Research progress of high piezoelectric activity of potassium sodium niobate based lead-free ceramics

Xing Jie; Tan Zhi; Zheng Ting; Wu Jia-Gang; Xiao Ding-Quan; Zhu Jian-Guo

doi:10.7498/aps.69.20200288

Abstract

Due to excellent piezoelectric properties and electromechanical coupling properties, lead-based piezoelectric ceramics represented by lead zirconate titanate Pb(Zr_xTi_1–x)O₃ (PZT) are widely used in science and technology, industry, military and daily life. However, the content of Pb in PZT-based ceramics exceeds 60% (mass ratio), which will cause serious damage to human ecological environment in the process of their production, use and waste treatment. Therefore, the development of lead-free piezoelectric ceramics has become one of the hot research spots. Potassium sodium niobate (K_0.5Na_0.5)NbO₃ (KNN) lead-free piezoelectric ceramics are considered as one of the most promising material systems to substitute for lead-based piezoelectric ceramics because of their good piezoelectric properties and higher Curie temperature. Through many years of researches, the piezoelectric properties of modified KNN based lead-free piezoelectric ceramics have approached to or even exceeded those of some lead-based piezoelectric ceramics. Combining with our relevant work, we comprehensively review the research progress of high piezoelectric activity of KNN based lead-free piezoelectric ceramics, especially focus on the research progress of high-performance potassium sodium niobate lead-free piezoelectric ceramics, preparation technology and related theoretical mechanisms. The future research direction and prospect of KNN-based lead-free piezoelectric ceramics are also presented.

Keywords:

Authors and contacts

College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China

Corresponding author: Zhu Jian-Guo, nic0400@scu.edu.cn

FullText HTML : translate this paragraph

References

[1]	Xiao D Q 2011 J. Adv. Dielectr. 01 33 Google Scholar
[2]	Aksel E, Jones J L 2010 Sensors 10 1935 Google Scholar
[3]	Rödel J, Webber K G, Dittmer R, Jo W, Kimura M, Damjanovic D 2015 J. Eur Ceram. Soc. 35 1659 Google Scholar
[4]	Vats G, Vaish R 2014 Int. J. Appl. Ceram. Tec. 11 883 Google Scholar
[5]	Thong H C, Zhao C L, Zhou Z, Wu C F, Liu Y X, Du Z Z, Li J F, Gong W, Wang K 2019 Mater. Today 29 37 Google Scholar
[6]	Wang K, Malič B, Wu J G 2018 MRS Bull. 43 607 Google Scholar
[7]	Lv X., Zhu J G, Xiao D Q, Zhang X X, Wu J G 2020 Chem. Soc. Rev. 49 671 Google Scholar
[8]	Wu J G, Xiao D Q, Zhu J G 2015 Chem. Rev. 115 2559 Google Scholar
[9]	Gou Q, Wu J G, Li A Q, Wu B, Xiao D Q, Zhu J G 2012 J. Alloy. Comp. 521 4 Google Scholar
[10]	Saito Y, Takao H, Tani T, Nonoyama T, Takatori K, Homma T, Nagaya T, Nakamura M 2004 Nature 432 84 Google Scholar
[11]	Li P, Zhai J W, Shen Bo, Zhang S J, Li X L, Zhu F Y, Zhang X M 2018 Adv. Mater. 30 1705171 Google Scholar
[12]	Tao H, Wu H J, Liu Y, Zhang Y, Wu J G, Li F, Lyu X, Zhao C L, Xiao D Q, Zhu J G, Pennycook S J 2019 J. Am. Chem. Soc. 141 13987 Google Scholar
[13]	Egerton L, Dillond D M 1959 J. Am. Chem. Soc. 42 5 Google Scholar
[14]	Qin Y L, Zhang J L, Yao W Z, Lu C J, Zhang S J 2016 ACS Appl. Mater. Interfaces 8 7257 Google Scholar
[15]	Wang Y Y, Wu J G, Xiao D Q, Wu W J, Zhang B, Wu L, Zhu J G 2008 J. Am. Ceram. Soc. 91 2772 Google Scholar
[16]	Tan C K I, Shannigrahi S, Yao K, Ma J 2015 J. Electroceram. 35 19 Google Scholar
[17]	Pang X M, Qiu J H, Zhu K J 2014 J. Adv. Ceram. 3 147 Google Scholar
[18]	Wang Y Y, Wu J G, Xiao D Q, Zhu J M, Jin Y, Zhu J G, Yu P, Wu L, Li X 2007 J. Appl. Phys. 102 054101 Google Scholar
[19]	Wu W J, Wang Z, Xiao D Q, Ma J, Wu J G, Li J, Liang W F, Zhu J G 2013 Integr. Ferroelectr. 141 82 Google Scholar
[20]	Wu W J, Xiao D Q, Wu J G, Liang W F, Li J, Zhu J G 2011 J. Alloy. Comp. 509 L284 Google Scholar
[21]	Wu J G, Xiao D Q, Wang Y Y, Zhu J G, Yu P 2008 J. Appl. Phys. 103 024102 Google Scholar
[22]	Wu B, Ma J, Wu W J, Chen M, Ding Y C 2018 Ceram. Inter. 44 1172 Google Scholar
[23]	Wen Y, Fan G F, Hao M M, Wang Y J, Chen X, Zhang Q W, Lv W Z 2019 J. Electron. Mater. 49 931 Google Scholar
[24]	Xing J, Tan Z, Yuan J, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 RSC Adv. 6 57210 Google Scholar
[25]	Tang X, Chen T, Liu Y H, Zhang J W, Zhang T, Wang G C, Zhou J F 2016 J. Alloy. Comp. 672 277 Google Scholar
[26]	Yang Y, Wang H, Li Y, Zheng Q J, Liao J, Jie W J, Lin D M 2019 Dalton Trans. 48 10676 Google Scholar
[27]	Wu W J, Chen M, Wu B, Ding Y C, Liu C Q 2017 J. Alloy. Comp. 695 1175 Google Scholar
[28]	Lv X, Wu J G, Xiao D Q, Tao H, Yuan Y, Zhu J G, Wang X J, Lou X J 2015 Dalton Trans. 44 4440 Google Scholar
[29]	Zhong H Y, Xiao HNY, Jiao N, Guo Y P 2019 J. Am. Ceram. Soc. 102 6422 Google Scholar
[30]	Li F L, Tan Z, Xing J, Jiang L M, Wu B, Wu J G, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 8803 Google Scholar
[31]	Li F L, Gou Q, Xing J, Tan Z, Jiang L M, Xie L X, Wu J G, Zhang W, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 18090 Google Scholar
[32]	Lv X, Li Z Y, Wu J G, Xi J W, Gong M, Xiao D Q, Zhu J G 2016 Mater. Design 109 609 Google Scholar
[33]	Lv X, Wu J G, Yang S, Xiao D Q, Zhu J G 2016 ACS Appl. Mater. Interfaces 8 18943 Google Scholar
[34]	Zhou C M, Zhang J L, Yao W Z, Liu D K, He G H 2020 J. Alloy. Comp. 820 153411 Google Scholar
[35]	Wu B, Ma J, Gou Q, Wu W J, Chen M 2019 J. Am. Ceram. Soc. 103 1698 Google Scholar
[36]	Shi C Y, Ma J, Wu J, Chen K, Wu B 2020 Ceram. Inter. 46 7 Google Scholar
[37]	Wang X P, Wu J G, Xiao D Q, Zhu J G, Cheng X J, Zheng T, Zhang B Y, Lou X J, Wang X J 2014 J. Am. Chem. Soc. 136 2905 Google Scholar
[38]	Wang X P, Wu J G, Xiao D Q, Cheng X J, Zheng T, Zhang B Y, Lou X J, Zhu J G 2014 J. Mater. Chem. A 2 4122 Google Scholar
[39]	Tao H, Wu J G, Zheng T, Wang X J, Lou X J 2015 J. Appl. Phys. 118 044102 Google Scholar
[40]	Zhou J S, Wang K, Yao F Z, Zheng T, Wu J G, Xiao D Q, Zhu J G, Li J F 2015 J. Mater. Chem. C 3 8780 Google Scholar
[41]	Xing J, Tan Z, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 J. Appl. Phys. 119 034101 Google Scholar
[42]	Zheng T, Wu H J, Yuan Y, Lv X, Li Q, Men T L, Zhao C L, Xiao D Q, Wu J G, Wang K, Li J F, Gu Y L, Zhu J G, Pennycook S J 2017 Energy Environ. Sci. 10 528 Google Scholar
[43]	Wu B, Wu H J, Wu J G, Xiao D Q, Zhu J G, Pennycook S J 2016 J. Am. Chem. Soc. 138 15459 Google Scholar
[44]	Yang W W, Li P, Li F, Liu X, Shen B, Zhai J W 2019 Ceram. Inter. 45 2275 Google Scholar
[45]	Xu K, Li J, Lv X, Wu J G, Zhang X X, Xiao D Q, Zhu J G 2016 Adv. Mater. 28 8519 Google Scholar
[46]	Wu B, Ma J, Wu W J, Chen M 2020 J. Mater. Chem. C 8 2838 Google Scholar
[47]	Yang W W, Li P, Wu S H, Li F, Shen B, Zhai J W 2020 Ceram. Inter. 46 6 Google Scholar
[48]	Liu Q, Zhang Y C, Gao J, Zhou Z, Wang H, Wang K, Zhang X W, Li L T, Li J F 2018 Energy Environ. Sci. 11 3531 Google Scholar
[49]	Feng W, Cen Z Y, Liang S Y, Luo B C, Zhang Y, Zhen Y C, Wang X H, Li L T 2019 J. Alloy. Comp. 786 498 Google Scholar
[50]	Hreščak J, Dražić G, Deluca M, Arčon I, Kodre A, Dapiaggi M, Rojac T, Malič B, Bencan A 2017 J. Eur Ceram. Soc. 37 2073 Google Scholar
[51]	Cen Z Y, Yu Y, Zhao P Y, Chen L L, Zhu C Q, Li L T, Wang X H 2019 J. Mater. Chem. C 7 1379 Google Scholar
[52]	Sun X X, Zhang J W, Lv X, Zhang X X, Liu Y, Li F, Wu J G 2019 J. Mater. Chem. A 7 16803 Google Scholar
[53]	Qin Y L, Zhang J L, Tan Y Q, Yao W Z, Wang C L, Zhang S J 2014 J. Eur Ceram. Soc. 34 4177 Google Scholar
[54]	Yao W Z, Zhang J L, Wang X M, Zhou C M, Sun X, Zhan J 2019 J. Eur Ceram. Soc. 39 287 Google Scholar
[55]	Zhou C M, Zhang J L, Yao W Z, Wang X M, Liu D K, Sun X 2018 J. Appl. Phys. 124 164101 Google Scholar
[56]	López-Juárez R, Novelo-Peralta O, González-García F, Rubio-Marcos F, Villafuerte-Castrejón M-E 2011 J. Eur Ceram. Soc. 31 1861 Google Scholar
[57]	Xing J, Tan Z, Chen X Y, Jiang L M, Wang W W, Deng X, Wu B, Wu J G, Xiao D Q, Zhu J G 2019 Inorg. Chem. 58 428 Google Scholar
[58]	Huan Y, Wei T, Wang Z X, Lei Y C, Chen F L, Wang X H 2019 J. Eur Ceram. Soc. 39 1002 Google Scholar
[59]	Ding Y, Zheng T, Zhao C L, Wu J G 2019 J. Appl. Phys. 126 124101 Google Scholar
[60]	Zhao C L, Wu B, Wang K, Li J F, Xiao D Q, Zhu J G, Wu J G 2018 J. Mater. Chem. A 6 23736 Google Scholar
[61]	Qin Y L, Zhang J L, Gao Y, Tan Y Q, Wang C L 2013 J. Appl. Phys. 113 204107 Google Scholar
[62]	Liu Q, Zhang Y C, Zhao L, Gao J, Zhou Z, Wang K, Zhang X W, Li L T, Li J F 2018 J. Mater. Chem. C 6 10618 Google Scholar
[63]	Liu Q, Li J F, Zhao L, Zhang Y C, Gao J, Sun W, Wang K, Li L T 2018 J. Mater. Chem. C 6 1116 Google Scholar
[64]	Fu J, Zuo R Z, Qi H, Zhang C, Li J F, Li L T 2014 Appl. Phys. Lett. 105 242903 Google Scholar
[65]	Zhou C M, Zhang J L, Yao W Z, Liu D K, Su W B 2019 Scripta Mater. 162 86 Google Scholar
[66]	Li P, Huan Y, Yang W W, Zhu F Y, Li X L, Zhang X M, Shen B, Zhai J W 2019 Acta Mater. 165 486 Google Scholar
[67]	Liu D K, Zhang X C, Su W B, Wang X M, Yao W Z, Zhou C M, Zhang J L 2019 J. Alloy. Comp. 779 800 Google Scholar
[68]	Lv X, Wu J G 2019 J. Mater. Chem. C 7 2037 Google Scholar
