Progress of defect and defect passivation in perovskite solar cells

Wang Cheng-Lin; Zhang Zuo-Lin; Zhu Yun-Fei; Zhao Xue-Fan; Song Hong-Wei; Chen Cong

doi:10.7498/aps.71.20220359

Abstract

Research on perovskite solar cells is prevalent because of their excellent photovoltaic performance. Most of the perovskite films are prepared by polycrystalline perovskite films and low-temperature solution method, thus inevitably creating a high density of defects, including point defects and extended defects. These defects can also be divided into two types: shallow-level defects and deep-level defects. The multiple types of defects are the main cause of nonradiative recombination, which will limit the enhancement of photovoltaic properties and stability of solar cell devices. In this paper, we review the latest advances in defect passivation and describe in detail the mechanisms of different methods to passivate defects at the surface and interface of perovskite films to reduce nonradiative recombination. We also summarize the research results about the defect passivation to reduce the deep energy level traps by Lewis acid and base, anion and cation, and the results about the conversion of defects into wide band gap materials as well. The effects of various strategies to modulate the mechanism of passivation of perovskite surface/interface defects are also elaborated. In addition, we discuss the intrinsic link between crystal defects and device stability, and provide an outlook on the feasibility of defect passivation strategies in future research.

Keywords:

Authors and contacts

1.
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China
2.
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science & Engineering, Jilin University, Changchun 130012, China

