MnPS<sub>3</sub>可饱和吸收体被动锁模掺铒光纤激光器双波长激光

俞强; 郭琨; 陈捷; 王涛; 汪进; 史鑫尧; 吴坚; 张凯; 周朴

doi:10.7498/aps.69.20200342

摘要

过渡金属硫代亚磷酸盐MnPS₃是三元含磷二维材料, 具有新颖的光电特性. 采用化学气相传输方法生长MnPS₃单晶, 结合机械剥离方法制备可饱和吸收体光纤调制器件. 以MnPS₃可饱和吸收体构建掺铒光纤环形激光器, 实现脉冲间隔为196.1 ns, 脉冲宽度为3.8 ns, 最高输出功率为27.2 mW, 1565.19 nm和1565.63 nm双波长锁模脉冲激光输出, 实现280 h以上高稳定自启动双波长锁模输出.

关键词:

MnPS₃ /
可饱和吸收 /
锁模

Abstract

As a member of the metal phosphorus trichalcogenide family, MPS₃ is widely used in nonlinear optics and devices, which can be regarded as a significant benefit for the excellent photonic and optoelectronic properties. In this work, the MnPS₃ nanosheet is prepared by the chemical vapor transport method and the MnPS₃ saturable absorber is demonstrated by modifying mechanical exfoliation. To the best of our knowledge, the dual-wavelength self-starting mode-locking erbium-doped fiber laser with MnPS₃ saturable absorber is demonstrated for the first time. The dual wavelength mode-locked laser with a pulse repetition rate of 5.102 MHz at 1565.19 nm and 1565.63 nm is proposed. Its maximum output power at the dual-wavelength is 27.2 MW. The mode-locked laser can self-start and stably run for more than 280 h.

Keywords:

作者及机构信息

1.
中国科学院苏州纳米技术与纳米仿生研究所, 国际实验室, 苏州　215123

2.
国防科技大学前沿交叉学科学院, 长沙　410073

通信作者: 吴坚, wujian15@nudt.edu.cn ; 张凯, kzhang2015@sinano.ac.cn ;

基金项目: 国家自然科学基金(批准号: 61922082, 61875223, 61801472)和湖南省自然科学基金(批准号: 2018JJ3610)资助的课题

Authors and contacts

1.
i-lab, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China

2.
College of Advanced Interdisciplinary Studies, National University of Defense Technology, Changsha 410073, China

Corresponding author: Wu Jian, wujian15@nudt.edu.cn ; Zhang Kai, kzhang2015@sinano.ac.cn ;

Funds: Project supported by the the National Natural Science Foundation of China (Grant Nos. 61922082, 61875223, 61801472) and the Natural Science Foundation of Hunan Province, China (Grant No. 2018JJ3610)