[69]	Zhang N, Zhao C, Wu J G 2019 Ceram. Inter. 45 24827 Google Scholar
[70]	Xing J, Tan Z, Xie L X, Jiang L M, Yuan J, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2018 J. Am. Ceram. Soc. 101 1632 Google Scholar
[71]	Tao H, Wu J G, Wang H 2016 J. Alloy. Comp. 684 217 Google Scholar
[72]	Wang T, Wu C, Xing J, Wu J G, Li Chen B W, Xu X Y, Wang K, Zhu J G 2019 J. Am. Ceram. Soc. 102 6126 Google Scholar
[73]	Cen Z Y, Wang X H, Huan Y, Li L T 2018 J. Am. Ceram. Soc. 101 2391 Google Scholar
[74]	Jiang L M, Tan Z, Xing J, Wu J G, Chen Q, Zhang W, Xiao D Q, Zhu J G 2016 J. Mater. Sci.- Mater. El. 27 9812 Google Scholar
[75]	Wang X P, Wu J G, Lv X, Tao H, Cheng X J, Zheng T, Zhang B Y, Xiao D Q, Zhu J G 2014 J. Mater. Sci.- Mater. El. 25 3219 Google Scholar
[76]	Wang Z, Xiao D Q, Wu J G, Xiao M, Li F X, Zhu J G, Damjanovic D 2014 J. Am. Ceram. Soc. 97 688 Google Scholar
[77]	Feng S S, Xiao D Q, Wu J G, Xiao M, Zhu J G 2015 J. Alloy. Comp. 619 560 Google Scholar
[78]	Cheng X J, Wu J G, Wang X P, Zhang B Y, Lou X J, Wang X J, Xiao D Q, Zhu J G 2013 ACS Appl. Mater. Interfaces 5 10409 Google Scholar
[79]	Gou Q, Zhu J G, Wu J G, Li F L, Jiang L M, Xiao D Q 2018 J. Alloy. Comp. 730 311 Google Scholar
[80]	Cheng X J, Wu J G, Lou X J, Wang X J, Wang X P, Xiao D Q, Zhu J G 2014 ACS Appl. Mater. Interfaces 6 750 Google Scholar
[81]	Gou Q, Xiao D Q, Wu B, Xiao M, Feng S S, Ma Zhao D D, Wu J G, Zhu J G 2015 RSC Adv. 5 30660 Google Scholar
[82]	Ma Q, Wan B B, Cheng L J, Liu S J, Liu F S 2016 J. Electroceram. 36 30 Google Scholar
[83]	Kim J H, Kim J S, Han S H, Kang H W, Lee H G, Cheon C I 2016 Ceram. Inter. 42 5226 Google Scholar
[84]	Sumang R, Wicheanrat C, Bongkarn T, Maensiri S 2015 Ceram. Inter. 41 S136 Google Scholar
[85]	Zhang S J, Xia R, Hao H, Liu H X, Shrout T R 2008 Appl. Phys. Lett. 92 152904 Google Scholar
[86]	Yao F Z, Wang K, Jo W, Webber K G, Comyn T P, Ding J X, Xu B, Cheng L Q, Zheng M P, Hou Y D, Li J F 2016 Adv. Funct. Mater. 26 1217 Google Scholar
[87]	Lv X, Wu J G, Zhu J G, Xiao D Q 2018 Phys. Chem. Chem. Phys. 20 20149 Google Scholar
[88]	Zhang M H, Wang K, Du Y J, Dai G, Sun W, Li G, Hu D, Thong H C, Zhao C L, Xi X Q, Yue Z X, Li J F 2017 J. Am. Chem. Soc. 139 3889 Google Scholar
[89]	Tao H, Zhao C L, Zhang R, Wu J G 2019 J. Alloy. Comp. 795 401 Google Scholar
[90]	Cen Z Y, Feng W, Zhao P Y, Chen L L, Zhu C Q, Yu Y, Li L T, Wang X H 2018 J. Am. Ceram. Soc. 102 2675 Google Scholar
[91]	Huang Y L, Zhao C L, Wu B, Wu J G 2019 J. Am. Ceram. Soc. 102 2648 Google Scholar
[92]	Zheng T, Wu J G 2020 Acta Mater. 182 1 Google Scholar
[93]	Ramajo L, Rubio-Marcos F, Del Campo A, Fernández J F, Castro M S, Parra R 2015 J. Mater. Sci.- Mater. El. 26 9402 Google Scholar
[94]	Liu W L, Tan G Q, Xiong P, Xue X, Hao H F, Ren H J 2014 J. Mater. Sci.- Mater. El. 25 2348 Google Scholar
[95]	Hao H F, Tan G Q, Ren H J, Xia A, Xiong P 2014 Ceram. Inter. 40 9485 Google Scholar
[96]	Gu Q L, Sun Q M, Zhu K J, Liu J S, Qiu J H 2017 Ceram. Inter. 43 1135 Google Scholar
[97]	Cheng L Q, Wang K, Li J F 2015 Mater. Lett. 138 128 Google Scholar
[98]	Li Y M, Wang J S, Liao R H, Huang D, Jiang X P 2010 J. Alloy. Compd. 496 282 Google Scholar
[99]	Kumar P, Pattanaik M, Sonia 2013 Ceram. Inter. 39 65 Google Scholar
[100]	Haugen A B, Madaro F, Bjørkeng L-P, Grande T, Einarsrud M A 2015 J. Eur Ceram. Soc. 35 1449 Google Scholar
[101]	Jiang C Y, Tian X X, Shi G D 2016 Adv. Intell. Sys. Res. 136 7 Google Scholar
[102]	Yokouchi Y, Maeda T, Bornmann P, Hemsel T, Morita T 2013 Jpn. J. Appl. Phys. 52 07HB03 Google Scholar
[103]	Wang C, Fang B J, Qu Y H, Chen Z H, Zhang S, Ding J N 2020 J. Alloy. Compd. 832 153043 Google Scholar
[104]	Jaeger R E, Egerton L 1962 J. Am. Ceram. Soc. 45 5 Google Scholar
[105]	Li M Y, Chan N Y, Wang D Y 2017 J. Am. Ceram. Soc. 100 2984 Google Scholar
[106]	Feizpour M, Barzegar Bafrooei H, Hayati R, Ebadzadeh T 2014 Ceram. Inter. 40 871 Google Scholar
[107]	Ma J Z, Li H Y, Wang H J, Lin C, Wu X, Lin T F, Zheng X H, Yu X 2019 J. Eur Ceram. Soc. 39 986 Google Scholar
[108]	Chi M S, Ma W B, Guo J D, Wu J Q, Li T T, Wang S H, Zhang P F 2019 J. Mater. Sci.- Mater. El. 39 986 Google Scholar
[109]	Yu Z D, Chen X M, Su Y L, Lian H L, Lu J B, Zhou J P, Liu P 2019 J. Mater. Sci. 54 13457 Google Scholar
[110]	Li J F, Wang K, Zhang B P, Zhang L M 2006 J. Am. Ceram. Soc. 89 706 Google Scholar
[111]	Cen Z Y, Li L T, Wang X H 2019 J. Alloy. Comp. 797 1115 Google Scholar
[112]	Li H, Gong D W, Yang W L, Zhou Z X 2012 J. Mater. Sci. 48 1396 Google Scholar
[113]	Liao Y, Wang D M, Wang H, Wang T, Wei X H, Zheng Q J, Jie W J, Lin D M 2019 Ceram. Inter. 45 2644 Google Scholar
[114]	Wu B, Yin J, Lv X, Xiao D Q, Zhu J G, Wu J G 2019 J. Appl. Phys. 125 082526 Google Scholar
[115]	Liao Y, Wang D M, Wang H, Zhou L X, Zheng Q J, Lin D M 2020 Dalton Trans. 49 1311 Google Scholar
[116]	Comes R, Lambert M, Guinier A 1968 Solid State Commun. 6 715 Google Scholar
[117]	Cohen R E 1992 Nature 358 136 Google Scholar
[118]	Atern E A, Yacoby Y 1996 J. Phys. Chem. Solids 57 1449 Google Scholar
[119]	Rytz D, Höchli U T, Bilz H 1980 Phys. Rev. B 22 359 Google Scholar
[120]	Shuvaeva V A, Yanagi K, Yagi K, Sakaue K, Terauchi H 1998 Solid State Commun 106 335 Google Scholar
[121]	Devonshire A F 1949 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 40 1040 Google Scholar
[122]	Devonshire A F 1951 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 42 1065 Google Scholar
[123]	Cochran W 1959 Phys. Rev. Lett. 3 412 Google Scholar
[124]	Damjanovic D, Demartin 1997 J. Phys.-Condens. Mat. 9 4943 Google Scholar
[125]	谭智 2019 博士学位论文 (成都: 四川大学) Tan Z 2019 Ph. D. Dissertation (Chengdu: Sichuan University) (in Chinese)
[126]	Tellier J, Malic B, Dkhil B, Jenko D, Cilensek J, Kosec M 2009 Solid State Sci. 11 320 Google Scholar
[127]	Baker D W, Thomas P A, Zhang N, Glazer A M 2009 Appl. Phys. Lett. 95 091903 Google Scholar
[128]	Guo Y P, Kakimoto K, Ohsato H 2004 Appl. Phys. Lett. 85 4121 Google Scholar
[129]	Yang D, Wei L L, Chao X L, Yang Z P, Zhou X Y 2016 Phys. Chem. Chem. Phys. 18 7702 Google Scholar
[130]	Wu Z G, Cohen R E 2005 Phys. Rev. Lett. 95 037601 Google Scholar
[131]	Shannon R D 1976 Acta Crystallogra. A 32 751 Google Scholar
[132]	Tan Z, Xing J, Jiang L M, Zhu J G, Wu B 2017 Front. Mater. Sci. 11 344 Google Scholar
[133]	Ke S M, Huang H T, Fan H Q, Lee H K, Zhou L M, Mai Y M 2012 Appl. Phys. Lett. 101 082901 Google Scholar
[134]	Fu H X, Cohen R E 2000 Nature 403 281 Google Scholar
[135]	Suewattana M, Singh D J 2010 Phys. Rev. B 82 014114 Google Scholar
[136]	Voas B K, Usher T M, Liu X, Li S, Jones J L, Tan X, Cooper V R, Beckman S P 2014 Phys. Rev. B 90 024105 Google Scholar
[137]	Matsumoto K, Hiruma Y, Nagata H, Takenaka T 2008 Ceram. Inter. 34 787 Google Scholar
[138]	Tan Z, Peng Y T, An J, Zhang Q M, Zhu J G 2019 J. Am. Ceram. Soc. 102 5262 Google Scholar
[139]	Peng Y, T Tan Z, An J, Zhu J G, Zhang Q M 2019 J. Eur. Ceram. Soc. 39 5252 Google Scholar
[140]	Li C W, Xu X, Gao Q, Lu Z L 2019 Ceram. Int. 45 11092 Google Scholar
[141]	Liu S Y, Liu S, Li D J, Shen Y, Dang H, Liu Y, Xue W, Wang S 2014 J. Am. Ceram. Soc 97 4019 Google Scholar
[142]	Li Q, Zhang R, Lv T Q, Zheng L M 2015 Chin. Phys. B 24 053101 Google Scholar
[143]	Yang D, Chai Q Z, Wei L L, Chao X L, Yang Z P 2017 Phys. Chem. Chem. Phys. 19 27368 Google Scholar

