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Model of the relationship between properties and phase composition of zirconia solid electrolyte

Hu Yong-Gang Xiao Jian-Zhong Xia Feng Wu Xi-Wang Yan Shuang-Zhi

Model of the relationship between properties and phase composition of zirconia solid electrolyte

Hu Yong-Gang, Xiao Jian-Zhong, Xia Feng, Wu Xi-Wang, Yan Shuang-Zhi
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  • The relative content of each phase at room temperature and the ratio of transformable phase at high temperature of zirconia solid electrolyte are important to its thermal shock resistance and electrical conductivity. The match of thermal shock resistance and electrical conductivity plays an important role in measuring the lower oxygen activity in molten steel. A linear model between the thermal shock resistance and the phase composition at room temperature is proposed based on this concept, another evolved relationship between the pyroconductivity and the elevated temperature transformation is also proposed. These models provide theoretical reference for the preparation of the high precision oxygen sensor for measuring the lower partial pressure of oxygen in molten steel.
    [1]

    Xiang J, Wang X H 2008 Acta Phys. Sin. 58 4417 (in Chinese) [向 军、王晓晖 2008 物理学报 58 4417]

    [2]

    Xiang J, Li L P, Su W H 2003 Acta Phys. Sin. 52 1474 (in Chinese) [向 军、李莉萍、苏文辉 2003 物理学报 52 1474]

    [3]

    Caproni E, Carvalho F M S, Muccillo R 2008 Solid State Ion. 179 1652

    [4]

    Maier J 1995 Prog. Solid State Chem. 23 171

    [5]

    Li F S, Tang Y H, Li L F 1996 Solid State Ion. 88 1027

    [6]

    Liu Q G, An S L, Qiu W H 1999 Solid State Ion. 121 61

    [7]

    Huang K Q, Xia Y H, Wu W J, Liu Q G 1994 J. Chin. Silic. Soc. 22 195 (in Chinese) [黄克勤、夏玉华、吴卫江、刘庆国 1994 硅酸盐学报 22 195]

    [8]

    Kong X H 2001 (Ph. D. Dissertation) (Beijing: University of Science and Technology Beijing) (in Chinese) [孔祥华 2001 博士学位论文(北京:北京科技大学)] 〖9] Bu Dc' ko M M 2004 J. Eur. Ceram. Soc. 24 1305

    [9]

    Guo X, Yuan R Z, Sun R Q, Cui K 1996 Acta Phys. Sin. 45 860 (in Chinese) [郭 新、袁润章、孙尧卿、崔 崑 1996 物理学报 45 860]

    [10]

    Zhou Z H, Ding P D, Chen P, Yi Y 2002 Mater. Sci. Engng. 1 35 (in Chinese) [周泽华、丁培道、陈 蓓、易 于 2002 材料科学与工程 1 35]

    [11]

    Wu X H, Xiang J Z 2002 Morden Material Numeration and Design (Beijing:Publishing House of Electronics Industry) pp200—233 (in Chinese) [吴兴惠、项金钟 2002 现代材料计算与设计教程(北京:电子工业出版社)第200—233页]

    [12]

    Muccillo R, Muccillo E N S, Saito N H 1998 Mater. Lett. 34 128

    [13]

    Gao Y M, Guo X M, Zhou G Z 2005 J. Wuhan Univ. Sci. Tec. (Nat. Sci. E) 3 237 (in Chinese) [高运明、郭兴敏、周国治 2005 武汉科技大学学报(自然科学版) 3 237]

    [14]

    Zhu W Z 1996 Ceram. Int. 22 389

    [15]

    An S L, Wu W J, Liu Q G 1988 Solid State Ion. 28/30 546

    [16]

    An S L, Zhou T P, Wu W J, Liu Q G 1990 Solid State Ion. 40/41 750

  • [1]

    Xiang J, Wang X H 2008 Acta Phys. Sin. 58 4417 (in Chinese) [向 军、王晓晖 2008 物理学报 58 4417]

    [2]

    Xiang J, Li L P, Su W H 2003 Acta Phys. Sin. 52 1474 (in Chinese) [向 军、李莉萍、苏文辉 2003 物理学报 52 1474]

    [3]

    Caproni E, Carvalho F M S, Muccillo R 2008 Solid State Ion. 179 1652

    [4]

    Maier J 1995 Prog. Solid State Chem. 23 171

    [5]

    Li F S, Tang Y H, Li L F 1996 Solid State Ion. 88 1027

    [6]

    Liu Q G, An S L, Qiu W H 1999 Solid State Ion. 121 61

    [7]

    Huang K Q, Xia Y H, Wu W J, Liu Q G 1994 J. Chin. Silic. Soc. 22 195 (in Chinese) [黄克勤、夏玉华、吴卫江、刘庆国 1994 硅酸盐学报 22 195]

    [8]

    Kong X H 2001 (Ph. D. Dissertation) (Beijing: University of Science and Technology Beijing) (in Chinese) [孔祥华 2001 博士学位论文(北京:北京科技大学)] 〖9] Bu Dc' ko M M 2004 J. Eur. Ceram. Soc. 24 1305

    [9]

    Guo X, Yuan R Z, Sun R Q, Cui K 1996 Acta Phys. Sin. 45 860 (in Chinese) [郭 新、袁润章、孙尧卿、崔 崑 1996 物理学报 45 860]

    [10]

    Zhou Z H, Ding P D, Chen P, Yi Y 2002 Mater. Sci. Engng. 1 35 (in Chinese) [周泽华、丁培道、陈 蓓、易 于 2002 材料科学与工程 1 35]

    [11]

    Wu X H, Xiang J Z 2002 Morden Material Numeration and Design (Beijing:Publishing House of Electronics Industry) pp200—233 (in Chinese) [吴兴惠、项金钟 2002 现代材料计算与设计教程(北京:电子工业出版社)第200—233页]

    [12]

    Muccillo R, Muccillo E N S, Saito N H 1998 Mater. Lett. 34 128

    [13]

    Gao Y M, Guo X M, Zhou G Z 2005 J. Wuhan Univ. Sci. Tec. (Nat. Sci. E) 3 237 (in Chinese) [高运明、郭兴敏、周国治 2005 武汉科技大学学报(自然科学版) 3 237]

    [14]

    Zhu W Z 1996 Ceram. Int. 22 389

    [15]

    An S L, Wu W J, Liu Q G 1988 Solid State Ion. 28/30 546

    [16]

    An S L, Zhou T P, Wu W J, Liu Q G 1990 Solid State Ion. 40/41 750

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  • Received Date:  19 November 2009
  • Accepted Date:  28 December 2009
  • Published Online:  15 October 2010

Model of the relationship between properties and phase composition of zirconia solid electrolyte

  • 1. (1)Department of Materials Science and Engineering,Huazhong University of Science and Technology,Wuhan 430074, China; (2)Sinosteel Corporation Luoyang Institute of Refractories Research,Luoyang 471039, China

Abstract: The relative content of each phase at room temperature and the ratio of transformable phase at high temperature of zirconia solid electrolyte are important to its thermal shock resistance and electrical conductivity. The match of thermal shock resistance and electrical conductivity plays an important role in measuring the lower oxygen activity in molten steel. A linear model between the thermal shock resistance and the phase composition at room temperature is proposed based on this concept, another evolved relationship between the pyroconductivity and the elevated temperature transformation is also proposed. These models provide theoretical reference for the preparation of the high precision oxygen sensor for measuring the lower partial pressure of oxygen in molten steel.

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