Corresponding author: Song Hong-Wei, songhw@jlu.edu.cn

FullText HTML : translate this paragraph

References

[1]	Grätzel M 2003 J. Photochem. Photobiol. C 4 145 Google Scholar
[2]	Günes S, Neugebauer H, Sariciftci N S 2007 Chem. Rev. 107 1324 Google Scholar
[3]	Li G, Shrotriya V, Huang J, Yao Y, Moriarty T, Emery K, Yang Y 2005 Nat. Mater. 4 864
[4]	Pazos-Outon L M, Xiao T P, Yablonovitch E 2018 J. Phys. Chem. Lett. 9 1703 Google Scholar
[5]	Stranks S D 2017 ACS Energy Lett. 2 1515 Google Scholar
[6]	Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088 Google Scholar
[7]	Jeon N J, Na H, Jung E H, Yang T Y, Lee Y G, Kim G, Shin H W, Seok S I, Lee J, Seo J 2018 Nature Energy 3 682 Google Scholar
[8]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen Y, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photonics 13 460 Google Scholar
[9]	Jung E H, Jeon N J, Park E Y, Moon C S, Shin T J, Yang T Y, Noh J H, Seo J 2019 Nature 567 511 Google Scholar
[10]	Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Graetzel M, Park N G 2012 Sci. Rep. 2 591 Google Scholar
[11]	Kim M, Kim G H, Lee T K, Choi I W, Choi H W, Jo Y, Yoon Y J, Kim J W, Lee J, Huh D, Lee H, Kwak S K, Kim J Y, Kim D S 2019 Joule 3 2179 Google Scholar
[12]	Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050 Google Scholar
[13]	Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J P, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341 Google Scholar
[14]	National Renewable Energy Laboratory, Best research cell efficiencies, www. nrel. gov/pv/cell-efficiency. html (2022)
[15]	Chen J, Park N G 2019 Adv. Mater. 31 1803019 Google Scholar
[16]	Sarritzu V, Sestu N, Marongiu D, Chang X, Masi S, Rizzo A, Colella S, Quochi F, Saba M, Mura A, Bongiovanni G 2017 Sci. Rep. 7 44629 Google Scholar
[17]	Holzhey P, Saliba M 2018 J. Mater. Chem. A 6 21794 Google Scholar
[18]	Han T H, Tan S, Xue J L, Meng L, Lee J W, Yang Y 2019 Adv. Mater. 31 1803515 Google Scholar
[19]	Ono L K, Liu S, Qi Y 2020 Angew. Chem. Int. Ed. 59 6676 Google Scholar
[20]	Shockley W, Read W T 1952 Phys. Rev. 87 835 Google Scholar
[21]	Agiorgousis M L, Sun Y Y, Zeng H, Zhang S 2014 J. Am. Chem. Soc. 136 14570 Google Scholar
[22]	Tress W, Marinova N, Inganas O, Nazeeruddin M K, Zakeeruddin S M, Graetzel M 2015 Adv. Energy Mater. 5 1400812 Google Scholar
[23]	Abate A 2017 Joule 1 659 Google Scholar
[24]	Kieslich G, Sun S, Cheetham A 2014 Chem. Sci. 5 4712 Google Scholar
[25]	Li X, Hoffman J M, Kanatzidis M G 2021 Chem. Rev. 121 2230 Google Scholar
[26]	Rajagopal A, Yao K, Jen A K Y 2018 Adv. Mater. 30 1800455 Google Scholar
[27]	Miyata A, Mitioglu A, Plochocka P, Portugall O, Wang J T W, Stranks S D, Snaith H J, Nicholas R J 2015 Nat. Phys. 11 582 Google Scholar
[28]	Liu N, Yam C 2018 Phys. Chem. Chem. Phys. 20 6800 Google Scholar
[29]	Yin W J, Shi T, Yan Y 2014 Appl. Phys. Lett. 104 063903 Google Scholar
[30]	Li W, Liu J, Bai F Q, Zhang H X, Prezhdo O V 2017 ACS Energy Lett. 2 1270 Google Scholar
[31]	Saliba M, Matsui T, Seo J Y, Domanski K, Correa-Baena J P, Nazeeruddin M K, Zakeeruddin S M, Tress W, Abate A, Hagfeldt A, Gratzel M 2016 Energy Environ. Sci. 9 1989 Google Scholar
[32]	Yin W J, Shi T, Yan Y 2014 Applied Physics Letters 104 063903
[33]	Steirer K X, Schulz P, Teeter G, Stevanovic V, Yang M, Zhu K, Berry J J 2016 ACS Energy Lett. 1 360 Google Scholar
[34]	Azpiroz J M, Mosconi E, Bisquert J, De Angelis F 2015 Energy Environ. Sci. 8 2118 Google Scholar
[35]	Yuan Y, Li T, Wang Q, Xing J, Gruverman A, Huang J 2017 Sci. Adv. 3 e1602164 Google Scholar
[36]	Hoke E T, Slotcavage D J, Dohner E R, Bowring A R, Karunadasa H I, McGehee M D 2015 Chem. Sci. 6 613 Google Scholar
[37]	Carrillo J, Guerrero A, Rahimnejad S, Almora O, Zarazua I, Mas-Marza E, Bisquert J, Garcia-Belmonte G 2016 Adv. Energy Mater. 6 1502246 Google Scholar
[38]	Shao Y, Fang Y, Li T, Wang Q, Dong Q, Deng Y, Yuan Y, Wei H, Wang M, Gruverman A 2016 Energy Environ. Sci. 9 1752 Google Scholar
[39]	Chen B, Rudd P N, Yang S, Yuan Y, Huang J 2019 Chem. Soc. Rev. 48 3842 Google Scholar
[40]	Aberle A G 2001 Solar Energy Mater. 65 239 Google Scholar
[41]	Hoex B, Schmidt J, Pohl P, Van de Sanden M, Kessels W 2008 J. Appl. Phys. 104 044903 Google Scholar
[42]	Aberle A G 2000 Prog. Photovoltaics Res. Appl. 8 473 Google Scholar
[43]	Ran C, Xu J, Gao W, Huang C, Dou S 2018 Chem. Soc. Rev. 47 4581 Google Scholar
[44]	Ross R T J T J o C P 1967 J. Chem. Phys. 46 4590 Google Scholar
[45]	Kim H S, Mora-Sero I, Gonzalez-Pedro V, Fabregat-Santiago F, Juarez-Perez E J, Park N G, Bisquert J 2013 Nat. Commun. 4 1 Google Scholar
[46]	Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511 Google Scholar
[47]	Shao Y, Xiao Z, Bi C, Yuan Y, Huang J 2014 Nat. Commun. 5 1 Google Scholar
[48]	Lin Y, Chen B, Zhao F, Zheng X, Deng Y, Shao Y, Fang Y, Bai Y, Wang C, Huang J 2017 Adv. Mater. 29 1700607 Google Scholar
[49]	Wang J, Datta K, Weijtens C H L, Wienk M M, Janssen R A J 2019 Adv. Func. Mater. 29 1905883 Google Scholar
[50]	Haddon R C 1993 Science 261 1545 Google Scholar
[51]	Xu J, Buin A, Ip A H, Li W, Voznyy O, Comin R, Yuan M, Jeon S, Ning Z, McDowell J J 2015 Nat. Commun. 6 7081 Google Scholar
[52]	Abate A, Saliba M, Hollman D J, Stranks S D, Wojciechowski K, Avolio R, Grancini G, Petrozza A, Snaith H J 2014 Nano Lett. 14 3247 Google Scholar
[53]	Yang Z, Dou J, Kou S, Dang J, Ji Y, Yang G, Wu W Q, Kuang D B, Wang M 2020 Adv. Funct. Mater. 30 1910710 Google Scholar
[54]	Lee J W, Kim H S, Park N G 2016 Acc Chem. Res. 49 311 Google Scholar
[55]	Noel N K, Abate A, Stranks S D, Parrott E S, Burlakov V M, Goriely A, Snaith H J 2014 ACS Nano 8 9815 Google Scholar
[56]	Zuo L J, Guo H X, deQuilettes D W, Jariwala S, De Marco N, Dong S Q, DeBlock R, Ginger D S, Dunn B, Wang M K, Yang Y 2017 Sci. Adv. 3 e1700106 Google Scholar
[57]	Liu L, Fang W H, Long R, Prezhdo O V 2018 J. Phys. Chem. Lett. 9 1164 Google Scholar
[58]	Hou Y, Zhou Z R, Wen T Y, Qiao H W, Lin Z Q, Ge B, Yang H G 2019 Nanoscale Horiz. 4 208 Google Scholar
[59]	Zeng Q, Zhang X, Feng X, Lu S, Chen Z, Yong X, Redfern S A, Wei H, Wang H, Shen H 2018 Adv. Mater. 30 1705393 Google Scholar
[60]	You S, Wang H, Bi S, Zhou J, Qin L, Qiu X, Zhao Z, Xu Y, Zhang Y, Shi X, Zhou H, Tang Z 2018 Adv. Mater. 30 1706924 Google Scholar