Cited By

图 1 (a) KNN基无铅压电陶瓷d₃₃的历史演变图; (b) KNN基无铅压电陶瓷与铅基陶瓷d₃₃对比图^{[11,12,34,37,43,45]}

Figure 1. (a) Historical evolution in d₃₃ values of KNN-based ceramics as a function of time; (b) comparison of d₃₃ values among KNN-based ceramics and PZT materials^{[11,12,34,37,43,45]}.

DownLoad: Full-Size Img PowerPoint

图 2 (a)正交相(K_0.5Na_0.5NbO₃陶瓷^[56,61]); (b)室温下O-T相界(KNNL-BZ-BNT陶瓷体系^[62], KNNSL-BNZ-BZ-MnO₂陶瓷体系^[63]); (c)室温下R-T/R-O-T相界KNN基陶瓷的畴结构(KNNS-BF-BNZ陶瓷体系^[43], KNNS-BNZ-BZ陶瓷体系^[34])

Figure 2. Domain structures of KNN-based ceramcis with different phase boundaries at room temperature: (a) Orthorhombic (K_0.5Na_0.5NbO₃ ceramics^[56,61]); (b) O-T phase boundaries (KNNL-BZ-BNT ceramics^[62], KNNSL-BNZ-BZ-MnO₂ ceramics^[63]); (c) R-T/R-O-T phase boundaries (KNNS-BF-BNZ ceramics^[43], KNNS-BNZ-BZ ceramics^[34]).

DownLoad: Full-Size Img PowerPoint

图 3 KNN基无铅压电陶瓷d₃₃与T_C对比图^[12,15-47]

Figure 3. Comparison of d₃₃ and T_C values of KNN-based ceramics^[12,15-47].

DownLoad: Full-Size Img PowerPoint

图 4 根据文献[120]重画的KNbO₃中Nb原子位置在(001)平面的投影示意图

Figure 4. Projections of real Nb off-center displacements on the (001) plane redrawn from the Ref. [120].

DownLoad: Full-Size Img PowerPoint

图 5 B位原子在单四方相与两相共存时沿[$ \overline{1} 01$]方向的能量分布示意图^[125]

Figure 5. Energy distribution for B-site atom in single tetragonal phase and two-phase coexistence along [$ \overline{1} 01$] direction^[125].

DownLoad: Full-Size Img PowerPoint

表 1 室温下具有O-T相界的KNN压电陶瓷性能

Table 1. Properties of KNN ceramics with O-T phase boundary at room temperature.

Material system	d₃₃/pC·N^–1	k_p	T_C/℃
KNLANT^[15]	252	0.454	438
KNLN-BCZT^[16]	180	0.34	425
KNN-KLN^[17]	121	0.39	—
KNLN-AS^[18]	230	0.39	430
KNLN-BNCT^[19]	262	0.36	～400
KNN-BC^[20]	165	0.40	～390
KNN-LS^[21]	280	0.494	364
KNN-BLZ^[22]	265	0.365	364
KNN-BC-BNH^[23]	272	0.47	333

DownLoad: CSV

表 2 室温下具有R-O-T相界的KNN压电陶瓷的性能

Table 2. Properties of KNN ceramics with R-O-T phase boundary at room temperature.

Material system	d₃₃/pC·N^–1	k_p	T_C /℃
KNN-BNZ-BG^[24]	312	0.44	341
KNN-BZ-BNZ^[25]	345	0.50	～260
KNN-NS-BNKZH^[26]	452	0.63	～270
KNNS-BNCZ^[27]	415	0.46	245
KNNTS-BNKZ^[28]	400	0.46	240
KNN-BNZN^[29]	318 ± 10	—	360
KNNS-BKZH^[30]	451	0.52	258
KNNS-BLKZ^[31]	385	—	245
KNNS-SZ-BNH^[32]	470 ± 5	0.51 ± 0.02	244
KNNS-BS-BNZ^[33]	～480	—	～225
KNNS-BNZ-BZ^[34]	610	0.58	241
KNNS-BNKZ-Fe-AS^[12]	650	—	～180

DownLoad: CSV

表 3 室温下具有R-T相界的KNN压电陶瓷的性能

Table 3. Properties of KNN ceramics with R-T phase boundary at room temperature.

Material system	d₃₃ /pC·N^–1	k_p	T_C/℃
KNNS-BNZSn^[35]	465	0.51	240
KNNS-BZH^[36]	410	—	255
KNNS-BNKZ^[37]	490	0.46	227
KNNTS-BNKZ^[38]	460	0.40	～220
KNNS-BNH^[39]	419	0.45	242
KNNS-BKZS^[40]	430	—	243
KNNS-BNLCZ^[41]	485	0.48	227
KNNS-BNKH^[42]	525	—	～210
KNNS-BF-BNZ^[43]	550	—	237
KNNS-CZ-BKHT-MnO₂^[44]	425	0.49	215
KNNS-BZ-BKH^[45]	570 ± 10	—	～190
KNNS-BNZ-BF^[46]	511	0.515	269
KNANS-BNZ^[47]	440	0.50	250

DownLoad: CSV

表 4 KNN基无铅压电陶瓷压电常数与畴结构尺寸

Table 4. Piezoelectric constant of KNN ceramics with domain size.

Material system	d₃₃ or $ {d}_{33}^{*} $	Domain size
KNNS-SZ-BAZ^[52]	487 pC/N	30—65 nm, 65—160 nm, 30—45 nm
KNNS-BZ-BNH^[48]	600 pm/V	10—100 nm
KNNS-BNKH^[42]	525 pC/N	10—30 nm
KNNS-BNKZ-Fe-AS^[12]	(650 ± 20) pC/N	2 nm
KNNS-BNZ-BZ^[34]	610 pC/N	50—70 nm
KNNT-BNKZ-CZ^[51]	482 pm/V	60 nm
KNNS-BZ-BNZ^[65]	300 pC/N	150 nm—1.0 μm
KNNS-CZ-BKH^[66]	550 pC/N	30—230 nm
KNNS-BNH^[67]	512 pC/N	100 nm
KNNS-SZ-BNZ^[68]	450 pC/N	50—200 nm
KNLNTS^[54]	455 pC/N	110—310 nm
KNNS-BNZ-BF^[46]	510 pC/N	< 1 μm
KNN-BNZ-MnO₂-Sb₂O₃^[69]	318 pC/N	< 1 μm
KNN-BI-BNZ^[57]	317 pC/N	～200 nm
KNNdNS-BNZ^[70]	400 pC/N	～ 1 μm

DownLoad: CSV

表 5 同时具有高压电性能和高居里温度的KNN陶瓷体系

Table 5. The KNN-based ceramics with high piezoelectric constant and high Curie temperature.

Material system	d₃₃ /pC·N^–1	T_C/℃
KNN-BNH^[71]	385	315
KNN-BNZ-LF^[72]	345	314
KNN-BNZ-MnO₂^[73]	300	345
KNN-BNZ-BG^[24]	312	341
KNN-BNZ-BA^[74]	355	335
KNN-BAZ^[75]	347	318
KNN-BNZ^[76]	360	329
KNN-BKZ-BZ^[77]	305	～300
KNLNS-BS^[78]	325	358
KNN-BNZS^[79]	350	315
KNN-BS-BNKLZ^[80]	366	335
KNN-BNT-BNZ^[81]	318	326
KNN-BNZ-BI^[57]	317	336

DownLoad: CSV

表 6 温度稳定性高的KNN陶瓷体系的压电常数以及变化量

Table 6. Comparison of piezoelectric constant and variation among KNN-based ceramics.

	d₃₃/pC·N^–1	d₃₃ variation/%	$ {d}_{33}^{*} $/pm·V^–1	$ {d}_{33}^{*} $ variation/%
KNLNT-CZ^[86]	—	—	—	almost unchanged @140 ℃
KNN-BNZ-LF^[72]	345	—	420	8%@100 ℃
KNNT-BNKZ-SZ-MnO₂^[49]	—	—	400	10%@180 ℃
KNNT-BNKZ-CZ-MnO₂^[51]	—	—	482	10%@120 ℃
KNNS-BNZ-SZ^[87]	390	—	—	13%@180 ℃
KNN-BLT-BZ-MnO₂^[88]	—	—	470	8.5%@100 ℃, 21.2%@170 ℃
KNNS-BZ-BNZ^[65]	300	10@100 ℃	—	—
KNNS-(BHo)NHf^[89]	—	—	～386	almost unchanged @140 ℃
KNNT-BNZ-CZ^[90]	—	—	502	10%@135 ℃
KNNS-BNKH^[42]	525	—	460	10%@80 ℃
KNN-BZ-BNH-MnO₂^[91]	300	15@120 ℃	540 ± 10	5%@100 ℃
KNN-BNH-BF-MnO₂^[92]	450	—	—	28%@160 ℃
KNN-BNZ-MnO₂-Sb₂O₃^[69]	318	—	—	9%@170 ℃
KNNS-BZH-BNZ^[36]	410	—	441	2.5%@100 ℃, 16.1%@180 ℃
注: 16.1%@180 ℃表示到180 ℃性能下降16.1%.

