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中国物理学会期刊

磷光染料掺杂有机分子发光的能量转移研究

CSTR: 32037.14.aps.57.7317

The energy transfer in phosphorescent dye PtOEP doped organic molecule Alq

CSTR: 32037.14.aps.57.7317
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  • 用稳态光谱和时间分辨的超快光谱研究了不同浓度磷光染料PtOEP掺杂有机小分子Alq薄膜的发光特性和能量转移.据PtOEP的吸收光谱与Alq的荧光光谱,用Frster理论估算出Alq:PtOEP掺杂体系的能量转移临界半径及其转移效率.稳态荧光光谱显示,在Alq:PtOEP掺杂薄膜中,随着掺杂浓度的升高,PtOEP的发光强度增强,Alq的发光强度逐渐减弱,两者间的能量转移效率与理论计算结果一致.利用时间分辨光谱研究了Alq:PtOEP掺杂薄膜体系的能量转移动力学过程,观察到Alq:PtOEP掺杂薄膜的荧光寿

     

    The energy transfer process of phosphorescent dye PtOEP (2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine platinum(II) doped organic molecule Alq (tris(8- hydroxyquinoline) aluminum) thin films were studied by steady-state spectrum and time-resolved spectrum. The energy transfer efficiency and critical radius of the doped thin films were estimated from the overlap integral between the absorption spectra of PtOEP and the fluorescent spectra of Alq based on Frster theory. The experimental results from steady fluorescent spectra were approximately consistent with the estimation, which indicates that Frster energy transfer mechanism is operative in dye doped organic thin films. The experimental results from time-resolved fluorescent spectroscopy show that the fluorescent lifetime of Alq in the doped thin films decreases gradually with the doping concentration, indicating that there is an efficient energy transfer from Alq to PtOEP in the doped thin films.

     

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