[61]	Zhu L, Zhang X, Li M, Shang X, Lei K, Zhang B, Chen C, Zheng S, Song H, Chen J 2021 Adv. Energy Mater. 11 2100529 Google Scholar
[62]	deQuilettes D W, Koch S, Burke S, Paranji R K, Shropshire A J, Ziffer M E, Ginger D S 2016 ACS Energy Lett. 1 438 Google Scholar
[63]	Wang X, Sun Y, Wang Y, Ai X C, Zhang J P 2022 J. Phys. Chem. Lett. 13 1571 Google Scholar
[64]	Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng X C, Huang J 2017 Nature Energy 2 1 Google Scholar
[65]	Zhang F, Bi D, Pellet N, Xiao C, Li Z, Berry J J, Zakeeruddin S M, Zhu K, Gratzel M 2018 Energy Environ. Sci. 11 3480 Google Scholar
[66]	Zheng X, Deng Y, Chen B, Wei H, Xiao X, Fang Y, Lin Y, Yu Z, Liu Y, Wang Q 2018 Adv. Mater. 30 1803428 Google Scholar
[67]	Bi C, Zheng X, Chen B, Wei H, Huang J 2017 ACS Energy Lett. 2 1400 Google Scholar
[68]	Abdi-Jalebi M, Andaji-Garmaroudi Z, Cacovich S, Stavrakas C, Philippe B, Richter J M, Alsari M, Booker E P, Hutter E M, Pearson A J, Lilliu S, Savenije T J, Rensmo H, Divitini G, Ducati C, Friend R H, Stranks S D 2018 Nature 555 497 Google Scholar
[69]	Zhang W, Liu H, Qi X, Yu Y, Zhou Y, Xia Y, Cui J, Shi Y, Chen R, Wang H L 2022 Adv. Sci. e2106054
[70]	Ling X, Zhou S, Yuan J, Shi J, Qian Y, Larson B W, Zhao Q, Qin C, Li F, Shi G, Stewart C, Hu J, Zhang X, Luther J M, Duhm S, Ma W 2019 Adv. Energy Mater. 9 1900721 Google Scholar
[71]	Zhang Y, Liu X, Li P, Duan Y, Hu X, Li F, Song Y 2019 Nano Energy 56 733 Google Scholar
[72]	Jung M, Shin T J, Seo J, Kim G, Seok S I 2018 Energy Environ. Sci. 11 2188 Google Scholar
[73]	Zhao T, Chueh C C, Chen Q, Rajagopal A, Jen A K Y J A E L 2016 ACS Energy Lett. 1 757 Google Scholar
[74]	Jokar E, Chien C H, Fathi A, Rameez M, Chang Y H, Diau E W G 2018 Energy Environ. Sci. 11 2353 Google Scholar
[75]	Lin Y, Bai Y, Fang Y J, Wang Q, Deng Y H, Huang J S 2017 ACS Energy Lett. 2 1571 Google Scholar
[76]	Wang Z, Lin Q, Chmiel F P, Sakai N, Herz L M, Snaith H J 2017 Nature Energy 2 17135 Google Scholar
[77]	Lee D, Yun J S, Kim J, Soufiani A M, Chen S, Cho Y, Deng X F, Seidel J, Lim S, Huang S J, Ho-Baillie A W Y 2018 ACS Energy Lett. 3 647 Google Scholar
[78]	Grancini G, Roldán-Carmona C, Zimmermann I, Mosconi E, Lee X, Martineau D, Narbey S, Oswald F, De Angelis F, Graetzel M 2017 Nat. Commun. 8 1 Google Scholar
[79]	Pool V L, Gold-Parker A, McGehee M D, Toney M F 2015 Chem. Mater. 27 7240 Google Scholar
[80]	Luo Y, Gamliel S, Nijem S, Aharon S, Holt M, Stripe B, Rose V, Bertoni M I, Etgar L, Fenning D P 2016 Chem. Mater. 28 6536 Google Scholar
[81]	Nan G J, Zhang X, Abdi-Jalebi M, Andaji-Garmaroudi Z, Stranks S D, Lu G, Beljonne D 2018 Adv. Energy Mater. 8 1702754 Google Scholar
[82]	Chen Q, Zhou H, Fang Y, Stieg A Z, Song T B, Wang H H, Xu X, Liu Y, Lu S, You J 2015 Nat. Commun. 6 7269 Google Scholar
[83]	Son D Y, Lee J W, Choi Y J, Jang I H, Lee S, Yoo P J, Shin H, Ahn N, Choi M, Kim D 2016 Nature Energy 1 1 Google Scholar
[84]	Yi H, Duan L, Haque F, Bing J, Zheng J, Yang Y, Mo A C H, Zhang Y, Xu C, Conibeer G, Uddin A 2020 J. Power Sources 466 228320 Google Scholar
[85]	Zhang J, Wu S, Liu T, Zhu Z, Jen A K Y 2019 Adv. Funct. Mater. 29 1808833 Google Scholar
[86]	Chen J, Kim S G, Park N G 2018 Adv. Mater. 30 1801948 Google Scholar
[87]	Jokar E, Chuang H S, Kuan C H, Wu H P, Hou C H, Shyue J J, Wei-Guang Diau E 2021 J. Phys. Chem. Lett. 12 10106 Google Scholar
[88]	Yang Y M, Chen X, Liu S, Zhu H, Wang W, Kuang C, Liu X 2021 J. Phys. Chem. C 125 12560 Google Scholar
[89]	Sun Y, Peng J, Chen Y, Yao Y, Liang Z 2017 Sci. Rep. 7 46193 Google Scholar
[90]	Yang S, Liu W, Zuo L, Zhang X, Ye T, Chen J, Li C Z, Wu G, Chen H 2016 J. Mater. Chem. A 4 9430 Google Scholar
[91]	Kim M K, Jeon T, Park H I, Lee J M, Nam S A, Kim S O 2016 CrystEngComm 18 6090 Google Scholar
[92]	Han Q, Bai Y, Liu J, Du K-z, Li T, Ji D, Zhou Y, Cao C, Shin D, Ding J, Franklin A D, Glass J T, Hu J, Therien M J, Liu J, Mitzi D B 2017 Energy Environ. Sci. 10 2365 Google Scholar
[93]	Zhang X, Wu G, Fu W, Qin M, Yang W, Yan J, Zhang Z, Lu X, Chen H 2018 Adv. Energy Mater. 8 1702498 Google Scholar
[94]	Zhang X, Wu G, Yang S, Fu W, Zhang Z, Chen C, Liu W, Yan J, Yang W, Chen H 2017 Small 13 1700611 Google Scholar
[95]	Chen J, Rong Y, Mei A, Xiong Y, Liu T, Sheng Y, Jiang P, Hong L, Guan Y, Zhu X, Hou X, Duan M, Zhao J, Li X, Han H 2016 Adv. Energy Mater. 6 1502009 Google Scholar
[96]	Yang L, Ma X, Shang X, Gao D, Wang C, Li M, Chen C, Zhang B, Xu S, Zheng S, Song H 2021 Solar RRL 5 2100352 Google Scholar
[97]	Bi H, Liu B, He D, Bai L, Wang W, Zang Z, Chen J 2021 Chem. Eng. J. 418
[98]	Wang Z, Wu T, Xiao L, Qin P, Yu X, Ma L, Xiong L, Li H, Chen X, Wang Z, Wu T, Xiao M L, Qin P, Yu D X, Ma D L, Xiong D L, Li D H, Chen X 2021 J. Power Sources 488 229451 Google Scholar
[99]	Wu Q, Zhou W, Liu Q, Zhou P, Chen T, Lu Y, Qiao Q, Yang S 2016 ACS Appl. Mater. Interfaces 8 34464 Google Scholar
[100]	Goh S, Jang G, Ma S, Park J, Ban H, Lee C U, Lee J, Moon J 2021 ACS Sustainable Chem. Eng. 9 16730 Google Scholar
[101]	Zhang C, Wang H, Li H, Zhuang Q, Gong C, Hu X, Cai W, Zhao S, Chen J, Zang Z 2021 J. Energy Chem. 63 452 Google Scholar
[102]	Wang K, Ma S, Xue X, Li T, Sha S, Ren X, Zhang J, Lu H, Ma J, Guo S, Liu Y, Feng J, Najar A, Liu S F 2022 Adv. Sci. e2105103 Google Scholar
[103]	Chen Q, Zhou H, Song T B, Luo S, Hong Z, Duan H S, Dou L, Liu Y, Yang Y 2014 Nano Lett. 14 4158 Google Scholar
[104]	Lin Y, Bai Y, Fang Y J, Chen Z L, Yang S, Zheng X P, Tang S, Liu Y, Zhao J J, Huang J S 2018 J. Phys. Chem. Lett. 9 654 Google Scholar
[105]	Hu Y, Schlipf J, Wussler M, Petrus M L, Jaegermann W, Bein T, Müller-Buschbaum P, Docampo P 2016 ACS Nano 10 5999 Google Scholar
[106]	Ma X, Yang L, Shang X, Li M, Gao D, Wu C, Zheng S, Zhang B, Chen J, Chen C, Song H 2021 Chem. Eng. J. 426 130685 Google Scholar
[107]	Chen C, Li F, Zhu L, Shen Z, Weng Y, Lou Q, Tan F, Yue G, Huang Q, Wang M 2020 Nano Energy 68 104313 Google Scholar
[108]	Kim H, Lee J W, Han G R, Kim S K, Oh J H 2020 Adv. Funct. Mater. 31 2008801 Google Scholar
[109]	Cai S, Dai J, Shao Z, Rothmann M U, Jia Y, Gao C, Hao M, Pang S, Wang P, Lau S P, Zhu K, Berry J J, Herz L M, Zeng X C, Zhou Y 2022 J. Am. Chem. Soc. 144 1910 Google Scholar
[110]	Zhang Y, Wang Y, Yang X, Zhao L, Su R, Wu J, Luo D, Li S, Chen P, Yu M, Gong Q, Zhu R 2022 Adv. Mater. 34 2107420 Google Scholar