文章全文

参考文献

[1]	Penilla E H, Devia Cruz L F, Wieg A T, Martinez Torres P, Cuando Espitia N, Sellappan P, Kodera Y, Aguilar G, Garay J E 2019 Science 365 803 Google Scholar
[2]	Fermann M E, Hartl I 2013 Nat. Photonics 7 868 Google Scholar
[3]	王聪, 刘杰, 张晗 2019 物理学报 68 188101 Google Scholar Wang C, Liu J, Zhang H 2019 Acta Phys. Sin. 68 188101 Google Scholar
[4]	Zhang H, Tang D, Knize R J, Zhao L, Bao Q, Loh K P 2010 Appl. Phys. Lett. 96 111112 Google Scholar
[5]	Sun Z, Hasan T, Torrisi F, Popa D, Privitera G, Wang F, Bonaccorso F, Basko D M, Ferrari A C 2010 ACS nano 4 803 Google Scholar
[6]	Tan C, Cao X, Wu X J, He Q, Yang J, Zhang X, Chen J, Zhao W, Han S, Nam G H, Sindoro M, Zhang H 2017 Chem. Rev. 117 6225 Google Scholar
[7]	Wu H S, Song J, Wu J, Xu J, Xiao H, Leng J, Zhou P 2018 IEEE J. Sel. Top. Quant. 24 0901206 Google Scholar
[8]	Hong S, Ledee F, Park J, Song S, Lee H, Lee Y S, Kim B, Yeom D I, Deleporte E, Oh K 2018 Laser Photonics Rev. 12 1800118 Google Scholar
[9]	黄诗盛, 王勇刚, 李会权, 林荣勇, 闫培光 2014 物理学报 63 084202 Google Scholar Huang S S, Wang Y G, Li H Q, Lin R Y, Yan P G 2014 Acta Phys. Sin. 63 084202 Google Scholar
[10]	Liu X, Li X, Tang Y, Zhang S 2020 Opt. Lett. 45 161 Google Scholar
[11]	Ahmad H, Salim M A M, Thambiratnam K, Norizan S F, Harun S W 2016 Laser Phys. Lett. 13 095103 Google Scholar
[12]	Hisyam M B, Rusdi M F M, Latiff A A, Harun S W 2017 Ieee J. Sel. Top. Quant. 23 39 Google Scholar
[13]	Wang T, Jin X, Yang J, Wu J, Yu Q, Pan Z, Shi X, Xu Y, Wu H, Wang J, He T, Zhang K, Zhou P 2019 ACS Appl. Mater. Inter. 11 36854 Google Scholar
[14]	Wang T, Shi X, Wang J, Xu Y, Chen J, Dong Z, Jiang M, Ma P, Su R, Ma Y, Wu J, Zhang K, Zhou P 2019 Sci. China Inf. Sci. 62 220406 Google Scholar
[15]	Liu J, Li X B, Wang D, Lau W M, Peng P, Liu L M 2014 J. Chem. Phys. 140 054707 Google Scholar
[16]	Liu J, Zhao F, Wang H, Zhang W, Hu X, Li X, Wang Y 2019 Opt. Mater. 89 100 Google Scholar
[17]	史鑫尧 2019 硕士学位论文 (合肥: 中国科学技术大学) Shi X Y 2019 M. S. Thesis (Hefei: University of Science and Technology of China) (in Chinese)
[18]	Hou X, Zhang X, Ma Q, Tang X, Hao Q, Cheng Y, Qiu T 2020 Adv. Funct. Mater. 30 1910171 Google Scholar
[19]	Gusmão R, Sofer Z, Pumera M 2019 Adv. Funct. Mater. 29 1805975 Google Scholar
[20]	Yin Q, Wang J, Shi X Y, Wang T, Yang J, Zhao X X, Shen Z J, Wu J, Zhang K, Zhou P, Jiang Z F 2019 Chin. Phys. B 28 084208 Google Scholar
[21]	Liu J, Li X, Xu Y, Ge Y, Wang Y, Zhang F, Wang Y, Fang Y, Yang F, Wang C, Song Y, Xu S, Fan D, Zhang H 2019 Nanoscale 11 14383 Google Scholar
[22]	Du K Z, Wang X Z, Liu Y, Hu P, Utama M I B, Gan C K, Xiong Q, Kloc C 2016 ACS Nano 10 1738 Google Scholar
[23]	Cheng Z, Shifa T A, Wang F, Gao Y, He P, Zhang K, Jiang C, Liu Q, He J 2018 Adv. Mater. 30 1707433 Google Scholar
[24]	Lee J U, Lee S, Ryoo J H, Kang S, Kim T Y, Kim P, Park C H, Park J G, Cheong H 2016 Nano Lett. 16 7433 Google Scholar
[25]	Kumar R, Jenjeti R N, Austeria M P, Sampath S 2019 J. Mater. Chem. C 7 324 Google Scholar
[26]	Kargar F, Coleman E A, Ghosh S, Lee J, Gomez M J, Liu Y, Magana A S, Barani Z, Mohammadzadeh A, Debnath B, Wilson R B, Lake R K, Balandin A A 2020 ACS Nano 14 2424 Google Scholar
[27]	Kinyanjui M K, Koester J, Boucher F, Wildes A, Kaiser U 2018 Phys. Rev. B 98 035417 Google Scholar
[28]	邱小浪, 王爽爽, 张晓健, 朱仁江, 张鹏, 郭于鹤洋, 宋晏蓉 2019 物理学报 68 114204 Google Scholar Qiu X L, Wang S S, Zhang X J, Zhu R J, Zhang P, Guo Y H Y, Song Y R 2019 Acta Phys. Sin. 68 114204 Google Scholar
[29]	Shi X, Wang T, Wang J, Xu Y, Yang Z, Yu Q, Wu J, Zhang K, Zhou P 2019 Opt. Mater. Express 9 2348 Google Scholar
[30]	Yang J, Hu J, Luo H, Li J, Liu J, Li X, Liu Y 2020 Photon. Res. 8 70 Google Scholar
[31]	Wu X, Zhou Z W, Yin J D, Zhang M, Zhou L L, Na Q X, Wang J T, Yu Y, Yang J B, Chi R H, Yan P G 2020 Nanotechnology 31 245204 Google Scholar
[32]	Guo C, Wei J, Yan P, Luo R, Ruan S, Wang J, Guo B, Hua P, Lue Q 2020 Appl. Phys. Express 13 012013 Google Scholar
[33]	Wang Y M, Zhang J F, Li C H, Ma X L, Ji J T, Jin F, Lei H C, Liu K, Zhang W L, Zhang Q M 2019 Chin. Phys. B 28 056301 Google Scholar

