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Preparation and near-infrared luminescence properties of Bi2O3-B2O3-BaO glasses

Liu Jun-Fang Su Liang-Bi Xu Jun

Preparation and near-infrared luminescence properties of Bi2O3-B2O3-BaO glasses

Liu Jun-Fang, Su Liang-Bi, Xu Jun
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  • xBi2O3-50B2O3-(50-x)BaO glasses are prepared by melting method. Their infrared luminescence spectra, fluorescence decay curves and Raman scattering spectra are measured. No obvious near-infrared (NIR) luminescence is observed in 50Bi2O3-50B2O3 glass under 808 nm laser diode (LD) pumping. Adding BaO, broadband NIR luminescences are observed in 40Bi2O3-50B2O3-10BaO glass, 45Bi2O3-50B2O3-5BaO glass and 49Bi2O3-50B2O3-1BaO glass. With the increase of BaO concentration, no obvious NIR luminescences are observed in 30Bi2O3-50B2O3-20BaO glass, 20Bi2O3-50B2O3-30BaO glass and 10Bi2O3-50B2O3-40BaO glass. The NIR emissions with several emission peaks appear in 0.5Bi2O3-50B2O3-50BaO glass and 1Bi2O3-50B2O3-50BaO glass. The mechanism for the emission is investigated preliminarily.
    • Funds: Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 61008045) and the Fundamental Research Funds for the Central Universities, China.
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    S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407

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    Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122

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    Xia H P, Wang X J 2006 Optics Communications 268 75

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    [21]

    Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504

    [22]

    Xu J, Zhao H Y, Su L B 2010 Opt. Express 18 3385

    [23]

    Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325

    [24]

    Ruan J, Su L B, Qiu J R 2009 Opt. Express 17 5136

    [25]

    Dvoyrin V V, Mashinsky V M, Dianov A A 2005 31st European Conference on Optics Communication Glasgow, Scotland 4 949

    [26]

    Yang Z W, Liu Z L, Song Z G 2011 Materials Research Innovations 15 264

    [27]

    Zhou D C, Liu Z L. Song Z G 2012 Acta Phys. Sin. 61 127802 (in Chinese) [周大成, 刘志亮, 宋志国 2012 物理学报 61 127802]

    [28]

    Zhang N, Qiu J R, Dong G P 2012 Journal of Materials Chemistry 22 3153

    [29]

    Alexey N R, Zukhra T F, Alexander A V 2012 Opt. Expres 20 7212

    [30]

    Alexey N R, Zukhra T F, Denis M Z 2011 Optical Materials 33 631

    [31]

    Guo X, Li H J, Su LB 2012 Optical Materials 34 675

    [32]

    Yu P S, Su LB, Zhao H Y 2011 Optical Materials 33 831

    [33]

    Baia L, Stefan Rn, Kiefer W 2002 Journal of Non-Crystalline Solids 303 379

    [34]

    Liu J F, Su LB Xu J 2012 Acta Phys. Sin. 61 127806 (in Chinese) [刘军芳, 苏良碧, 徐军 2012 物理学报 61 127806]

    [35]

    Su L B, Zhou P, Xu J 2009 Opt. Express 17 13554

  • [1]

    Yamada M, Ono H, Ohishi Y 1998 Electron. Lett 34 1490

    [2]

    Fujimoto Y, Nakatsuka M 2001 Jpn. J. Appl. Phys 40 L279

    [3]

    Peng M Y, Qiu J R, Cheng D P 2004 Opt. Lett. 29 1998

    [4]

    Peng M Y, Qiu J R, Cheng D P 2005 Opt. Lett 30 2433

    [5]

    Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1628

    [6]

    Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1635

    [7]

    Dvoyrin V V, Mashinsky V M Bulatov L I 2006 Opt. Lett. 31 2966

    [8]

    Arai Y, Suzuki T, Ohishi Y 2007 Appl. Phys. Lett. 90 261110

    [9]

    Sun H T, Miwa Y, Shimaoka F 2009 Opt. Lett. 34 1219

    [10]

    Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett 33 1488

    [11]