Cited By

图 1 (a)三维钙钛矿结构示意图^[25]; (b)双钙钛矿结构示意图, 其中两种二价金属M²⁺(Ge²⁺, Sn²⁺, Pb²⁺等)被单价M⁺ (Na⁺, K⁺, Rb⁺, Cu⁺, Ag⁺等)和三价的金属M³⁺ (Sb³⁺, Bi³⁺等)组合取代^[23]; (c)二维钙钛矿结构示意图^[25]; (d)正置型PSCs结构示意图; (e)倒置型PSCs结构示意图

Figure 1. (a) Schematic illustration of 3D perovskite structure; (b) schematic showing the perovskite structure with two divalent metals (M²⁺: Ge²⁺, Sn²⁺, Pb²⁺) replaced by a combination of monovalent (M⁺: Na⁺, K⁺, Rb⁺, Cu⁺, Ag⁺) and trivalent (M³⁺: Sb³⁺, Bi³⁺) metals; (c) schematic illustration of 2D perovskite structure; (d) schematic illustration of normal planar; (e) schematic illustration of inverted planar PSCs.

DownLoad: Full-Size Img PowerPoint

图 2 缺陷类型　(a)完美晶体结构; (b)空位缺陷;(c)间隙缺陷; (d)反位缺陷; (e)反位杂质缺陷; (f)间隙杂质缺陷

Figure 2. Types of defects: (a) Perfect crystal structure; (b) vacancy defects; (c) interstitial defects; (d) antisite defects; (e) antisite impurity defects; (f) interstitial impurity defects.

DownLoad: Full-Size Img PowerPoint

图 3 缺陷钝化机理图, 钙钛矿薄膜中的缺陷及其通过离子键、配位键和转换为宽带隙材料的钝化, 可以通过缺陷钝化抑制晶界处的离子迁移^[39]

Figure 3. Schematic illustration of defect passivation mechanism: Imperfections in perovskite films and their passivation by ionic bonding, coordinate bonding, and conversion to wide bandgap materials. Suppression of ion migration at GBs can be achieved by passivation^[39].

