Angle-resolved photoemisson spectra were measured at normal emission on the cleaved (111) surface of C60 single crystal.Valence band dispersions have been studied with varying photon energy of synchrotron radiation rays from 13.0eV to 34.0eV. The largest dispersions are 0.27eV and 0.42eV along the Γ—L direction for the HOMO and HOMO-1 derived bands respectively. The dispersion curves coincide with the theoretical electronic structure fairly well.