DownLoad: CSV

表 7 处于6配位时的离子半径表^[131]

Table 7. The ionic radii in six-fold coordination^[131].

	Nb⁵⁺	Ta⁵⁺	Zr⁴⁺	Hf⁴⁺	Sn⁴⁺	Ti⁴⁺	Sb⁵⁺	Sb³⁺	Ga³⁺
离子半径/Å	0.64	0.64	0.72	0.71	0.69	0.605	0.60	0.76	0.62

DownLoad: CSV

表 8 不同结构下原子内坐标随应变的梯度, 注意O_I位于Bmm2不包含Nb原子的(010)平面, KNN中O_I,1和O_I,2沿a方向分别靠近K和Na原子^[138]

Table 8. Internal atomic coordinate gradients as a function of strains in different structure, noted that O_I is located at the (010) plane without Nb atoms in Bmm2, O_I,1 and O_I,2 are close to K and Na along a axis, respectively^[139].

		K	Nb		O_Ⅱ		O_Ⅰ
KN	∂u₃/∂η₃	0.108	0.166		–0.092		–0.091
KN	∂u₁/∂η₅	0.115	0.210		–0.151		–0.024

		K	Na	Nb	O_Ⅱ	O_I,1	O_I,2
KNN	∂u₃/∂η₃	0.103	0.542	0.125	–0.158	–0.125	–0.135
KNN	∂u₁/∂η₅	0.094	0.828	0.194	–0.235	–0.061	–0.309

