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DEVIATION OF VAN DER WAALS INTERACTION FROM ADDITIVE RELATIONS

KUN HUANG AVRIL RHYS

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DEVIATION OF VAN DER WAALS INTERACTION FROM ADDITIVE RELATIONS

KUN HUANG, AVRIL RHYS
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  • With a lattice of isotropic point-oscillators as an idealized model, the error of the usual additive approximation for the van der Waals interaction in solids is estimated. For a few common crystals, the estimated errors for van der Waals energy and its first and second derivatives have values up to 13%, 34% and 70% respectively. The model moreover points to the possible importance of the long range dipolar interaction as a mechanism determining the structure of the exciton-band in. insulators.
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  • Abstract views:  6177
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  • Received Date:  20 August 1951
  • Published Online:  20 March 1951

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