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中国物理学会期刊

动力学对称群方法对三原子分子高激发振动态的理论研究

CSTR: 32037.14.aps.48.438

DYNAMICAL SYMMETRY GROUP FOR VIBRATIONAL SPECTRA OF TRIATOMIC MOLECULES

CSTR: 32037.14.aps.48.438
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  • 利用动力学对称群方法研究了弯曲三原子分子的振动高激发态能谱-该方法显示:三原子分子的动力学对称性为U1(4)U2(4),则三原子分子的Hamiltonian量可写成代数的各元素之和,通过李代数处理而求得分子代数Hamiltonian量的本征值,进而得到分子的振动能谱-并具体计算了O3分子-

     

    Dynamical symmetry group for highly excited vibrational spectra of triatomic molecules has been studied-The results showed that the dynamicsl symmetry of tiratomic molecules are U1(4)U2(4)-Therefore,the Hamiltonian of triatomic molecules can be writen as the sum of elements of Lie algebra U1(4)U2(4)- And the eigenvalue of molecular Hamiltonian can be obtained by Lie algebraic treatment-

     

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