DownLoad: CSV

[1]	Xiao D Q 2011 J. Adv. Dielectr. 01 33 Google Scholar
[2]	Aksel E, Jones J L 2010 Sensors 10 1935 Google Scholar
[3]	Rödel J, Webber K G, Dittmer R, Jo W, Kimura M, Damjanovic D 2015 J. Eur Ceram. Soc. 35 1659 Google Scholar
[4]	Vats G, Vaish R 2014 Int. J. Appl. Ceram. Tec. 11 883 Google Scholar
[5]	Thong H C, Zhao C L, Zhou Z, Wu C F, Liu Y X, Du Z Z, Li J F, Gong W, Wang K 2019 Mater. Today 29 37 Google Scholar
[6]	Wang K, Malič B, Wu J G 2018 MRS Bull. 43 607 Google Scholar
[7]	Lv X., Zhu J G, Xiao D Q, Zhang X X, Wu J G 2020 Chem. Soc. Rev. 49 671 Google Scholar
[8]	Wu J G, Xiao D Q, Zhu J G 2015 Chem. Rev. 115 2559 Google Scholar
[9]	Gou Q, Wu J G, Li A Q, Wu B, Xiao D Q, Zhu J G 2012 J. Alloy. Comp. 521 4 Google Scholar
[10]	Saito Y, Takao H, Tani T, Nonoyama T, Takatori K, Homma T, Nagaya T, Nakamura M 2004 Nature 432 84 Google Scholar
[11]	Li P, Zhai J W, Shen Bo, Zhang S J, Li X L, Zhu F Y, Zhang X M 2018 Adv. Mater. 30 1705171 Google Scholar
[12]	Tao H, Wu H J, Liu Y, Zhang Y, Wu J G, Li F, Lyu X, Zhao C L, Xiao D Q, Zhu J G, Pennycook S J 2019 J. Am. Chem. Soc. 141 13987 Google Scholar
[13]	Egerton L, Dillond D M 1959 J. Am. Chem. Soc. 42 5 Google Scholar
[14]	Qin Y L, Zhang J L, Yao W Z, Lu C J, Zhang S J 2016 ACS Appl. Mater. Interfaces 8 7257 Google Scholar
[15]	Wang Y Y, Wu J G, Xiao D Q, Wu W J, Zhang B, Wu L, Zhu J G 2008 J. Am. Ceram. Soc. 91 2772 Google Scholar
[16]	Tan C K I, Shannigrahi S, Yao K, Ma J 2015 J. Electroceram. 35 19 Google Scholar
[17]	Pang X M, Qiu J H, Zhu K J 2014 J. Adv. Ceram. 3 147 Google Scholar
[18]	Wang Y Y, Wu J G, Xiao D Q, Zhu J M, Jin Y, Zhu J G, Yu P, Wu L, Li X 2007 J. Appl. Phys. 102 054101 Google Scholar
[19]	Wu W J, Wang Z, Xiao D Q, Ma J, Wu J G, Li J, Liang W F, Zhu J G 2013 Integr. Ferroelectr. 141 82 Google Scholar
[20]	Wu W J, Xiao D Q, Wu J G, Liang W F, Li J, Zhu J G 2011 J. Alloy. Comp. 509 L284 Google Scholar
[21]	Wu J G, Xiao D Q, Wang Y Y, Zhu J G, Yu P 2008 J. Appl. Phys. 103 024102 Google Scholar
[22]	Wu B, Ma J, Wu W J, Chen M, Ding Y C 2018 Ceram. Inter. 44 1172 Google Scholar
[23]	Wen Y, Fan G F, Hao M M, Wang Y J, Chen X, Zhang Q W, Lv W Z 2019 J. Electron. Mater. 49 931 Google Scholar
[24]	Xing J, Tan Z, Yuan J, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 RSC Adv. 6 57210 Google Scholar
[25]	Tang X, Chen T, Liu Y H, Zhang J W, Zhang T, Wang G C, Zhou J F 2016 J. Alloy. Comp. 672 277 Google Scholar
[26]	Yang Y, Wang H, Li Y, Zheng Q J, Liao J, Jie W J, Lin D M 2019 Dalton Trans. 48 10676 Google Scholar
[27]	Wu W J, Chen M, Wu B, Ding Y C, Liu C Q 2017 J. Alloy. Comp. 695 1175 Google Scholar
[28]	Lv X, Wu J G, Xiao D Q, Tao H, Yuan Y, Zhu J G, Wang X J, Lou X J 2015 Dalton Trans. 44 4440 Google Scholar
[29]	Zhong H Y, Xiao HNY, Jiao N, Guo Y P 2019 J. Am. Ceram. Soc. 102 6422 Google Scholar
[30]	Li F L, Tan Z, Xing J, Jiang L M, Wu B, Wu J G, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 8803 Google Scholar
[31]	Li F L, Gou Q, Xing J, Tan Z, Jiang L M, Xie L X, Wu J G, Zhang W, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 18090 Google Scholar
[32]	Lv X, Li Z Y, Wu J G, Xi J W, Gong M, Xiao D Q, Zhu J G 2016 Mater. Design 109 609 Google Scholar
[33]	Lv X, Wu J G, Yang S, Xiao D Q, Zhu J G 2016 ACS Appl. Mater. Interfaces 8 18943 Google Scholar
[34]	Zhou C M, Zhang J L, Yao W Z, Liu D K, He G H 2020 J. Alloy. Comp. 820 153411 Google Scholar
[35]	Wu B, Ma J, Gou Q, Wu W J, Chen M 2019 J. Am. Ceram. Soc. 103 1698 Google Scholar
[36]	Shi C Y, Ma J, Wu J, Chen K, Wu B 2020 Ceram. Inter. 46 7 Google Scholar
[37]	Wang X P, Wu J G, Xiao D Q, Zhu J G, Cheng X J, Zheng T, Zhang B Y, Lou X J, Wang X J 2014 J. Am. Chem. Soc. 136 2905 Google Scholar
[38]	Wang X P, Wu J G, Xiao D Q, Cheng X J, Zheng T, Zhang B Y, Lou X J, Zhu J G 2014 J. Mater. Chem. A 2 4122 Google Scholar
[39]	Tao H, Wu J G, Zheng T, Wang X J, Lou X J 2015 J. Appl. Phys. 118 044102 Google Scholar
[40]	Zhou J S, Wang K, Yao F Z, Zheng T, Wu J G, Xiao D Q, Zhu J G, Li J F 2015 J. Mater. Chem. C 3 8780 Google Scholar
[41]	Xing J, Tan Z, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 J. Appl. Phys. 119 034101 Google Scholar
[42]	Zheng T, Wu H J, Yuan Y, Lv X, Li Q, Men T L, Zhao C L, Xiao D Q, Wu J G, Wang K, Li J F, Gu Y L, Zhu J G, Pennycook S J 2017 Energy Environ. Sci. 10 528 Google Scholar
[43]	Wu B, Wu H J, Wu J G, Xiao D Q, Zhu J G, Pennycook S J 2016 J. Am. Chem. Soc. 138 15459 Google Scholar
[44]	Yang W W, Li P, Li F, Liu X, Shen B, Zhai J W 2019 Ceram. Inter. 45 2275 Google Scholar
[45]	Xu K, Li J, Lv X, Wu J G, Zhang X X, Xiao D Q, Zhu J G 2016 Adv. Mater. 28 8519 Google Scholar
[46]	Wu B, Ma J, Wu W J, Chen M 2020 J. Mater. Chem. C 8 2838 Google Scholar
[47]	Yang W W, Li P, Wu S H, Li F, Shen B, Zhai J W 2020 Ceram. Inter. 46 6 Google Scholar
[48]	Liu Q, Zhang Y C, Gao J, Zhou Z, Wang H, Wang K, Zhang X W, Li L T, Li J F 2018 Energy Environ. Sci. 11 3531 Google Scholar
[49]	Feng W, Cen Z Y, Liang S Y, Luo B C, Zhang Y, Zhen Y C, Wang X H, Li L T 2019 J. Alloy. Comp. 786 498 Google Scholar
[50]	Hreščak J, Dražić G, Deluca M, Arčon I, Kodre A, Dapiaggi M, Rojac T, Malič B, Bencan A 2017 J. Eur Ceram. Soc. 37 2073 Google Scholar
[51]	Cen Z Y, Yu Y, Zhao P Y, Chen L L, Zhu C Q, Li L T, Wang X H 2019 J. Mater. Chem. C 7 1379 Google Scholar
[52]	Sun X X, Zhang J W, Lv X, Zhang X X, Liu Y, Li F, Wu J G 2019 J. Mater. Chem. A 7 16803 Google Scholar
[53]	Qin Y L, Zhang J L, Tan Y Q, Yao W Z, Wang C L, Zhang S J 2014 J. Eur Ceram. Soc. 34 4177 Google Scholar
[54]	Yao W Z, Zhang J L, Wang X M, Zhou C M, Sun X, Zhan J 2019 J. Eur Ceram. Soc. 39 287 Google Scholar
[55]	Zhou C M, Zhang J L, Yao W Z, Wang X M, Liu D K, Sun X 2018 J. Appl. Phys. 124 164101 Google Scholar
[56]	López-Juárez R, Novelo-Peralta O, González-García F, Rubio-Marcos F, Villafuerte-Castrejón M-E 2011 J. Eur Ceram. Soc. 31 1861 Google Scholar
[57]	Xing J, Tan Z, Chen X Y, Jiang L M, Wang W W, Deng X, Wu B, Wu J G, Xiao D Q, Zhu J G 2019 Inorg. Chem. 58 428 Google Scholar
[58]	Huan Y, Wei T, Wang Z X, Lei Y C, Chen F L, Wang X H 2019 J. Eur Ceram. Soc. 39 1002 Google Scholar
[59]	Ding Y, Zheng T, Zhao C L, Wu J G 2019 J. Appl. Phys. 126 124101 Google Scholar
[60]	Zhao C L, Wu B, Wang K, Li J F, Xiao D Q, Zhu J G, Wu J G 2018 J. Mater. Chem. A 6 23736 Google Scholar
[61]	Qin Y L, Zhang J L, Gao Y, Tan Y Q, Wang C L 2013 J. Appl. Phys. 113 204107 Google Scholar
[62]	Liu Q, Zhang Y C, Zhao L, Gao J, Zhou Z, Wang K, Zhang X W, Li L T, Li J F 2018 J. Mater. Chem. C 6 10618 Google Scholar
[63]	Liu Q, Li J F, Zhao L, Zhang Y C, Gao J, Sun W, Wang K, Li L T 2018 J. Mater. Chem. C 6 1116 Google Scholar
[64]	Fu J, Zuo R Z, Qi H, Zhang C, Li J F, Li L T 2014 Appl. Phys. Lett. 105 242903 Google Scholar
[65]	Zhou C M, Zhang J L, Yao W Z, Liu D K, Su W B 2019 Scripta Mater. 162 86 Google Scholar
[66]	Li P, Huan Y, Yang W W, Zhu F Y, Li X L, Zhang X M, Shen B, Zhai J W 2019 Acta Mater. 165 486 Google Scholar
[67]	Liu D K, Zhang X C, Su W B, Wang X M, Yao W Z, Zhou C M, Zhang J L 2019 J. Alloy. Comp. 779 800 Google Scholar
[68]	Lv X, Wu J G 2019 J. Mater. Chem. C 7 2037 Google Scholar
[69]	Zhang N, Zhao C, Wu J G 2019 Ceram. Inter. 45 24827 Google Scholar