施引文献

图 1 MnPS₃晶体生长及表征　(a)化学气相传输法制备MnPS₃晶体的工艺流程示意图; (b) MnPS₃单晶的照片; (c) MnPS₃单晶的拉曼光谱

Fig. 1. Characteristics of MnPS₃ crystals: (a) Chemical vapor transport method; (b) picture of MnPS₃; (c) Raman spectrum for MnPS₃

下载: 全尺寸图片幻灯片

图 2 MnPS₃-SA的SEM表征　(a)随机选取的样品SEM图像和元素分析表; (b)−(d) Mn, P和S的EDX元素面扫描

Fig. 2. SEM characteristics of MnPS₃ -SA: (a) SEM image of a randomly selected MnPS₃ flake, and elemental analysis of this sample; (b)−(d) EDX element mappings for Mn, P, and S.

下载: 全尺寸图片幻灯片

图 3 MnPS₃纳米片的TEM表征　(a) MnPS₃纳米片形貌; (b) MnPS₃纳米片的HRTEM像; (c) SAED图

Fig. 3. TEM characterization of MnPS₃ nanosheets: (a) TEM image of a MnPS₃ nanosheet on a copper grid; (b) the HRTEM image of the MnPS₃ nanosheet; (c) the corresponding SAED showing its single crystal nature.

下载: 全尺寸图片幻灯片

图 4 MnPS₃-SA掺铒光纤激光器的实验装置

Fig. 4. Experimental setup of the erbium-doped fiber laser.

下载: 全尺寸图片幻灯片

图 5 基于MnPS₃-SA的脉冲光纤激光器的性能　(a)输出功率与抽运功率的关系; (b)输出光谱; (c)脉冲序列; (d)脉冲脉宽; (e) 0−10 MHz射频信号; (f)射频基频信号

Fig. 5. Performances of the pulse fiber laser based on MnPS₃-SA: (a) The output power versus the pump power; (b) output optical spectrum; (c) the pulse trace; (d) the duration of single pulse; (e) the radio frequency spectrum from 0−10 MHz; (f) the radio frequency spectrum with ～64 dB (inset).

下载: 全尺寸图片幻灯片

图 6 基于MnPS₃-SA的脉冲光纤激光器在70, 120, 170, 220和270 mW抽运功率下的(a)光谱、(b)波长和(c)频率特性

Fig. 6. Performances of the pulse fiber laser based on MnPS₃-SA with the pump power at 70, 120, 170, 220, and 270 mW pump power: (a) Spectrum; (b) wavelength; (c) frequency.

下载: 全尺寸图片幻灯片

图 7 基于MnPS₃-SA的脉冲激光长时间工作稳定性　(a)第1, 7, 8, 11, 12 天的输出光谱; (b)中心波长; (c)输出功率

Fig. 7. Output spectrum of the EDFL based on MnPS₃-SA: (a) Output spectrum recorded on 1^st, 7^th, 8^th, 11^th, 12^th day; (b) wavelength peak position; (c) output power.