    Ren J, Wu B, Jiang X 2007 Appl. Phys. B 88 363

    [12]

    Ren J, Qiu J R, Cheng D P 2008 J. Alloys and Compounds 463 L5

    [13]

    Zhou S F, Dong H F, Zeng H P 2007 Appl. Phys. Lett. 91 061919

    [14]

    S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407

    [15]

    Peng M Y, Zhao Q Z, Qiu J R 2009 J. Am. Ceram. Soc. 92 542

    [16]

    Zhou S F, Jiang N, Zhu B 2009 Advanced Functional Materials 19 2081

    [17]

    Xia H P, Wang X J 2006 Appl. Phys. Lett. 89 051917

    [18]

    Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122

    [19]

    Xia H P, Wang X J 2006 Optics Communications 268 75

    [20]

    Wang X J, Xia H P 2006 Acta Phys. Sin. 55 5263 (in Chinese) [王雪俊, 夏海平 2006 物理学报 55 5263

    [21]

    Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504

    [22]

    Xu J, Zhao H Y, Su L B 2010 Opt. Express 18 3385

    [23]

    Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325

    [24]

    Ruan J, Su L B, Qiu J R 2009 Opt. Express 17 5136

    [25]

    Dvoyrin V V, Mashinsky V M, Dianov A A 2005 31st European Conference on Optics Communication Glasgow, Scotland 4 949

    [26]

    Yang Z W, Liu Z L, Song Z G 2011 Materials Research Innovations 15 264

    [27]

    Zhou D C, Liu Z L. Song Z G 2012 Acta Phys. Sin. 61 127802 (in Chinese) [周大成, 刘志亮, 宋志国 2012 物理学报 61 127802]

    [28]

    Zhang N, Qiu J R, Dong G P 2012 Journal of Materials Chemistry 22 3153

    [29]

    Alexey N R, Zukhra T F, Alexander A V 2012 Opt. Expres 20 7212

    [30]

    Alexey N R, Zukhra T F, Denis M Z 2011 Optical Materials 33 631

    [31]

    Guo X, Li H J, Su LB 2012 Optical Materials 34 675

    [32]

    Yu P S, Su LB, Zhao H Y 2011 Optical Materials 33 831

    [33]

    Baia L, Stefan Rn, Kiefer W 2002 Journal of Non-Crystalline Solids 303 379

    [34]

    Liu J F, Su LB Xu J 2012 Acta Phys. Sin. 61 127806 (in Chinese) [刘军芳, 苏良碧, 徐军 2012 物理学报 61 127806]

    [35]

    Su L B, Zhou P, Xu J 2009 Opt. Express 17 13554

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Publishing process
  • Received Date:  19 June 2012
  • Accepted Date:  13 September 2012
  • Published Online:  05 February 2013

Preparation and near-infrared luminescence properties of Bi2O3-B2O3-BaO glasses

  • 1. College of Materials Science and Engineering, Tongji University, Shanghai 200092, China;
  • 2. Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, Shanghai 200092, China;
  • 3. Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China
Fund Project:  Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 61008045) and the Fundamental Research Funds for the Central Universities, China.

Abstract: xBi2O3-50B2O3-(50-x)BaO glasses are prepared by melting method. Their infrared luminescence spectra, fluorescence decay curves and Raman scattering spectra are measured. No obvious near-infrared (NIR) luminescence is observed in 50Bi2O3-50B2O3 glass under 808 nm laser diode (LD) pumping. Adding BaO, broadband NIR luminescences are observed in 40Bi2O3-50B2O3-10BaO glass, 45Bi2O3-50B2O3-5BaO glass and 49Bi2O3-50B2O3-1BaO glass. With the increase of BaO concentration, no obvious NIR luminescences are observed in 30Bi2O3-50B2O3-20BaO glass, 20Bi2O3-50B2O3-30BaO glass and 10Bi2O3-50B2O3-40BaO glass. The NIR emissions with several emission peaks appear in 0.5Bi2O3-50B2O3-50BaO glass and 1Bi2O3-50B2O3-50BaO glass. The mechanism for the emission is investigated preliminarily.

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