[70]	Xing J, Tan Z, Xie L X, Jiang L M, Yuan J, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2018 J. Am. Ceram. Soc. 101 1632 Google Scholar
[71]	Tao H, Wu J G, Wang H 2016 J. Alloy. Comp. 684 217 Google Scholar
[72]	Wang T, Wu C, Xing J, Wu J G, Li Chen B W, Xu X Y, Wang K, Zhu J G 2019 J. Am. Ceram. Soc. 102 6126 Google Scholar
[73]	Cen Z Y, Wang X H, Huan Y, Li L T 2018 J. Am. Ceram. Soc. 101 2391 Google Scholar
[74]	Jiang L M, Tan Z, Xing J, Wu J G, Chen Q, Zhang W, Xiao D Q, Zhu J G 2016 J. Mater. Sci.- Mater. El. 27 9812 Google Scholar
[75]	Wang X P, Wu J G, Lv X, Tao H, Cheng X J, Zheng T, Zhang B Y, Xiao D Q, Zhu J G 2014 J. Mater. Sci.- Mater. El. 25 3219 Google Scholar
[76]	Wang Z, Xiao D Q, Wu J G, Xiao M, Li F X, Zhu J G, Damjanovic D 2014 J. Am. Ceram. Soc. 97 688 Google Scholar
[77]	Feng S S, Xiao D Q, Wu J G, Xiao M, Zhu J G 2015 J. Alloy. Comp. 619 560 Google Scholar
[78]	Cheng X J, Wu J G, Wang X P, Zhang B Y, Lou X J, Wang X J, Xiao D Q, Zhu J G 2013 ACS Appl. Mater. Interfaces 5 10409 Google Scholar
[79]	Gou Q, Zhu J G, Wu J G, Li F L, Jiang L M, Xiao D Q 2018 J. Alloy. Comp. 730 311 Google Scholar
[80]	Cheng X J, Wu J G, Lou X J, Wang X J, Wang X P, Xiao D Q, Zhu J G 2014 ACS Appl. Mater. Interfaces 6 750 Google Scholar
[81]	Gou Q, Xiao D Q, Wu B, Xiao M, Feng S S, Ma Zhao D D, Wu J G, Zhu J G 2015 RSC Adv. 5 30660 Google Scholar
[82]	Ma Q, Wan B B, Cheng L J, Liu S J, Liu F S 2016 J. Electroceram. 36 30 Google Scholar
[83]	Kim J H, Kim J S, Han S H, Kang H W, Lee H G, Cheon C I 2016 Ceram. Inter. 42 5226 Google Scholar
[84]	Sumang R, Wicheanrat C, Bongkarn T, Maensiri S 2015 Ceram. Inter. 41 S136 Google Scholar
[85]	Zhang S J, Xia R, Hao H, Liu H X, Shrout T R 2008 Appl. Phys. Lett. 92 152904 Google Scholar
[86]	Yao F Z, Wang K, Jo W, Webber K G, Comyn T P, Ding J X, Xu B, Cheng L Q, Zheng M P, Hou Y D, Li J F 2016 Adv. Funct. Mater. 26 1217 Google Scholar
[87]	Lv X, Wu J G, Zhu J G, Xiao D Q 2018 Phys. Chem. Chem. Phys. 20 20149 Google Scholar
[88]	Zhang M H, Wang K, Du Y J, Dai G, Sun W, Li G, Hu D, Thong H C, Zhao C L, Xi X Q, Yue Z X, Li J F 2017 J. Am. Chem. Soc. 139 3889 Google Scholar
[89]	Tao H, Zhao C L, Zhang R, Wu J G 2019 J. Alloy. Comp. 795 401 Google Scholar
[90]	Cen Z Y, Feng W, Zhao P Y, Chen L L, Zhu C Q, Yu Y, Li L T, Wang X H 2018 J. Am. Ceram. Soc. 102 2675 Google Scholar
[91]	Huang Y L, Zhao C L, Wu B, Wu J G 2019 J. Am. Ceram. Soc. 102 2648 Google Scholar
[92]	Zheng T, Wu J G 2020 Acta Mater. 182 1 Google Scholar
[93]	Ramajo L, Rubio-Marcos F, Del Campo A, Fernández J F, Castro M S, Parra R 2015 J. Mater. Sci.- Mater. El. 26 9402 Google Scholar
[94]	Liu W L, Tan G Q, Xiong P, Xue X, Hao H F, Ren H J 2014 J. Mater. Sci.- Mater. El. 25 2348 Google Scholar
[95]	Hao H F, Tan G Q, Ren H J, Xia A, Xiong P 2014 Ceram. Inter. 40 9485 Google Scholar
[96]	Gu Q L, Sun Q M, Zhu K J, Liu J S, Qiu J H 2017 Ceram. Inter. 43 1135 Google Scholar
[97]	Cheng L Q, Wang K, Li J F 2015 Mater. Lett. 138 128 Google Scholar
[98]	Li Y M, Wang J S, Liao R H, Huang D, Jiang X P 2010 J. Alloy. Compd. 496 282 Google Scholar
[99]	Kumar P, Pattanaik M, Sonia 2013 Ceram. Inter. 39 65 Google Scholar
[100]	Haugen A B, Madaro F, Bjørkeng L-P, Grande T, Einarsrud M A 2015 J. Eur Ceram. Soc. 35 1449 Google Scholar
[101]	Jiang C Y, Tian X X, Shi G D 2016 Adv. Intell. Sys. Res. 136 7 Google Scholar
[102]	Yokouchi Y, Maeda T, Bornmann P, Hemsel T, Morita T 2013 Jpn. J. Appl. Phys. 52 07HB03 Google Scholar
[103]	Wang C, Fang B J, Qu Y H, Chen Z H, Zhang S, Ding J N 2020 J. Alloy. Compd. 832 153043 Google Scholar
[104]	Jaeger R E, Egerton L 1962 J. Am. Ceram. Soc. 45 5 Google Scholar
[105]	Li M Y, Chan N Y, Wang D Y 2017 J. Am. Ceram. Soc. 100 2984 Google Scholar
[106]	Feizpour M, Barzegar Bafrooei H, Hayati R, Ebadzadeh T 2014 Ceram. Inter. 40 871 Google Scholar
[107]	Ma J Z, Li H Y, Wang H J, Lin C, Wu X, Lin T F, Zheng X H, Yu X 2019 J. Eur Ceram. Soc. 39 986 Google Scholar
[108]	Chi M S, Ma W B, Guo J D, Wu J Q, Li T T, Wang S H, Zhang P F 2019 J. Mater. Sci.- Mater. El. 39 986 Google Scholar
[109]	Yu Z D, Chen X M, Su Y L, Lian H L, Lu J B, Zhou J P, Liu P 2019 J. Mater. Sci. 54 13457 Google Scholar
[110]	Li J F, Wang K, Zhang B P, Zhang L M 2006 J. Am. Ceram. Soc. 89 706 Google Scholar
[111]	Cen Z Y, Li L T, Wang X H 2019 J. Alloy. Comp. 797 1115 Google Scholar
[112]	Li H, Gong D W, Yang W L, Zhou Z X 2012 J. Mater. Sci. 48 1396 Google Scholar
[113]	Liao Y, Wang D M, Wang H, Wang T, Wei X H, Zheng Q J, Jie W J, Lin D M 2019 Ceram. Inter. 45 2644 Google Scholar
[114]	Wu B, Yin J, Lv X, Xiao D Q, Zhu J G, Wu J G 2019 J. Appl. Phys. 125 082526 Google Scholar
[115]	Liao Y, Wang D M, Wang H, Zhou L X, Zheng Q J, Lin D M 2020 Dalton Trans. 49 1311 Google Scholar
[116]	Comes R, Lambert M, Guinier A 1968 Solid State Commun. 6 715 Google Scholar
[117]	Cohen R E 1992 Nature 358 136 Google Scholar
[118]	Atern E A, Yacoby Y 1996 J. Phys. Chem. Solids 57 1449 Google Scholar
[119]	Rytz D, Höchli U T, Bilz H 1980 Phys. Rev. B 22 359 Google Scholar
[120]	Shuvaeva V A, Yanagi K, Yagi K, Sakaue K, Terauchi H 1998 Solid State Commun 106 335 Google Scholar
[121]	Devonshire A F 1949 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 40 1040 Google Scholar
[122]	Devonshire A F 1951 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 42 1065 Google Scholar
[123]	Cochran W 1959 Phys. Rev. Lett. 3 412 Google Scholar
[124]	Damjanovic D, Demartin 1997 J. Phys.-Condens. Mat. 9 4943 Google Scholar
[125]	谭智 2019 博士学位论文 (成都: 四川大学) Tan Z 2019 Ph. D. Dissertation (Chengdu: Sichuan University) (in Chinese)
[126]	Tellier J, Malic B, Dkhil B, Jenko D, Cilensek J, Kosec M 2009 Solid State Sci. 11 320 Google Scholar
[127]	Baker D W, Thomas P A, Zhang N, Glazer A M 2009 Appl. Phys. Lett. 95 091903 Google Scholar
[128]	Guo Y P, Kakimoto K, Ohsato H 2004 Appl. Phys. Lett. 85 4121 Google Scholar
[129]	Yang D, Wei L L, Chao X L, Yang Z P, Zhou X Y 2016 Phys. Chem. Chem. Phys. 18 7702 Google Scholar
[130]	Wu Z G, Cohen R E 2005 Phys. Rev. Lett. 95 037601 Google Scholar
[131]	Shannon R D 1976 Acta Crystallogra. A 32 751 Google Scholar
[132]	Tan Z, Xing J, Jiang L M, Zhu J G, Wu B 2017 Front. Mater. Sci. 11 344 Google Scholar
[133]	Ke S M, Huang H T, Fan H Q, Lee H K, Zhou L M, Mai Y M 2012 Appl. Phys. Lett. 101 082901 Google Scholar
[134]	Fu H X, Cohen R E 2000 Nature 403 281 Google Scholar
[135]	Suewattana M, Singh D J 2010 Phys. Rev. B 82 014114 Google Scholar
[136]	Voas B K, Usher T M, Liu X, Li S, Jones J L, Tan X, Cooper V R, Beckman S P 2014 Phys. Rev. B 90 024105 Google Scholar
[137]	Matsumoto K, Hiruma Y, Nagata H, Takenaka T 2008 Ceram. Inter. 34 787 Google Scholar
[138]	Tan Z, Peng Y T, An J, Zhang Q M, Zhu J G 2019 J. Am. Ceram. Soc. 102 5262 Google Scholar
[139]	Peng Y, T Tan Z, An J, Zhu J G, Zhang Q M 2019 J. Eur. Ceram. Soc. 39 5252 Google Scholar
[140]	Li C W, Xu X, Gao Q, Lu Z L 2019 Ceram. Int. 45 11092 Google Scholar
[141]	Liu S Y, Liu S, Li D J, Shen Y, Dang H, Liu Y, Xue W, Wang S 2014 J. Am. Ceram. Soc 97 4019 Google Scholar
[142]	Li Q, Zhang R, Lv T Q, Zheng L M 2015 Chin. Phys. B 24 053101 Google Scholar
[143]	Yang D, Chai Q Z, Wei L L, Chao X L, Yang Z P 2017 Phys. Chem. Chem. Phys. 19 27368 Google Scholar