下载: 全尺寸图片幻灯片

[1]	Penilla E H, Devia Cruz L F, Wieg A T, Martinez Torres P, Cuando Espitia N, Sellappan P, Kodera Y, Aguilar G, Garay J E 2019 Science 365 803 Google Scholar
[2]	Fermann M E, Hartl I 2013 Nat. Photonics 7 868 Google Scholar
[3]	王聪, 刘杰, 张晗 2019 物理学报 68 188101 Google Scholar Wang C, Liu J, Zhang H 2019 Acta Phys. Sin. 68 188101 Google Scholar
[4]	Zhang H, Tang D, Knize R J, Zhao L, Bao Q, Loh K P 2010 Appl. Phys. Lett. 96 111112 Google Scholar
[5]	Sun Z, Hasan T, Torrisi F, Popa D, Privitera G, Wang F, Bonaccorso F, Basko D M, Ferrari A C 2010 ACS nano 4 803 Google Scholar
[6]	Tan C, Cao X, Wu X J, He Q, Yang J, Zhang X, Chen J, Zhao W, Han S, Nam G H, Sindoro M, Zhang H 2017 Chem. Rev. 117 6225 Google Scholar
[7]	Wu H S, Song J, Wu J, Xu J, Xiao H, Leng J, Zhou P 2018 IEEE J. Sel. Top. Quant. 24 0901206 Google Scholar
[8]	Hong S, Ledee F, Park J, Song S, Lee H, Lee Y S, Kim B, Yeom D I, Deleporte E, Oh K 2018 Laser Photonics Rev. 12 1800118 Google Scholar
[9]	黄诗盛, 王勇刚, 李会权, 林荣勇, 闫培光 2014 物理学报 63 084202 Google Scholar Huang S S, Wang Y G, Li H Q, Lin R Y, Yan P G 2014 Acta Phys. Sin. 63 084202 Google Scholar
[10]	Liu X, Li X, Tang Y, Zhang S 2020 Opt. Lett. 45 161 Google Scholar
[11]	Ahmad H, Salim M A M, Thambiratnam K, Norizan S F, Harun S W 2016 Laser Phys. Lett. 13 095103 Google Scholar
[12]	Hisyam M B, Rusdi M F M, Latiff A A, Harun S W 2017 Ieee J. Sel. Top. Quant. 23 39 Google Scholar
[13]	Wang T, Jin X, Yang J, Wu J, Yu Q, Pan Z, Shi X, Xu Y, Wu H, Wang J, He T, Zhang K, Zhou P 2019 ACS Appl. Mater. Inter. 11 36854 Google Scholar
[14]	Wang T, Shi X, Wang J, Xu Y, Chen J, Dong Z, Jiang M, Ma P, Su R, Ma Y, Wu J, Zhang K, Zhou P 2019 Sci. China Inf. Sci. 62 220406 Google Scholar
[15]	Liu J, Li X B, Wang D, Lau W M, Peng P, Liu L M 2014 J. Chem. Phys. 140 054707 Google Scholar
[16]	Liu J, Zhao F, Wang H, Zhang W, Hu X, Li X, Wang Y 2019 Opt. Mater. 89 100 Google Scholar
[17]	史鑫尧 2019 硕士学位论文 (合肥: 中国科学技术大学) Shi X Y 2019 M. S. Thesis (Hefei: University of Science and Technology of China) (in Chinese)
[18]	Hou X, Zhang X, Ma Q, Tang X, Hao Q, Cheng Y, Qiu T 2020 Adv. Funct. Mater. 30 1910171 Google Scholar
[19]	Gusmão R, Sofer Z, Pumera M 2019 Adv. Funct. Mater. 29 1805975 Google Scholar
[20]	Yin Q, Wang J, Shi X Y, Wang T, Yang J, Zhao X X, Shen Z J, Wu J, Zhang K, Zhou P, Jiang Z F 2019 Chin. Phys. B 28 084208 Google Scholar
[21]	Liu J, Li X, Xu Y, Ge Y, Wang Y, Zhang F, Wang Y, Fang Y, Yang F, Wang C, Song Y, Xu S, Fan D, Zhang H 2019 Nanoscale 11 14383 Google Scholar
[22]	Du K Z, Wang X Z, Liu Y, Hu P, Utama M I B, Gan C K, Xiong Q, Kloc C 2016 ACS Nano 10 1738 Google Scholar
[23]	Cheng Z, Shifa T A, Wang F, Gao Y, He P, Zhang K, Jiang C, Liu Q, He J 2018 Adv. Mater. 30 1707433 Google Scholar
[24]	Lee J U, Lee S, Ryoo J H, Kang S, Kim T Y, Kim P, Park C H, Park J G, Cheong H 2016 Nano Lett. 16 7433 Google Scholar
[25]	Kumar R, Jenjeti R N, Austeria M P, Sampath S 2019 J. Mater. Chem. C 7 324 Google Scholar
[26]	Kargar F, Coleman E A, Ghosh S, Lee J, Gomez M J, Liu Y, Magana A S, Barani Z, Mohammadzadeh A, Debnath B, Wilson R B, Lake R K, Balandin A A 2020 ACS Nano 14 2424 Google Scholar
[27]	Kinyanjui M K, Koester J, Boucher F, Wildes A, Kaiser U 2018 Phys. Rev. B 98 035417 Google Scholar
[28]	邱小浪, 王爽爽, 张晓健, 朱仁江, 张鹏, 郭于鹤洋, 宋晏蓉 2019 物理学报 68 114204 Google Scholar Qiu X L, Wang S S, Zhang X J, Zhu R J, Zhang P, Guo Y H Y, Song Y R 2019 Acta Phys. Sin. 68 114204 Google Scholar
[29]	Shi X, Wang T, Wang J, Xu Y, Yang Z, Yu Q, Wu J, Zhang K, Zhou P 2019 Opt. Mater. Express 9 2348 Google Scholar
[30]	Yang J, Hu J, Luo H, Li J, Liu J, Li X, Liu Y 2020 Photon. Res. 8 70 Google Scholar
[31]	Wu X, Zhou Z W, Yin J D, Zhang M, Zhou L L, Na Q X, Wang J T, Yu Y, Yang J B, Chi R H, Yan P G 2020 Nanotechnology 31 245204 Google Scholar
[32]	Guo C, Wei J, Yan P, Luo R, Ruan S, Wang J, Guo B, Hua P, Lue Q 2020 Appl. Phys. Express 13 012013 Google Scholar
[33]	Wang Y M, Zhang J F, Li C H, Ma X L, Ji J T, Jin F, Lei H C, Liu K, Zhang W L, Zhang Q M 2019 Chin. Phys. B 28 056301 Google Scholar

