Preparation and electrochemical properties of Co2SnO4/graphene composites

Chen Chang; Ru Qiang; Hu She-Jun; An Bo-Nan; Song Xiong

doi:10.7498/aps.63.198201

Abstract

Co2SnO4/graphene composite has been prepared by multi-step synthetic process. Firstly, the formation of Co2SnO4 and the reduction of graphene oxide (GO) occur simultaneously during the hydrothermal process and the Co2SnO4 particles are uniformly embedded in the film-like graphene to form a mosaic structure. To characterize the phase and morphology of the composite material, X-ray diffraction (XRD), scanning electron microscope (SEM) are used. The constant current charge and discharge (CC), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are also used to test the electrochemical performance of Co2SnO4/graphene composite. Results show that graphene can effectively improve the electrochemical performance of Co2SnO4/graphene composite by its good dispersibility and high electrical conductivity. The composite material exhibits a first discharge specific capacity of 1415.2 mA·h/g with the specific capacity still higher than 469.7 mA·h/g after 50 cycles.

Keywords:

Authors and contacts

1.
Laboratory of Quantum Information Technology, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006, China;Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), Guangzhou 510006, China
Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51101062, 51171065), the Science and Technology Project of Guangzhou City, China (Grant No. 2011J4100075), the Foundation for Distinguished Young Talents in Higher Education of Guangdong, China (Grant No. LYM09052), the Natural Science Foundation of Guangdong Province, China (Grant Nos. S2012020010937, 10351063101000001), and the Graduate Student Research Innovation Fund of South China Normal University (Grant No. 2013KYJJ039).

References

[1]	Ostrovskii D, Scrosati B, Jacobsson P 1995 Nature 103 10
[2]	Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J M 2000 Nature 407 496
[3]	Cabana J, Monconduit L, Larcher D, Palacin MR 2010 Adv. Mater. 22 E170
[4]	Liang C, Gao M X, Pan H G, Liu Y F, Yan M 2013 J. Alloys Comp. 575 246
[5]	Zhang Q, Huang J Q, Qian W Z, Zhang Y Y, Wei F 2013 Small 9 1237
[6]	Datta M K, Kumta P N 2007 J. Power Sources 165 368
[7]	Hou X H, Yu H W, Hu S J 2010 Acta Phys. Sin. 59 8226(in Chinese) [侯贤华, 余洪文, 胡社军 2010 物理学报 59 8226]
[8]	Zheng M T, Liu Y L, Xiao Y, Dong H W, Feng H B, Zhang H R, Lei B F 2013 ACS Appl. Mater. Inter. 5 12561
[9]	Needham S A, Wang G X, Konstantinov K, Tournayre Y, Lao Z, Liu H K 2006 Electrochem. Solid. St. 9 A315
[10]	Dong X C, Xu H, Wang X W, Huang Y X, Mary B. Chan-Park, Zhang H, Wang L H, Huang W, Chen P 2012 ACS Nano. 6 3206
[11]	Cheng J L, Xin H L, Zheng H M, Wang B 2013 J. Power Sources 232 152
[12]	Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J M 2000 Nature 407 496
[13]	Courtney I A, Dahn J R 1997 J. Electrochem. Soc. 144 2943
