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中国物理学会期刊

基于相场方法的多孔合金马氏体相变模拟

CSTR: 32037.14.aps.72.20230212

Phase-field method based simulation of martensitic transformation in porous alloys

CSTR: 32037.14.aps.72.20230212
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  • 相比块体材料, 多孔材料中孔洞的存在影响形状记忆合金马氏体相变的演化过程, 包括马氏体变体形貌、分布以及自协调效应. 实验结果表明, 引入金属-空气界面可以细化马氏体变体组织, 从而可提升合金的阻尼性能. 本文在实验观察中发现界面周围没有出现马氏体变体的浮凸, 且存在非相变组织, 分析认为多孔材料中存在的金属-空气界面并不是自由表面. 基于与时间相关的金茨堡-朗道方程构建了不同界面约束下的三维相场模型, 研究了多孔材料中约束界面对马氏体变体自协调效应的影响. 在金属-空气界面附近模拟得到了细小的马氏体变体自协调形貌, 与实验结果一致. 在界面约束条件下, 体系主要以降低应变能的方式实现总能量的最小化. 不同界面条件下的模拟结果表明, 提高多孔材料的比表面积是得到更多细小马氏体变体组织的有效手段.

     

    Porous materials, characterized by the presence of interconnected pores, exhibit the properties different from their bulk counterparts. One of properties of interest is that the pores can influence the martensitic transformation in shape memory alloys (SMAs), which directly affects the material's shape memory effect and mechanical properties. The martensitic transformation is accompanied by the formation of different martensitic variants, which determine the overall morphology, distribution, and self-accommodation effect of the transformed regions. Previous experimental studies have shown that the presence of pores, particularly at the metal-air interface, can significantly affect the martensitic variant structure, leading to its thinning. This thinning effect has been found to be able to improve the damping performance of the alloy. Experimental observations have indicated that no relief of martensitic variants was found around the metal-air interface, but non-transformed regions were observed. These observations suggest that the metal-air interface in porous materials is not a free surface and plays a crucial role in influencing the martensitic transformation. To further investigate the effect of martensitic variant self-accommodation on different constrained interfaces in porous materials, a three-dimensional phase-field model based on the time dependent Ginzburg-Landau (TDGL) function is proposed in this study. The phase-field model can give a comprehensive understanding of the evolution of martensitic variants and their interaction with the constrained interfaces. Remarkably, the simulation results accord well with the experimental findings, demonstrating the presence of fine martensitic variants near the metal-air interface. The simulations under different interface constraint conditions reveal that increasing the specific surface area of porous materials is an effective strategy to obtain a more refined martensitic variant structure. The system’s total energy is minimized by reducing the strain energy, which leads to the formation of a greater number of fine martensitic variants. This finding suggests that controlling the specific surface area of porous materials can be a promising approach to tailoring the mechanical properties of SMAs for specific applications. In conclusion, the presence of metal-air interface in porous material significantly influences the evolution of the martensitic transformation in SMA. Experimental observations show that the introduction of pore can modify the martensitic variant structure, resulting in improved damping performance. The proposed phase-field model successfully captures the behavior of martensitic variants near constrained interface. The simulation results emphasize the importance of specific surface area in obtaining fine martensitic variant structures. These findings contribute to a more in-depth understanding of the role of porous materials in shaping the properties of SMAs and provide a valuable insight into their design and application in various fields.

     

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