DownLoad: Full-Size Img PowerPoint

图 4 (a) 具有PCBM层的器件结构^[47]; (b) 通过热导纳光谱获得的陷阱态密度 (tDOS)^[47]; (c) 钙钛矿薄膜和不同ETL衬底的能带示意图^[49]; (d)混合溶液的紫外(UV)-可见光吸收光谱图显示PCBM和钙钛矿离子之间的相互作用^[51]; (e)卤化物(X^–)通过碘五氟苯在过氧化物表面的卤素键络合而产生的静电屏蔽示图^[52]; (f)通过低配位卤化物和空穴之间的静电相互作用捕获电荷^[52]

Figure 4. (a) Device structure with PCBM layer; (b) trap density of states (tDOS) obtained by thermal conductivity spectroscopy; (c) schematic diagram of the energy bands of perovskite films and different ETL substrates; (d) the ultraviolet (UV)-visible absorption spectra of the mixed solutions show the interaction between PCBM and perovskite ions; (e) illustration of the electrostatic screening of the halide (X^–) via halogen bond complexation of Iodopentafluorobenzene on the perovskite surface; (f) charge trapping by electrostatic interactions between the undercoordinated halide and the hole.

DownLoad: Full-Size Img PowerPoint

图 5 (a)路易斯酸(A)-碱(B)反应形成具有配位键的加合物(A·B). 路易斯碱具有氧供体(O-donor)、硫供体(S-donor)、氮供体(N-donor)^[54]. (b) 有/无DMSO辅助结晶的钙钛矿薄膜SEM图^[54]. (c)噻吩(或吡啶)分子通过提供电子与 Pb²⁺ 作用, 中和多余的正电荷^[55]. (d) 11 MA钝化机理图^[61]. (e)经三辛基氧膦(TOPO, 红色)、1-十八烷基硫醇(ODT, 橙色)和三苯基膦(PPh₃, 蓝色)处理的薄膜的时间分辨光致发光衰减线^[62]. (f)标样和经TOPO, ODT, PPh₃处理薄膜的综合发光强度统计^[62]

Figure 5. (a) Lewis acid (A)–base (B) reaction to form an adduct (A·B) with a dative bond. Lewis bases with oxygen donor (O-donor), sulfur donor (S-donor), and nitrogen donor (N-donor). (b) SEM image of perovskite films with/without DMSO-assisted crystallization. (c) The thiophene (or pyridine) molecule neutralizes the excess positive charge by providing electrons to coordinate with Pb²⁺. (d) Schematic illustration of 11 MA passivation mechanism. (e) Time-resolved photoluminescence decay lines of films treated with trioctylphosphine oxide (TOPO, red), 1-octadecylthiol (ODT, orange), and triphenylphosphine (PPh3, blue). (f) The integrated luminescence intensity statistics of the control samples and the films treated with TOPO, ODT and PPh3.

DownLoad: Full-Size Img PowerPoint

图 6 (a) 钾离子含量增加的 KI 钝化钙钛矿薄膜的 PLQE图^[68]; (b) 薄膜横截面示意图, 显示在过量卤化物的情况下卤化物空位调控, 其中多余的卤化物通过与钾络合在晶界和表面形成良性化合物而被固定^[68]; (c) 草酸锌钝化机理图^[69]

Figure 6. (a) PLQE of KI passivated perovskite film with increased potassium ion content; (b) schematic cross-section of the film showing halide vacancy modulation in the presence of excess halide, where the excess halide is immobilized by complexation with potassium to form benign compounds at grain boundaries and surfaces; (c) schematic illustration of the passivation mechanism of zinc oxalate.

DownLoad: Full-Size Img PowerPoint

图 7 (a) 掺入不同浓度的NH₄BF₄(001)和(012)晶面的放大XRD图谱^[85]; (b)原始钙钛矿薄膜SEM图像^[84]; (c)掺入SCN^–离子后钙钛矿薄膜的SEM图像^[84]; (d) I^–和PF${}_6^- $之间的离子交换反应形成的上层FA_0.88Cs_0.12PbI_3–x(PF₆)_x钙钛矿薄膜的制备过程示意图^[86] ; (e)原始钙钛矿薄膜SEM图像^[86]; (f)用1 mg/ml的FAPF₆后处理的钙钛矿SEM图像^[86]

Figure 7. (a) XRD patterns of (FAPbI₃)_0.83(MAPbBr₃)_0.17 with different molar ratio of NH4BF4; (b) SEM image of control perovskite films; (c) SEM images of the perovskite films after doping with SCN^– ions; (d) schematic illustration of preparation process of upper layer perovskite film FA_0.88Cs_0.12PbI_3–x(PF₆)_x formed via ion exchange reaction between I^– and PF${}_6^- $; (e) SEM image of the control perovskite film; (f) SEM image of perovskite post-treated with 1 mg/ml of FAPF₆.

DownLoad: Full-Size Img PowerPoint

图 8 (a)两性离子液体功能添加剂材料的化学结构^[96]; (b)两步法制备多晶体钙钛矿薄膜的工艺^[96]; (c)两性离子液体功能添加剂材料改善太阳能电池性能和稳定性的机理图^[96]; (d)有无组合钝化策略晶体生长示意图^[102]

Figure 8. (a) Chemical structure of ZIL; (b) two-step process for the preparation of polycrystalline perovskite films; (c) mechanistic diagram of ZIL for improving the performance and stability of solar cells; (d) schematic diagram of crystal growth with and without combined passivation strategy.

DownLoad: Full-Size Img PowerPoint

图 9 通过I型对齐减少载流子复合. (a)—(c) PbI₂钝化: (a) SEM示意图^[103]; (b) 结构示意图^[103]; (c) MAPbI₃薄膜的能带排列, PbI₂包裹钙钛矿颗粒^[103]. (d) 分层/3D钙钛矿异质结构示意图^[76]

Figure 9. Reduction of carrier recombination by type-I alignment. (a)–(c) PbI2 passivation: (a) SEM, (b) schematic illustration, and (c) band alignment of MAPbI₃ film with PbI2 wrapping the perovskite grain. (d) Schematic illustration of the layered/3D perovskite heterostructure.

DownLoad: Full-Size Img PowerPoint

图 10 (a) 硫酸甲胺的分子结构图^[106]; (b)引入硫酸甲胺调节钙钛矿吸光层的湿度稳定性^[106]; (c) MS钝化机理图^[106]; (d) CH₃NH₃PbI₃/PbSO₄(PbO)₄界面间键合作用^[107]; (e)CH₃NH₃PbI₃/PbSO₄(PbO)₄薄膜中的空穴和电子波函数分布^[107]

Figure 10. (a) Molecular structure of methylamine sulfate; (b) modulation of the humidity stability of the perovskite absorbing layer by methylamine sulfate; (c) mechanism diagram of methylamine sulfate passivation;(d) CH₃NH₃PbI₃/PbSO₄(PbO)₄ interfacial bonding interaction; (e) the hole and electron wave function distributions in the CH₃NH₃PbI₃/ PbSO₄₍PbO)₄ film.

DownLoad: Full-Size Img PowerPoint

图 11 未来调控PSCs中晶体缺陷的可行性策略　(a)多功能协同钝化策略机理图^[108]; (b)使用STEM-HAADF表征金属卤化物钙钛矿的精细原子结构^[109]; (c)对钙钛矿粉末进行预处理而后再溶解制备出低缺陷密度钙钛矿薄膜^[110]

Figure 11. Potential optimization strategies of PSCs: (a) Schematic diagram of the multifunctional synergistic passivation strategy; (b) characterization of the fine atomic structure of metal halide perovskite by using STEM-HAADF; (c) pre-treatment of perovskite powder followed by dissolution to prepare low defect density perovskite film.

DownLoad: Full-Size Img PowerPoint

表 1 基于SCN^–钝化的钙钛矿薄膜的PSCs的光伏参数

Table 1. Photovoltaic parameters of PSCs with SCN^– passivated of perovskite films.