[14]	Wang G, Gao X P, Shen P W 2009 J. Power Sources 192 719
[15]	Yue Q, Ning D, Hui Z, Ping W, Yang D R 2011 J. Power Sources 196 10234
[16]	Wang G, Liu Z Y, Liu P 2011 Electrochim. Acta. 56 9515
[17]	Wang R, He F, Wan Y Z, Qi Y 2012 J. Alloys Compd. 514 35
[18]	Zhao D L, Zhang J M, Li X, Shen Z M 2010 J. Alloys Compd. 505 712
[19]	Ampoumogli A, Steriotis T, Trikalitis P, Giasafaki D, Bardaji E G, Fichtner M, Charalambopoulou G 2011 J. Alloys Compd. 509 S705
[20]	Zhu Y W, Murali S, Stoller M D, Ganesh K J, Cai W W, Ferreira P J, Pirkle A, Wallace R M, Cychosz K A, Thommes M, Su D, Stach E A, Ruoff R S 2011 Science 332 1537
[21]	Yeh T S, Wu Y S and LeeY H 2012 J. Alloys Compd. 515 90
[22]	Zhu Y W, Murali S, Cai W W, Li X S, Suk J W, Potts J R, Ruoff R S 2010 Adv. Mater. 22 3906
[23]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A 2004 Science 306 666
[24]	Geim A K, Novoselov K S 2007 Nature Materials 6 183
[25]	Geim A K 2009 Science 324 1530
[26]	Hernandez Y, Nicolosi V, Lotya M 2008 Nat. Nanotechnol. 3 563
[27]	Uhm S, Tuyen N H, Lee J 2011 Electrochem. Commun. 13 677
[28]	Vincent C T, Matthew J A, Yang Y, Richard B K 2009 Nature Nanotech. 329 25
[29]	McAllister M J, Li J L, Adamson D H, Schniepp H C 2007 Chem. Mater. 19 4396
[30]	Qin M M, Ji W, Feng Y Y, Feng W 2014 Chin. Phys. B 23 028103
[31]	Wang X L, Han W Q 2010 Appl. Mater. Interfaces 2 3709
[32]	Li Z P, Men C L, Wang W, Cao J 2014 Chin. Phys. B 23 057205
[33]	Wu Y P, Jiang C, Wan C, Holze R 2002 J. Power Sources 112 255
[34]	Chen D, Feng H B, Li J H 2012 Chem. Rev. 112 6027
[35]	Qi Y, Du N, Zhang H, Wu P, Yang D R 2011 J. Power Sources 196 10234
[36]	Chang C C, Liu S J, Wu J J, Yang C H 2007 J. Phys. Chem. C 111 16423
[37]	Marcinek M, Hardwick L J, Richardson T J, Song X, Kostecki R 2007 J. Power Sources 173 965
[38]	Sharma Y, Sharma N, Rao G V S, Chowdari B V R 2007 J. Power Sources 173 495
[39]	Chen J S, Cheah Y L, Chen Y T, Jayaprakash N, Madhavi S, Yang Y H, Lou X W 2009 J. Phys. Chem. C 113 20504
[40]	Wu P, Du N, Zhang H, Yu J X, Yang D R 2011 J. Phys. Chem. C 115 3612
[41]	Lavela P, Ortiz G F, Tirado J L, Zhecheva E, Stoyanova R, Ivanova S 2007 J. Phys. Chem. C 111 14238
[42]	Aurbach D, Nimberger A, Markovsky B, Levi E, Sominski E, Gedanken A 2002 Chem. Mater. 14 4155
[43]	Du N, Zhang H, Chen B D, Wu J B, Ma X Y, Liu Z H, Zhang Y Q, Yang D R, Huang X H, Tu J P 2007 Adv. Mater. 19 4505
[44]	Xue M Z, Fu Z W 2006 Electrochem. Solid-State Lett. 9 A468
[45]	Alcantara R, Ortiz G F, Lavela P, Tirado J L 2006 Electrochem. Commun. 8 731
[46]	Choi H C, Lee S Y, Kim S B, Kim M G, Lee M K, Shin H J, Lee J S 2002 J. Phys. Chem. B 106 9252
[47]	Liu H C, Yen S K 2007 J. Power Sources 166 478
[48]	Maier J 2005 Nat. Mater. 4 805
[49]	Huang X H, Tu J P, Zhang C Q, Xiang J Y 2007 Electrochem. Commun. 9 1180
[50]	Yang S B, Song H H, Chen X H 2006 Electrochem. Commun. 8 137
[51]	Zhang J J, Liang J W, Zhu Y C, Wei D H, Fan L, Qian Y T 2014 J. Mater. Chem. A 2 2728

