Development of ultrahigh strength bulk metallic glasses

Wei Xin-Quan; Bi Jia-Zi; Li Ran

doi:10.7498/aps.66.176408

Abstract

It is always desirable to develop bulk metal materials with extremely mechanical properties. Ultrahigh strength bulk metallic glass (BMG) is a kind of advanced metallic material with extremely high strength (above 4 GPa), high thermal stability (the glass transition temperature: normally above 800 K), and high hardness (normally above 12 GPa). A typical system of the ultrahigh strength BMG is Co-Ta-B alloy with a fracture strength of above 6 GPa, which is the highest value in the fracture strengths for all kinds of bulk metallic materials (including crystalline and amorphous ones) that we have known so far. In this paper, the compositions, thermal properties, elastic constants, and mechanical properties for all of the reported ultrahigh strength BMGs are summarized. The research progress of these BMGs is also introduced. The correlations among the characteristic temperature, elastic constants, hardness and mechanical properties are built, and the natures of chemical bonding for the ultrahigh strength and high hardness of these BMGs are revealed. The results relating to the structure and physical properties of this kind of ultrahigh strength BMG are significant for potential applications in advanced manufacture, super-durable components and machining.

Keywords:

Authors and contacts

1.
School of Materials Science and Engineering, Beihang University, Beijing 100191, China

Corresponding author: Li Ran, liran@buaa.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant No. 51131002), the Fok Ying-Tong Education Foundation for Young Teachers in the Higher Education Institutions of China (Grant No. 142008), and the Beijing Natural Science Foundation, China (Grant No. 2172034).

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[41]	Liu Y H, Wang G, Wang R J, Zhao D Q, Pan M X, Wang W H 2007 Science 315 1385
[42]	Lewandowski J J, Wang W H, Greer A L 2005 Phil. Mag. Lett. 85 77
[43]	Egami T, Poon S J, Zhang Z, Keppens V 2007 Phys. Rev. B 76 024203
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Cited By

[1]	Ashby M F 2005 Materials Selection in Mechanical Design (Third Edition) (Butterworth-Heinemann) pp1-9
[2]	Lu K 2010 Science 328 319
[3]	Morris Jr J W, Guo Z, Krenn C R, Kim Y H 2001 ISIJ International 41 599
[4]	Li Y, Raabe D, Herbig M, Choi P P, Goto S, Kostka A, Yarita H 2014 Phys. Rev. Lett. 113 106104
[5]	Li Y J, Choi P, Goto S Borchers C, Raabe D, Kirchheim R 2012 Acta Mater. 60 4005
[6]	Ashby M F, Greer A L 2006 Scripta Mater. 54 321
[7]	Wang W H 2005 J. Non-Cryst. Solids 351 1481
[8]	Inoue A 2000 Acta Mater 48 279
[9]	Wang W H 2012 Prog. Mater. Sci. 57 487
[10]	Chen H S 1974 Acta Metall. 22 1505
[11]	Drehman A J, Greer A L, Turnbull D 1982 Appl. Phys. Lett. 41 716
[12]	Inoue A, Zhang T, Masumoto T 1989 Mater. Trans. JIM 30 965
[13]	Inoue A, Zhang T, Masumoto T 1990 Mater. Trans. JIM 31 425
[14]	Inoue A, Kato A, Zhang T 1991 Mater. Trans. JIM 32 609
[15]	Zhang T, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 1005
[16]	Inoue A, Zhang T 1996 Mater. Trans. JIM 37 185
[17]	Peker A, Johnson W L 1993 Appl. Phys. Lett. 63 2342
[18]	Inoue A Shinohara1 Y, Gook J S 1995 Mater. Trans. JIM 36 1427
[19]	Inoue A, Shen B L, Koshiba H, Kato H, Yavari A R 2003 Nature Mater. 2 661
[20]	Chang C T, Shen B L, Inoue A 2006 Appl. Phys. Lett. 88 011901
[21]	Inoue A, Shen B L, Koshiba H, Kato H, Yavari A R 2004 Acta Mater. 52 1631
[22]	Zhang T, Yang Q, Ji Y F, Li R, Pang S J, Wang J F, Xu T 2011 Chin. Sci. Bull. 56 3972
[23]	Inoue A, Shen B L, Chang C T 2006 Intermetallics 14 936
[24]	Wang J Li R, Hua N B, Zhang T 2011 J. Mater. Res. 26 2072
[25]	Dun T T, Liu H S, Shen B L 2012 J. Non-Cryst. Solids 358 3060
[26]	Wang J F, Wang L G, Guan S K, Zhu S J, Li R, Zhang T 2014 J. Alloys Compod. 617 7
[27]	Wang J F, Li R, Xiao R J, Xu T, Li R, Liu Z Q, Huang L, Hua N B, Li G, Li Y C, Zhang T 2011 Appl. Phys. Lett. 99 151911
[28]	Man Q K, Sun H J, Dong Y Q, Shen B L, Kimura H, Makino A, Inoue A 2010 Intermetallics 18 1876
[29]	Dong Y Q, Wang A D, Man Q K, Shen B L 2012 Intermetallics 23 63
[30]	Shen B L, Inoue A, Chang C T 2004 Appl. Phys. Lett. 85 4911
[31]	Lin C Y, Li M C, Chin T S 2007 J. Phys. D: Appl. Phys. 40 310
[32]	Yao J H, Wang J Q, Li Y 2008 Appl. Phys. Lett 92 251906
[33]	Yao J H, Yang H, Zhang J, Wang J Q, Li Y 2008 J. Mater. Res. 23 392
[34]	Chang Z Y, Huang X M, Chen L Y, Ge M Y, Jiang Q K, Nie X P, Jiang J Z 2009 Mater. Sci. Engineer. A 517 246
[35]	Park J M, Wang G, Li R, Mattern N, Eckert J, Kim D H 2010 Appl. Phys. Lett. 96 031905
[36]	Gu X J, Joseph P S, Shiflet G J 2007 J. Mater. Res. 22 344
[37]	Wei X Q 2017 M. S. Dissertation (Beijing: Beihang University) (in Chinese) [魏新权 2017 硕士学位论文 (北京: 北京航空航天大学)]
[38]	Schuh C A, Hufnagel T C, Ramamurty U 2007 Acta Mater. 55 4067
[39]	Liu Z Q, Wang R F, Qu R T, Zhang Z F 2014 J. Appl. Phys. 115 203513
[40]	Chen X Q, Niu H, Li D, Li Y 2011 Intermetallics 19 1275
[41]	Liu Y H, Wang G, Wang R J, Zhao D Q, Pan M X, Wang W H 2007 Science 315 1385
[42]	Lewandowski J J, Wang W H, Greer A L 2005 Phil. Mag. Lett. 85 77
[43]	Egami T, Poon S J, Zhang Z, Keppens V 2007 Phys. Rev. B 76 024203
[44]	Johnson W L, Samwer K 2005 Phys. Rev. Lett. 95 95501

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Vol. 66, Issue 17 - 2017-09-05

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