Device	J_SC/ (mA·cm^–2) (C/T)	V_OC/V (C/T)	FF(C/T)	效率(C/T)	Ref.
ITO/PEDOT:PSS/FA_0.8GA_0.2SnI₃/PHSCN/C₆₀/BCP/Ag	21.1/21.9	0.645/0.81	76.3/76	10.6/13.5	[87]
ITO/PEDOT:PSS/FA_0.55MA_0.45Sn_0.55Pb_0.45I₃(SnF₂ and Pb(SCN)₂)/C₆₀/BCP/Ag	11.4/28.9	0.54/0.76	38.6/82.3	2.4/18.1	[88]
ITO/PEDOT:PSS/FA_0.7MA_0.2Cs_0.1Pb(I_5/6Br_1/6)₃(Pb(SCN)₂)/ PCBM/Bphen/Al	6.98/18.21	1.10/1.06	71.87/72.97	5.52/14.09	[89]
FTO/TiO₂/FAPbI₃(NH₄SCN)/Spiro-OMeTAD/MoO₃/Ag	17.52/17.88	0.74/0.93	46.83/68.75	5.94/11.44	[90]
ITO/PEDOT:PSS/MAPbI₃(Pb(SCN)₂)/PCBM/Ca/Al	9.49/15.41	0.83/0.81	72.93/79.69	6.08/9.91	[91]
FTO/TiO₂/MAPbI₃(MASCN)/Spiro-OMeTAD/Au	8.78/22.29	0.638/1.064	36.48/76.83	2.04/18.22	[92]
ITO/SnO₂/MA_0.6FA_0.4PbI_xBr_1–x(Pb(SCN)₂)/Spiro-OMeTAD/Ag	21.86/23.16	1.03/1.12	75.76/75.26	17.13/19.64	[84]
ITO/PEDOT:PSS/(PEA)₂(MA)₄Pb₆I₁₆(NH₄SCN)/PC₆₁BM/BCP/Ag	0.93/15.01	1.02/1.11	59/63	0.56/11.01	[93]
ITO/PEDOT:PSS/(BA)₂(MA)₂Pb₃I₁₀(NH₄SCN)/PC₆₁BM/BCP/Ag	3.16/12.79	0.93/0.97	43/55	1.31/6.89	[94]

DownLoad: CSV

表 2 基于BF₄^–或PF₆^–钝化的钙钛矿薄膜的钙钛矿太阳能电池的光伏参数

Table 2. Photovoltaic parameters of PSCs with BF₄^– or PF₆^– passivated of perovskite films.

Device	J_SC/ (mA·cm^–2 (C/T)	V_OC/V (C/T)	FF(C/T)	效率(C/T)	Ref.
FTO/TiO₂/MApbI₃(MABF₄)/ZrO₄/Carbon	16.92/18.15	0.914/0.957	0.68/0.76	10.54/13.24	[95]
ITO/SnO₂/(FAPbI₃)_0.83(MAPbBr)_0.17(NH₄BF₄)/ Spiro-OMeTAD/MoO₃/Ag	23.39/23.38	1.12/1.15	0.67/0.75	17.55/20.16	[85]
ITO/SnO₂/(FAPbI₃)_1–x(MAPbBr₃)_x(4FBBF₄) /Spiro-OMeTAD/Ag	24.00/24.85	1.130/1.162	0.76/0.78	20.69/22.52	[96]
FTO/bl-TiO₂/mp-TiO₂/FA_0.88Cs_0.12PbI₃/(FAPF₆)/Spiro-OMeTAD/Au	23.00/23.11	1.020/1.045	0.76/0.80	17.79/19.25	[86]
ITO/SnO₂/KPF₆/FA_0.88Cs_0.12PbI₃/Spiro-OMeTAD/Au	22.38/22/83	1.100/1.145	0. 80/0.82	19.66/21.39	[97]
FTO/SnO₂ QD/KPF₆/(CsI)_0.04(FAI)_0.82(PbI₂)_0.86(MAPbBr₃)_0.14/ Spiro-OMeTAD/Au	21.60/23.15	1.072/1.12	0.74/0.81	17.04/21.05	[98]
FTO/TiO₂/[EMIM]PF₆–IL/CH₃NH₃I/Spiro-OMeTAD/Au ITO/SnO₂/ Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83Br_0.17)₃/ Spiro-OMeTAD(LiPF₆)/Au	19.30/23.52 22.59/23.78	1.07/1.09 1.06/1.10	0.66/0.71 0.78/0.79	14.20/18.42 19.04/20.78	[99] [100]