[1]	Chen Xiao-Ming, Wang Ming-Yan, Karaki Tomoaki, Li Guo-Rong. Temperature-stable electrical properties of CaZrO₃-modified (Na, K)NbO₃-based lead-free piezoceramics. Acta Physica Sinica, 2021, 70(19): 197701. doi: 10.7498/aps.70.20210440
[2]	Zhang Guan-Jie, Yang Hao, Zhang Nan. Research progress of the investigation of intrinsic and extrinsic origin of piezoelectric materials by X-ray diffraction. Acta Physica Sinica, 2020, 69(12): 127711. doi: 10.7498/aps.69.20200301
[3]	Liu Yi-Xuan, Li Zhao, Thong Hao-Cheng, Lu Jing-Tong, Li Jing-Feng, Gong Wen, Wang Ke. Grain size effect on piezoelectric performance in perovskite-based piezoceramics. Acta Physica Sinica, 2020, 69(21): 217704. doi: 10.7498/aps.69.20201079
[4]	Xu Ze, Lou Lu-Yao, Zhao Chun-Lin, Tang Hao-Cheng, Liu Yi-Xuan, Li Zhao, Qi Xiao-Mei, Zhang Bo-Ping, Li Jing-Feng, Gong Wen, Wang Ke. Effect of manganese doping on ferroelectric and piezoelectric properties of KNbO₃ and (K_0.5Na_0.5)NbO₃ lead-free ceramics. Acta Physica Sinica, 2020, 69(12): 127705. doi: 10.7498/aps.69.20200277
[5]	Liu Yong, Xu Zhi-Jun, Fan Li-Qun, Yi Wen-Tao, Yan Chun-Yan, Ma Jie, Wang Kun-Peng. Preparation and properties of multi-effect potassium sodium niobate based transparent ferroelectric ceramics. Acta Physica Sinica, 2020, 69(24): 247702. doi: 10.7498/aps.69.20201317
[6]	Wei Xiao-Wei, Tao Hong, Zhao Chun-Lin, Wu Jia-Gang. Piezoelectric and electrocaloric properties of high performance potassium sodium niobate-based lead-free ceramics. Acta Physica Sinica, 2020, 69(21): 217705. doi: 10.7498/aps.69.20200540
[7]	Jing Qi, Li Xiao-Juan. Preparation of porous barium titanate ceramics and enhancement of piezoelectric sensitivity. Acta Physica Sinica, 2019, 68(5): 057701. doi: 10.7498/aps.68.20181790
[8]	Wu Bao-Jia, Li Yan, Peng Gang, Gao Chun-Xiao. Electrical transport properties of InSe under high pressure. Acta Physica Sinica, 2013, 62(14): 140702. doi: 10.7498/aps.62.140702
[9]	Liu Shi-Yu, Yu Da-Shu, Lü Yue-Kai, Li De-Jun, Cao Mao-Sheng. First-principles study of structural stability and electronic properties of tetragonal and orthorhombic as well as monoclinic K0.5Na0.5NbO3. Acta Physica Sinica, 2013, 62(17): 177102. doi: 10.7498/aps.62.177102
[10]	Wang Bin-Ke, Tian Xiao-Xia, Xu Zhuo, Qu Shao-Bo, Li Zhen-Rong. Preparation and performances of KNN-based lead-free transparent ceramics. Acta Physica Sinica, 2012, 61(19): 197703. doi: 10.7498/aps.61.197703
[11]	Zhao Jing-Bo, Du Hong-Liang, Qu Shao-Bo, Zhang Hong-Mei, Xu Zhuo. Effects of A-site equivalence and non-equivalence substitution on polarization properties of K0.5Na0.5NbO3 lead-free piezoelectric ceramics. Acta Physica Sinica, 2011, 60(10): 107701. doi: 10.7498/aps.60.107701
[12]	Ming Bao-Quan, Wang Jin-Feng, Zang Guo-Zhong, Wang Chun-Ming, Gai Zhi-Gang, Du Juan, Zheng Li-Mei. X-ray diffraction and phase transition analysis for (K, Na)NbO3-based lead-free piezoelectric ceramics. Acta Physica Sinica, 2008, 57(9): 5962-5967. doi: 10.7498/aps.57.5962
[13]	Zhao Su-Chuan, Li Guo-Rong, Zhang Li-Na, Wang Tian-Bao, Ding Ai-Li. Dielectric properties of Na0.25K0.25Bi0.5TiO3 lead-free ceramics. Acta Physica Sinica, 2006, 55(7): 3711-3715. doi: 10.7498/aps.55.3711
[14]	Kang Xiang-Zhe, Ye Hui. Electro-optic properties of potassium sodium strontium barium niobate ferroelectric thin films. Acta Physica Sinica, 2006, 55(9): 4928-4933. doi: 10.7498/aps.55.4928
[15]	Chu Rui-Qing, Xu Zhi-Jun, Li Guo-Rong, Zeng Hua-Rong, Yu Han-Feng, Shao Xin, Luo Hao-Su, Yin Qing-Rui. Ultrahigh piezoelectric response along some special cleavage plane in BaTiO3 single-crystals. Acta Physica Sinica, 2005, 54(2): 935-938. doi: 10.7498/aps.54.935
[16]	Zhao Ming-Lei, Wang Chun-Lei, Wang Jin-Feng, Chen Hong-Cun, Zhong Wei-Lie. Enhanced piezoelectric properties of (Bi0.5Na0.5)1－xBax TiO3 lead-free ceramics by sol-gel method. Acta Physica Sinica, 2004, 53(7): 2357-2362. doi: 10.7498/aps.53.2357
[17]	CHU BAO-JIN, LI GUO-RONG, YIN QING-RUI, ZHANG WANG-ZHONG, CHEN DA-REN. INFLUENCE OF NONSTOICHIOMETRY AND DOPING ON ELECTRICAL PROPERTIES OF (Na1/2Bi1/2)0.92Ba0.08TiO3 CERAMICS. Acta Physica Sinica, 2001, 50(10): 2012-2016. doi: 10.7498/aps.50.2012
[18]	YIN XIN, Lü MENG-KAI, LI FU-QI. THE PIEZOELECTRIC PROPERTY OF NH4IO2 CRYSTAL. Acta Physica Sinica, 1989, 38(1): 124-127. doi: 10.7498/aps.38.124
[19]	ZHU YONG, ZHANG DAO-FAN. THE ELECTRO-OPTIC,PYROELECTRIC,DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF THE SINGLE CRYSTAL Sr₄NaLiNb₁₀O₃₀. Acta Physica Sinica, 1979, 28(2): 234-239. doi: 10.7498/aps.28.234
[20]	HUANG ZHAO-MING, ZHUANG PEI-GI, JIANG ZU-TAO, YU GUI-FANG. A METHOD OF DYNAMIC MEASUREMENT OF THE PIEZOELECTRIC PROPERTY OF ADP CRYSTAL. Acta Physica Sinica, 1966, 22(8): 911-918. doi: 10.7498/aps.22.911

Catalog

Vol. 69, Issue 12 - 2020-06-20

Metrics

Abstract views: 21503
PDF Downloads: 896
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板