Cited By

[1]	Ostrovskii D, Scrosati B, Jacobsson P 1995 Nature 103 10
[2]	Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J M 2000 Nature 407 496
[3]	Cabana J, Monconduit L, Larcher D, Palacin MR 2010 Adv. Mater. 22 E170
[4]	Liang C, Gao M X, Pan H G, Liu Y F, Yan M 2013 J. Alloys Comp. 575 246
[5]	Zhang Q, Huang J Q, Qian W Z, Zhang Y Y, Wei F 2013 Small 9 1237
[6]	Datta M K, Kumta P N 2007 J. Power Sources 165 368
[7]	Hou X H, Yu H W, Hu S J 2010 Acta Phys. Sin. 59 8226(in Chinese) [侯贤华, 余洪文, 胡社军 2010 物理学报 59 8226]
[8]	Zheng M T, Liu Y L, Xiao Y, Dong H W, Feng H B, Zhang H R, Lei B F 2013 ACS Appl. Mater. Inter. 5 12561
[9]	Needham S A, Wang G X, Konstantinov K, Tournayre Y, Lao Z, Liu H K 2006 Electrochem. Solid. St. 9 A315
[10]	Dong X C, Xu H, Wang X W, Huang Y X, Mary B. Chan-Park, Zhang H, Wang L H, Huang W, Chen P 2012 ACS Nano. 6 3206
[11]	Cheng J L, Xin H L, Zheng H M, Wang B 2013 J. Power Sources 232 152
[12]	Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J M 2000 Nature 407 496
[13]	Courtney I A, Dahn J R 1997 J. Electrochem. Soc. 144 2943
[14]	Wang G, Gao X P, Shen P W 2009 J. Power Sources 192 719
[15]	Yue Q, Ning D, Hui Z, Ping W, Yang D R 2011 J. Power Sources 196 10234
[16]	Wang G, Liu Z Y, Liu P 2011 Electrochim. Acta. 56 9515
[17]	Wang R, He F, Wan Y Z, Qi Y 2012 J. Alloys Compd. 514 35
[18]	Zhao D L, Zhang J M, Li X, Shen Z M 2010 J. Alloys Compd. 505 712
[19]	Ampoumogli A, Steriotis T, Trikalitis P, Giasafaki D, Bardaji E G, Fichtner M, Charalambopoulou G 2011 J. Alloys Compd. 509 S705
[20]	Zhu Y W, Murali S, Stoller M D, Ganesh K J, Cai W W, Ferreira P J, Pirkle A, Wallace R M, Cychosz K A, Thommes M, Su D, Stach E A, Ruoff R S 2011 Science 332 1537
[21]	Yeh T S, Wu Y S and LeeY H 2012 J. Alloys Compd. 515 90
[22]	Zhu Y W, Murali S, Cai W W, Li X S, Suk J W, Potts J R, Ruoff R S 2010 Adv. Mater. 22 3906
[23]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A 2004 Science 306 666
[24]	Geim A K, Novoselov K S 2007 Nature Materials 6 183
[25]	Geim A K 2009 Science 324 1530
[26]	Hernandez Y, Nicolosi V, Lotya M 2008 Nat. Nanotechnol. 3 563
[27]	Uhm S, Tuyen N H, Lee J 2011 Electrochem. Commun. 13 677
[28]	Vincent C T, Matthew J A, Yang Y, Richard B K 2009 Nature Nanotech. 329 25
[29]	McAllister M J, Li J L, Adamson D H, Schniepp H C 2007 Chem. Mater. 19 4396
[30]	Qin M M, Ji W, Feng Y Y, Feng W 2014 Chin. Phys. B 23 028103
[31]	Wang X L, Han W Q 2010 Appl. Mater. Interfaces 2 3709
[32]	Li Z P, Men C L, Wang W, Cao J 2014 Chin. Phys. B 23 057205
[33]	Wu Y P, Jiang C, Wan C, Holze R 2002 J. Power Sources 112 255
[34]	Chen D, Feng H B, Li J H 2012 Chem. Rev. 112 6027
[35]	Qi Y, Du N, Zhang H, Wu P, Yang D R 2011 J. Power Sources 196 10234
[36]	Chang C C, Liu S J, Wu J J, Yang C H 2007 J. Phys. Chem. C 111 16423
[37]	Marcinek M, Hardwick L J, Richardson T J, Song X, Kostecki R 2007 J. Power Sources 173 965
[38]	Sharma Y, Sharma N, Rao G V S, Chowdari B V R 2007 J. Power Sources 173 495
[39]	Chen J S, Cheah Y L, Chen Y T, Jayaprakash N, Madhavi S, Yang Y H, Lou X W 2009 J. Phys. Chem. C 113 20504
[40]	Wu P, Du N, Zhang H, Yu J X, Yang D R 2011 J. Phys. Chem. C 115 3612
[41]	Lavela P, Ortiz G F, Tirado J L, Zhecheva E, Stoyanova R, Ivanova S 2007 J. Phys. Chem. C 111 14238
[42]	Aurbach D, Nimberger A, Markovsky B, Levi E, Sominski E, Gedanken A 2002 Chem. Mater. 14 4155
[43]	Du N, Zhang H, Chen B D, Wu J B, Ma X Y, Liu Z H, Zhang Y Q, Yang D R, Huang X H, Tu J P 2007 Adv. Mater. 19 4505
[44]	Xue M Z, Fu Z W 2006 Electrochem. Solid-State Lett. 9 A468
[45]	Alcantara R, Ortiz G F, Lavela P, Tirado J L 2006 Electrochem. Commun. 8 731
[46]	Choi H C, Lee S Y, Kim S B, Kim M G, Lee M K, Shin H J, Lee J S 2002 J. Phys. Chem. B 106 9252
[47]	Liu H C, Yen S K 2007 J. Power Sources 166 478
[48]	Maier J 2005 Nat. Mater. 4 805
[49]	Huang X H, Tu J P, Zhang C Q, Xiang J Y 2007 Electrochem. Commun. 9 1180
[50]	Yang S B, Song H H, Chen X H 2006 Electrochem. Commun. 8 137
[51]	Zhang J J, Liang J W, Zhu Y C, Wei D H, Fan L, Qian Y T 2014 J. Mater. Chem. A 2 2728

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Vol. 63, Issue 19 - 2014-10-05

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