DownLoad: CSV

[1]	Grätzel M 2003 J. Photochem. Photobiol. C 4 145 Google Scholar
[2]	Günes S, Neugebauer H, Sariciftci N S 2007 Chem. Rev. 107 1324 Google Scholar
[3]	Li G, Shrotriya V, Huang J, Yao Y, Moriarty T, Emery K, Yang Y 2005 Nat. Mater. 4 864
[4]	Pazos-Outon L M, Xiao T P, Yablonovitch E 2018 J. Phys. Chem. Lett. 9 1703 Google Scholar
[5]	Stranks S D 2017 ACS Energy Lett. 2 1515 Google Scholar
[6]	Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088 Google Scholar
[7]	Jeon N J, Na H, Jung E H, Yang T Y, Lee Y G, Kim G, Shin H W, Seok S I, Lee J, Seo J 2018 Nature Energy 3 682 Google Scholar
[8]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen Y, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photonics 13 460 Google Scholar
[9]	Jung E H, Jeon N J, Park E Y, Moon C S, Shin T J, Yang T Y, Noh J H, Seo J 2019 Nature 567 511 Google Scholar
[10]	Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Graetzel M, Park N G 2012 Sci. Rep. 2 591 Google Scholar
[11]	Kim M, Kim G H, Lee T K, Choi I W, Choi H W, Jo Y, Yoon Y J, Kim J W, Lee J, Huh D, Lee H, Kwak S K, Kim J Y, Kim D S 2019 Joule 3 2179 Google Scholar
[12]	Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050 Google Scholar
[13]	Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J P, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341 Google Scholar
[14]	National Renewable Energy Laboratory, Best research cell efficiencies, www. nrel. gov/pv/cell-efficiency. html (2022)
[15]	Chen J, Park N G 2019 Adv. Mater. 31 1803019 Google Scholar
[16]	Sarritzu V, Sestu N, Marongiu D, Chang X, Masi S, Rizzo A, Colella S, Quochi F, Saba M, Mura A, Bongiovanni G 2017 Sci. Rep. 7 44629 Google Scholar
[17]	Holzhey P, Saliba M 2018 J. Mater. Chem. A 6 21794 Google Scholar
[18]	Han T H, Tan S, Xue J L, Meng L, Lee J W, Yang Y 2019 Adv. Mater. 31 1803515 Google Scholar
[19]	Ono L K, Liu S, Qi Y 2020 Angew. Chem. Int. Ed. 59 6676 Google Scholar
[20]	Shockley W, Read W T 1952 Phys. Rev. 87 835 Google Scholar
[21]	Agiorgousis M L, Sun Y Y, Zeng H, Zhang S 2014 J. Am. Chem. Soc. 136 14570 Google Scholar
[22]	Tress W, Marinova N, Inganas O, Nazeeruddin M K, Zakeeruddin S M, Graetzel M 2015 Adv. Energy Mater. 5 1400812 Google Scholar
[23]	Abate A 2017 Joule 1 659 Google Scholar
[24]	Kieslich G, Sun S, Cheetham A 2014 Chem. Sci. 5 4712 Google Scholar
[25]	Li X, Hoffman J M, Kanatzidis M G 2021 Chem. Rev. 121 2230 Google Scholar
[26]	Rajagopal A, Yao K, Jen A K Y 2018 Adv. Mater. 30 1800455 Google Scholar
[27]	Miyata A, Mitioglu A, Plochocka P, Portugall O, Wang J T W, Stranks S D, Snaith H J, Nicholas R J 2015 Nat. Phys. 11 582 Google Scholar
[28]	Liu N, Yam C 2018 Phys. Chem. Chem. Phys. 20 6800 Google Scholar
[29]	Yin W J, Shi T, Yan Y 2014 Appl. Phys. Lett. 104 063903 Google Scholar
[30]	Li W, Liu J, Bai F Q, Zhang H X, Prezhdo O V 2017 ACS Energy Lett. 2 1270 Google Scholar
[31]	Saliba M, Matsui T, Seo J Y, Domanski K, Correa-Baena J P, Nazeeruddin M K, Zakeeruddin S M, Tress W, Abate A, Hagfeldt A, Gratzel M 2016 Energy Environ. Sci. 9 1989 Google Scholar
[32]	Yin W J, Shi T, Yan Y 2014 Applied Physics Letters 104 063903
[33]	Steirer K X, Schulz P, Teeter G, Stevanovic V, Yang M, Zhu K, Berry J J 2016 ACS Energy Lett. 1 360 Google Scholar
[34]	Azpiroz J M, Mosconi E, Bisquert J, De Angelis F 2015 Energy Environ. Sci. 8 2118 Google Scholar
[35]	Yuan Y, Li T, Wang Q, Xing J, Gruverman A, Huang J 2017 Sci. Adv. 3 e1602164 Google Scholar
[36]	Hoke E T, Slotcavage D J, Dohner E R, Bowring A R, Karunadasa H I, McGehee M D 2015 Chem. Sci. 6 613 Google Scholar
[37]	Carrillo J, Guerrero A, Rahimnejad S, Almora O, Zarazua I, Mas-Marza E, Bisquert J, Garcia-Belmonte G 2016 Adv. Energy Mater. 6 1502246 Google Scholar
[38]	Shao Y, Fang Y, Li T, Wang Q, Dong Q, Deng Y, Yuan Y, Wei H, Wang M, Gruverman A 2016 Energy Environ. Sci. 9 1752 Google Scholar
[39]	Chen B, Rudd P N, Yang S, Yuan Y, Huang J 2019 Chem. Soc. Rev. 48 3842 Google Scholar
[40]	Aberle A G 2001 Solar Energy Mater. 65 239 Google Scholar
[41]	Hoex B, Schmidt J, Pohl P, Van de Sanden M, Kessels W 2008 J. Appl. Phys. 104 044903 Google Scholar
[42]	Aberle A G 2000 Prog. Photovoltaics Res. Appl. 8 473 Google Scholar
[43]	Ran C, Xu J, Gao W, Huang C, Dou S 2018 Chem. Soc. Rev. 47 4581 Google Scholar
[44]	Ross R T J T J o C P 1967 J. Chem. Phys. 46 4590 Google Scholar
[45]	Kim H S, Mora-Sero I, Gonzalez-Pedro V, Fabregat-Santiago F, Juarez-Perez E J, Park N G, Bisquert J 2013 Nat. Commun. 4 1 Google Scholar
[46]	Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511 Google Scholar
[47]	Shao Y, Xiao Z, Bi C, Yuan Y, Huang J 2014 Nat. Commun. 5 1 Google Scholar
[48]	Lin Y, Chen B, Zhao F, Zheng X, Deng Y, Shao Y, Fang Y, Bai Y, Wang C, Huang J 2017 Adv. Mater. 29 1700607 Google Scholar
[49]	Wang J, Datta K, Weijtens C H L, Wienk M M, Janssen R A J 2019 Adv. Func. Mater. 29 1905883 Google Scholar
[50]	Haddon R C 1993 Science 261 1545 Google Scholar
[51]	Xu J, Buin A, Ip A H, Li W, Voznyy O, Comin R, Yuan M, Jeon S, Ning Z, McDowell J J 2015 Nat. Commun. 6 7081 Google Scholar
[52]	Abate A, Saliba M, Hollman D J, Stranks S D, Wojciechowski K, Avolio R, Grancini G, Petrozza A, Snaith H J 2014 Nano Lett. 14 3247 Google Scholar
[53]	Yang Z, Dou J, Kou S, Dang J, Ji Y, Yang G, Wu W Q, Kuang D B, Wang M 2020 Adv. Funct. Mater. 30 1910710 Google Scholar
[54]	Lee J W, Kim H S, Park N G 2016 Acc Chem. Res. 49 311 Google Scholar
[55]	Noel N K, Abate A, Stranks S D, Parrott E S, Burlakov V M, Goriely A, Snaith H J 2014 ACS Nano 8 9815 Google Scholar
[56]	Zuo L J, Guo H X, deQuilettes D W, Jariwala S, De Marco N, Dong S Q, DeBlock R, Ginger D S, Dunn B, Wang M K, Yang Y 2017 Sci. Adv. 3 e1700106 Google Scholar
[57]	Liu L, Fang W H, Long R, Prezhdo O V 2018 J. Phys. Chem. Lett. 9 1164 Google Scholar
[58]	Hou Y, Zhou Z R, Wen T Y, Qiao H W, Lin Z Q, Ge B, Yang H G 2019 Nanoscale Horiz. 4 208 Google Scholar
[59]	Zeng Q, Zhang X, Feng X, Lu S, Chen Z, Yong X, Redfern S A, Wei H, Wang H, Shen H 2018 Adv. Mater. 30 1705393 Google Scholar
[60]	You S, Wang H, Bi S, Zhou J, Qin L, Qiu X, Zhao Z, Xu Y, Zhang Y, Shi X, Zhou H, Tang Z 2018 Adv. Mater. 30 1706924 Google Scholar
[61]	Zhu L, Zhang X, Li M, Shang X, Lei K, Zhang B, Chen C, Zheng S, Song H, Chen J 2021 Adv. Energy Mater. 11 2100529 Google Scholar
[62]	deQuilettes D W, Koch S, Burke S, Paranji R K, Shropshire A J, Ziffer M E, Ginger D S 2016 ACS Energy Lett. 1 438 Google Scholar
[63]	Wang X, Sun Y, Wang Y, Ai X C, Zhang J P 2022 J. Phys. Chem. Lett. 13 1571 Google Scholar
[64]	Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng X C, Huang J 2017 Nature Energy 2 1 Google Scholar
[65]	Zhang F, Bi D, Pellet N, Xiao C, Li Z, Berry J J, Zakeeruddin S M, Zhu K, Gratzel M 2018 Energy Environ. Sci. 11 3480 Google Scholar
[66]	Zheng X, Deng Y, Chen B, Wei H, Xiao X, Fang Y, Lin Y, Yu Z, Liu Y, Wang Q 2018 Adv. Mater. 30 1803428 Google Scholar
[67]	Bi C, Zheng X, Chen B, Wei H, Huang J 2017 ACS Energy Lett. 2 1400 Google Scholar
[68]	Abdi-Jalebi M, Andaji-Garmaroudi Z, Cacovich S, Stavrakas C, Philippe B, Richter J M, Alsari M, Booker E P, Hutter E M, Pearson A J, Lilliu S, Savenije T J, Rensmo H, Divitini G, Ducati C, Friend R H, Stranks S D 2018 Nature 555 497 Google Scholar
[69]	Zhang W, Liu H, Qi X, Yu Y, Zhou Y, Xia Y, Cui J, Shi Y, Chen R, Wang H L 2022 Adv. Sci. e2106054
[70]	Ling X, Zhou S, Yuan J, Shi J, Qian Y, Larson B W, Zhao Q, Qin C, Li F, Shi G, Stewart C, Hu J, Zhang X, Luther J M, Duhm S, Ma W 2019 Adv. Energy Mater. 9 1900721 Google Scholar
[71]	Zhang Y, Liu X, Li P, Duan Y, Hu X, Li F, Song Y 2019 Nano Energy 56 733 Google Scholar
[72]	Jung M, Shin T J, Seo J, Kim G, Seok S I 2018 Energy Environ. Sci. 11 2188 Google Scholar
[73]	Zhao T, Chueh C C, Chen Q, Rajagopal A, Jen A K Y J A E L 2016 ACS Energy Lett. 1 757 Google Scholar
[74]	Jokar E, Chien C H, Fathi A, Rameez M, Chang Y H, Diau E W G 2018 Energy Environ. Sci. 11 2353 Google Scholar
[75]	Lin Y, Bai Y, Fang Y J, Wang Q, Deng Y H, Huang J S 2017 ACS Energy Lett. 2 1571 Google Scholar
[76]	Wang Z, Lin Q, Chmiel F P, Sakai N, Herz L M, Snaith H J 2017 Nature Energy 2 17135 Google Scholar
[77]	Lee D, Yun J S, Kim J, Soufiani A M, Chen S, Cho Y, Deng X F, Seidel J, Lim S, Huang S J, Ho-Baillie A W Y 2018 ACS Energy Lett. 3 647 Google Scholar
[78]	Grancini G, Roldán-Carmona C, Zimmermann I, Mosconi E, Lee X, Martineau D, Narbey S, Oswald F, De Angelis F, Graetzel M 2017 Nat. Commun. 8 1 Google Scholar
[79]	Pool V L, Gold-Parker A, McGehee M D, Toney M F 2015 Chem. Mater. 27 7240 Google Scholar
[80]	Luo Y, Gamliel S, Nijem S, Aharon S, Holt M, Stripe B, Rose V, Bertoni M I, Etgar L, Fenning D P 2016 Chem. Mater. 28 6536 Google Scholar
[81]	Nan G J, Zhang X, Abdi-Jalebi M, Andaji-Garmaroudi Z, Stranks S D, Lu G, Beljonne D 2018 Adv. Energy Mater. 8 1702754 Google Scholar
[82]	Chen Q, Zhou H, Fang Y, Stieg A Z, Song T B, Wang H H, Xu X, Liu Y, Lu S, You J 2015 Nat. Commun. 6 7269 Google Scholar
[83]	Son D Y, Lee J W, Choi Y J, Jang I H, Lee S, Yoo P J, Shin H, Ahn N, Choi M, Kim D 2016 Nature Energy 1 1 Google Scholar
[84]	Yi H, Duan L, Haque F, Bing J, Zheng J, Yang Y, Mo A C H, Zhang Y, Xu C, Conibeer G, Uddin A 2020 J. Power Sources 466 228320 Google Scholar
[85]	Zhang J, Wu S, Liu T, Zhu Z, Jen A K Y 2019 Adv. Funct. Mater. 29 1808833 Google Scholar
[86]	Chen J, Kim S G, Park N G 2018 Adv. Mater. 30 1801948 Google Scholar
[87]	Jokar E, Chuang H S, Kuan C H, Wu H P, Hou C H, Shyue J J, Wei-Guang Diau E 2021 J. Phys. Chem. Lett. 12 10106 Google Scholar
[88]	Yang Y M, Chen X, Liu S, Zhu H, Wang W, Kuang C, Liu X 2021 J. Phys. Chem. C 125 12560 Google Scholar
[89]	Sun Y, Peng J, Chen Y, Yao Y, Liang Z 2017 Sci. Rep. 7 46193 Google Scholar
[90]	Yang S, Liu W, Zuo L, Zhang X, Ye T, Chen J, Li C Z, Wu G, Chen H 2016 J. Mater. Chem. A 4 9430 Google Scholar
[91]	Kim M K, Jeon T, Park H I, Lee J M, Nam S A, Kim S O 2016 CrystEngComm 18 6090 Google Scholar
[92]	Han Q, Bai Y, Liu J, Du K-z, Li T, Ji D, Zhou Y, Cao C, Shin D, Ding J, Franklin A D, Glass J T, Hu J, Therien M J, Liu J, Mitzi D B 2017 Energy Environ. Sci. 10 2365 Google Scholar
[93]	Zhang X, Wu G, Fu W, Qin M, Yang W, Yan J, Zhang Z, Lu X, Chen H 2018 Adv. Energy Mater. 8 1702498 Google Scholar
[94]	Zhang X, Wu G, Yang S, Fu W, Zhang Z, Chen C, Liu W, Yan J, Yang W, Chen H 2017 Small 13 1700611 Google Scholar
[95]	Chen J, Rong Y, Mei A, Xiong Y, Liu T, Sheng Y, Jiang P, Hong L, Guan Y, Zhu X, Hou X, Duan M, Zhao J, Li X, Han H 2016 Adv. Energy Mater. 6 1502009 Google Scholar
[96]	Yang L, Ma X, Shang X, Gao D, Wang C, Li M, Chen C, Zhang B, Xu S, Zheng S, Song H 2021 Solar RRL 5 2100352 Google Scholar
[97]	Bi H, Liu B, He D, Bai L, Wang W, Zang Z, Chen J 2021 Chem. Eng. J. 418
[98]	Wang Z, Wu T, Xiao L, Qin P, Yu X, Ma L, Xiong L, Li H, Chen X, Wang Z, Wu T, Xiao M L, Qin P, Yu D X, Ma D L, Xiong D L, Li D H, Chen X 2021 J. Power Sources 488 229451 Google Scholar
[99]	Wu Q, Zhou W, Liu Q, Zhou P, Chen T, Lu Y, Qiao Q, Yang S 2016 ACS Appl. Mater. Interfaces 8 34464 Google Scholar
[100]	Goh S, Jang G, Ma S, Park J, Ban H, Lee C U, Lee J, Moon J 2021 ACS Sustainable Chem. Eng. 9 16730 Google Scholar
[101]	Zhang C, Wang H, Li H, Zhuang Q, Gong C, Hu X, Cai W, Zhao S, Chen J, Zang Z 2021 J. Energy Chem. 63 452 Google Scholar
[102]	Wang K, Ma S, Xue X, Li T, Sha S, Ren X, Zhang J, Lu H, Ma J, Guo S, Liu Y, Feng J, Najar A, Liu S F 2022 Adv. Sci. e2105103 Google Scholar
[103]	Chen Q, Zhou H, Song T B, Luo S, Hong Z, Duan H S, Dou L, Liu Y, Yang Y 2014 Nano Lett. 14 4158 Google Scholar
[104]	Lin Y, Bai Y, Fang Y J, Chen Z L, Yang S, Zheng X P, Tang S, Liu Y, Zhao J J, Huang J S 2018 J. Phys. Chem. Lett. 9 654 Google Scholar
[105]	Hu Y, Schlipf J, Wussler M, Petrus M L, Jaegermann W, Bein T, Müller-Buschbaum P, Docampo P 2016 ACS Nano 10 5999 Google Scholar
[106]	Ma X, Yang L, Shang X, Li M, Gao D, Wu C, Zheng S, Zhang B, Chen J, Chen C, Song H 2021 Chem. Eng. J. 426 130685 Google Scholar
[107]	Chen C, Li F, Zhu L, Shen Z, Weng Y, Lou Q, Tan F, Yue G, Huang Q, Wang M 2020 Nano Energy 68 104313 Google Scholar
[108]	Kim H, Lee J W, Han G R, Kim S K, Oh J H 2020 Adv. Funct. Mater. 31 2008801 Google Scholar
[109]	Cai S, Dai J, Shao Z, Rothmann M U, Jia Y, Gao C, Hao M, Pang S, Wang P, Lau S P, Zhu K, Berry J J, Herz L M, Zeng X C, Zhou Y 2022 J. Am. Chem. Soc. 144 1910 Google Scholar
[110]	Zhang Y, Wang Y, Yang X, Zhao L, Su R, Wu J, Luo D, Li S, Chen P, Yu M, Gong Q, Zhu R 2022 Adv. Mater. 34 2107420 Google Scholar

