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Fe-based amorphous alloys have continuously attracted extensive attention due to their excellent soft magnetic properties, such as high saturation magnetization, high permeability, low coercivity, and low core loss. However, the theoretical studies on the magnetism of amorphous alloys remain incomplete, and the structural origins of the magnetic properties in Fe-based amorphous alloys are still unclear, making it difficult to fully explain their magnetic behavior. Accordingly, this review summarizes recent experimental and computational progress in exploring potential correlation mechanisms between amorphous structures and soft-magnetic properties. Existing research has primarily focused on how different elements affect the electronic structure, magnetic moment, saturation magnetization, and other properties of iron-based amorphous alloys. However, little effort has been devoted to the in-depth exploration into the underlying mechanisms of the local atomic structures, including short-range and medium-range order, influence magnetic properties. This review aims to provide a reference for further elucidating the structural origins of magnetic properties in Fe-based amorphous alloys, while also identifying key unresolved issues in future research.
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Keywords:
- Fe-based amorphous alloys /
- soft magnetism /
- structural origin /
- amorphous alloys
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