relevant correlations

Zhang Li-Li; Huang Xin-Ru; Zhou Heng-Wei; Huang Yi-Neng

doi:10.7498/aps.61.077701

Abstract

In order to induce the general behaviors of the orientation correlations between molecules from the variation of static dielectric constant of liquid with temperature, we filtrate the experimental data of 18 kinds of liquids with the contribution of the electronic polarizations much smaller than that of the orientation correlations between molecules from the present references. The results indicate that there is a universal crossover for the varication of the static dielectric constants of the liquids with temperature, and for such a kind of crossover, there exist at least two kinds of orientation correlation orders between molecules, one increases but the other decreases with temperature.

Keywords:

Authors and contacts

1.
Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matter Physics, Physical College of Science and Technology, Yili Normal University, Yining 835000, China;
2.
National Lab of Solid State Microstructures, College of Physics, Nanjing University, Nanjing 210093, China;
3.
Department of Physics, Shihezi University, Shihezi 832003, China
Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 10774064, 30860076), the High Technology of Xin- jiang (Grant No. 200916126), and the Key Natural Science Foundation of Xinjiang Science-Technology Department (Grant Nos. 200821104, 200821184).

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[11]	Zhang J L, Wang L N, Zhou H W, Zhang L L, Zhao X Y, Huang Y N 2010 Chin. Phys. B 19 056403
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[17]	Jiang J G, Huang Y N 2009 Comp. Phys. Commun. 180 177
[18]	Jiang J G, Huang Y N, Wu J C 2009 J. Stat. Phys. 136 984
[19]	Guo X Z, Zhou H W, Zhang L L, Wu W H, Zhang J L, Huang Y N 2010 Acta Phys. Sin. 59 417 (in Chinese) [郭秀珍, 周恒为, 张丽丽, 吴文慧, 张晋鲁, 黄以能 2010 物理学报 59 417]
[20]	Zhao M L, Yi.X J, Wang C L, Wang J F, Zhang J L 2006 Chin. Phys. 15 1611
[21]	Wen C 1995 Chin. Phys. 4 54
[22]	Zhao H P, Liu Z Y, Liu Y Y 2001 Chin. Phys. 10 35
[23]	Wang X J, Gong Z Q, Qian Y F, Zhu J, Chen X B 2007 Chin. Phys. 16 2131
[24]	Zhou H W, Zhang J L, Huang Y N, Ying X N, Zhang L, Wu W H, Shen Y F 2007 Acta Phys. Sin. 56 6547 (in Chinese) [周恒为, 晋鲁, 黄以能, 应学农, 张亮, 吴文惠, 沈异凡 2007 物理学报 56 6547]
[25]	Zhao Z F, Zhang Z, Li Z, Wei P, Zhao D Q, Pan M X, Wang W L, Wang W H 2004 Acta Phys. Sin. 53 850 (in Chinese) [赵作峰, 张志, 李正, 闻平, 赵德乾, 潘明详, 王万录, 汪卫华 2004 物理学报 53 850]
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[31]	Weber M J 2003 Handbook of optical materials (CRC Press, Lawrence Berkeley National Laboratory)
[32]	Cardarelli F 2005 Materials Handbook, 2nd Edition (Berlin: Springer-Verlag)