[1]	Luo Pan, Li Xiang, Sun Xue-Yin, Tan Xiao-Hong, Luo Jun, Zhen Liang. Effect of electron irradiation on perovskite films and devices for novel space solar cells. Acta Physica Sinica, 2024, 73(3): 036102. doi: 10.7498/aps.73.20231568
[2]	Juan Ting, Xing Jia-He, Zeng Fan-Cong, Zheng Xin, Xu Lin. Performance of perovskite solar cells based on SnO₂:DPEPO hybrid electron transport layer. Acta Physica Sinica, 2024, 73(19): 198401. doi: 10.7498/aps.73.20240827
[3]	Zhang Xiao-Chun, Wang Li-Kun, Shang Wen-Li, Wan Zheng-Hui, Yue Xin, Yang Hua-Yi, Li Ting, Wang Hui. Fabrication of high-performance inverted perovskite solar cells based on dual modification strategy. Acta Physica Sinica, 2024, 73(24): 248401. doi: 10.7498/aps.73.20241238
[4]	Wang Hui, Zheng De-Xu, Jiang Xiao, Cao Yue-Xian, Du Min-Yong, Wang Kai, Liu Sheng-Zhong, Zhang Chun-Fu. Fabrication of high-performance flexible perovskite solar cells based on synergistic passivation strategy. Acta Physica Sinica, 2024, 73(7): 078401. doi: 10.7498/aps.73.20231846
[5]	Wang Jing, Gao Shan, Duan Xiang-Mei, Yin Wan-Jian. Influence of defect in perovskite solar cell materials on device performance and stability. Acta Physica Sinica, 2024, 73(6): 063101. doi: 10.7498/aps.73.20231631
[6]	Yang Mei-Li, Zou Li, Cheng Jia-Jie, Wang Jia-Ming, Jiang Yu-Fan, Hao Hui-Ying, Xing Jie, Liu Hao, Fan Zhen-Jun, Dong Jing-Jing. Improvement of performance of CsPbBr₃ perovskite solar cells by polyvinylidene fluoride additive. Acta Physica Sinica, 2023, 72(16): 168101. doi: 10.7498/aps.72.20230636
[7]	Li Pei, Xu Jie, He Chao-Hui, Liu Jia-Xin. Experimental study on irradiation of perovskite solar cells. Acta Physica Sinica, 2023, 72(12): 126101. doi: 10.7498/aps.72.20230230
[8]	Zhu Yong-Qi, Liu Yu-Xue, Shi Yang, Wu Cong-Cong. High performance perovskite solar cells synthesized by dissolving FAPbI₃ single crystal. Acta Physica Sinica, 2023, 72(1): 018801. doi: 10.7498/aps.72.20221461
[9]	Meng Jing, Gao Bo-Wen. Photovoltaic performance optimization of integrated perovskite/organic solar cells based on PM6:Y6 polymer non-fullerene system. Acta Physica Sinica, 2023, 72(12): 128801. doi: 10.7498/aps.72.20230081
[10]	Zhou Yang, Ren Xin-Gang, Yan Ye-Qiang, Ren Hao, Du Hong-Mei, Cai Xue-Yuan, Huang Zhi-Xiang. Physical mechanism of perovskite solar cell based on double electron transport layer. Acta Physica Sinica, 2022, 71(20): 208802. doi: 10.7498/aps.71.20220725
[11]	Sun Meng-Jie, He Zhi-Qun, Zheng Yi-Fan, Shao Yu-Chuan. Application of EDTA/SnO₂ double-layer composite electron transport layer to perovskite solar cells. Acta Physica Sinica, 2022, 71(13): 137201. doi: 10.7498/aps.71.20220074
[12]	Liu Yu-Xue, Ming Yi-Dong, Wu Cong-Cong. Properties and improvements of chlorine-doped methylamine-based perovskites. Acta Physica Sinica, 2022, 71(20): 207303. doi: 10.7498/aps.71.20220966
[13]	Gao Jiu-Lin, Lian Ya-Jun, Yang Ye, Li Guo-Qing, Yang Xiao-Hui. High-efficiency sky blue perovskite light-emitting diodes with ammonium thiocyanate additive. Acta Physica Sinica, 2021, 70(19): 198502. doi: 10.7498/aps.70.20211046
[14]	Wang Pei-Pei, Zhang Chen-Xi, Hu Li-Na, Li Shi-Qi, Ren Wei-Hua, Hao Yu-Ying. Research progress of inverted planar perovskite solar cells based on nickel oxide as hole transport layer. Acta Physica Sinica, 2021, 70(11): 118801. doi: 10.7498/aps.70.20201896
[15]	Wang Yan-Bo, Cui Dan-Yu, Zhang Cai-Yi, Han Li-Yuan, Yang Xu-Dong. Recent advances in perovskite solar cells: Space potential and optoelectronic conversion mechanism. Acta Physica Sinica, 2019, 68(15): 158401. doi: 10.7498/aps.68.20190569
[16]	Li Xiao-Guo, Zhang Xin, Shi Ze-Jiao, Zhang Hai-Juan, Zhu Cheng-Jun, Zhan Yi-Qiang. Research progress of interface passivation of n-i-p perovskite solar cells. Acta Physica Sinica, 2019, 68(15): 158803. doi: 10.7498/aps.68.20190468
[17]	Yang Ying-Guo, Yin Guang-Zhi, Feng Shang-Lei, Li Meng, Ji Geng-Wu, Song Fei, Wen Wen, Gao Xing-Yu. An in-situ real time study of the perovskite film micro-structural evolution in a humid environment by using synchrotron based characterization technique. Acta Physica Sinica, 2017, 66(1): 018401. doi: 10.7498/aps.66.018401
[18]	Chai Lei, Zhong Min. Recent research progress in perovskite solar cells. Acta Physica Sinica, 2016, 65(23): 237902. doi: 10.7498/aps.65.237902
[19]	Shi Jiang-Jian, Wei Hui-Yun, Zhu Li-Feng, Xu Xin, Xu Yu-Zhuan, Lü Song-Tao, Wu Hui-Jue, Luo Yan-Hong, Li Dong-Mei, Meng Qing-Bo. S-shaped current-voltage characteristics in perovskite solar cell. Acta Physica Sinica, 2015, 64(3): 038402. doi: 10.7498/aps.64.038402
[20]	Ting Hung-Kit, Ni Lu, Ma Sheng-Bo, Ma Ying-Zhuang, Xiao Li-Xin, Chen Zhi-Jian. progress in electron-transport materials in application of perovskite solar cells. Acta Physica Sinica, 2015, 64(3): 038802. doi: 10.7498/aps.64.038802

Catalog

Vol. 71, Issue 16 - 2022-08-20

Metrics

Abstract views: 29888
PDF Downloads: 1544
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板