Cited By

[1]	Donth E 2001 The Glass Transition (Berlin: Spring)
[2]	Yin Z W 2003 Dielectrics Physics (Beijing: Scientific Publication, 2nd Edition)
[3]	Fröhlich H 1958 Theory of Dielectrics (Oxford: Oxford university press 2nn Edition)
[4]	Böttcher C F J, Bordewijk P 1978 Theory of Electric Polarization Vol. (Amsterdam: Elsevier)
[5]	Anderson P W 1995 Science 267 1615
[6]	Liu Y H, Wang G, Wang R J, Zhao D Q, Pan M X, Wang W H 2007 Science 315 1385
[7]	Zhao Z F, Wen P, Sheck C H, Wang W H 2007 Phys. Rev. B 75 174201
[8]	Huang Y N, Wang C J, Riande E 2005 J. Chem. Phys. 122 144502
[9]	Huang Y N, Zhang J L, Ying X N 2006 Prog. Phys. 26 359 (in Chinese) [黄以能, 张晋鲁, 应学农 2006 物理学进展 26 359]
[10]	Huang Y N 2006 J. Yili Normal University 3 39 (in Chinese) [黄以能 2006 伊犁师范学院学报 3 39]
[11]	Zhang J L, Wang L N, Zhou H W, Zhang L L, Zhao X Y, Huang Y N 2010 Chin. Phys. B 19 056403
[12]	Zhang J L, Wang L N, Zhao X Y, Zhang L L, Zhou H W, Wei L, Huang Y N 2011 Chin. Phys. B 20 026401
[13]	Zhao X Y, Wang L N, Fan X H, Zhang L L, Wei L, Zhang J L, Huang Y N 2011 Acta Phys. Sin. 60 424 (in Chinese) [赵兴宇, 王丽娜, 樊小辉, 张丽丽, 卫来, 张晋鲁, 黄以能 2011 物理学报 60 424]
[14]	Wu W H, Zhang J L, Zhou H W, Huang Y N, Zhang L, Ying X N 2008 Appl. Phys. Lett. 92 011918
[15]	Zhang J L, Zhou H W, Wu W H, Huang Y N Appl. Phys. Lett. 92 131906
[16]	Zhang L L, Zhang J L, Jiang J G, Zhou H W, Huang Y N 2008 Acta Phys. Sin. 57 5817 (in Chinese) [张丽丽, 张晋鲁, 蒋建国, 周恒为, 黄以能 2008 物理学报 57 5817]
[17]	Jiang J G, Huang Y N 2009 Comp. Phys. Commun. 180 177
[18]	Jiang J G, Huang Y N, Wu J C 2009 J. Stat. Phys. 136 984
[19]	Guo X Z, Zhou H W, Zhang L L, Wu W H, Zhang J L, Huang Y N 2010 Acta Phys. Sin. 59 417 (in Chinese) [郭秀珍, 周恒为, 张丽丽, 吴文慧, 张晋鲁, 黄以能 2010 物理学报 59 417]
[20]	Zhao M L, Yi.X J, Wang C L, Wang J F, Zhang J L 2006 Chin. Phys. 15 1611
[21]	Wen C 1995 Chin. Phys. 4 54
[22]	Zhao H P, Liu Z Y, Liu Y Y 2001 Chin. Phys. 10 35
[23]	Wang X J, Gong Z Q, Qian Y F, Zhu J, Chen X B 2007 Chin. Phys. 16 2131
[24]	Zhou H W, Zhang J L, Huang Y N, Ying X N, Zhang L, Wu W H, Shen Y F 2007 Acta Phys. Sin. 56 6547 (in Chinese) [周恒为, 晋鲁, 黄以能, 应学农, 张亮, 吴文惠, 沈异凡 2007 物理学报 56 6547]
[25]	Zhao Z F, Zhang Z, Li Z, Wei P, Zhao D Q, Pan M X, Wang W L, Wang W H 2004 Acta Phys. Sin. 53 850 (in Chinese) [赵作峰, 张志, 李正, 闻平, 赵德乾, 潘明详, 王万录, 汪卫华 2004 物理学报 53 850]
[26]	Kirkwood J G 1939 J. Chem. Phys. 7 911
[27]	Oster G, Kirkwood J G 1943 J. Chem. Phys. 11 175
[28]	Dannhauser W, Cole R H 1955 J. Chem. Phys. 23 1762
[29]	Suresh S J, Naik V M 2000 J. Chem. Phys. 113 9727
[30]	Wohlfarth C 1991 Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures, Vol. 6 (Berlin: Springer-Verlag)
[31]	Weber M J 2003 Handbook of optical materials (CRC Press, Lawrence Berkeley National Laboratory)
[32]	Cardarelli F 2005 Materials Handbook, 2nd Edition (Berlin: Springer-Verlag)

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Vol. 61, Issue 7 - 2012-04-05

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