[1]	侯刘敏, 侯云龙, 刘圆凯, 李渊华, 林佳, 陈险峰. 基于可饱和吸收体锁模激光器中的呼吸子. 物理学报, 2025, 74(4): 044206. doi: 10.7498/aps.74.20241505
[2]	贺亮, 彭雪芳, 沈小雨, 朱仁江, 王涛, 蒋丽丹, 佟存柱, 宋晏蓉, 张鹏. 低重复频率被动锁模半导体碟片激光器. 物理学报, 2024, 73(12): 124205. doi: 10.7498/aps.73.20240441
[3]	崔文文, 邢笑伟, 肖悦嘉, 刘文军. 高损伤阈值可饱和吸收体锁模脉冲光纤激光器的研究进展. 物理学报, 2022, 71(2): 024206. doi: 10.7498/aps.71.20212442
[4]	戴川生, 董志鹏, 林加强, 姚培军, 许立新, 顾春. 基于纯水可饱和吸收体的1.9 μm波段被动调Q和锁模掺铥光纤激光器. 物理学报, 2022, 71(17): 174202. doi: 10.7498/aps.71.20212125
[5]	窦志远, 张斌, 刘帅林, 侯静. 高功率全光纤1.6微米类噪声方形脉冲激光器. 物理学报, 2020, 69(16): 164202. doi: 10.7498/aps.69.20200245
[6]	周峰, 蔡宇, 邹德峰, 胡丁桐, 张亚静, 宋有建, 胡明列. 钛宝石飞秒激光器中孤子分子的内部动态探测. 物理学报, 2020, 69(8): 084202. doi: 10.7498/aps.69.20191989
[7]	令维军, 夏涛, 董忠, 刘勍, 路飞平, 王勇刚. 基于WS2可饱和吸收体的调Q锁模Tm，Ho：LLF激光器. 物理学报, 2017, 66(11): 114207. doi: 10.7498/aps.66.114207
[8]	王小发, 张俊红, 高子叶, 夏光琼, 吴正茂. 基于石墨烯可饱和吸收体的纳秒锁模掺铥光纤激光器. 物理学报, 2017, 66(11): 114209. doi: 10.7498/aps.66.114209
[9]	连富强, 樊仲维, 白振岙, 刘一州, 林蔚然, 张晓雷, 赵天卓. 高稳定性、高质量脉冲压缩飞秒光纤激光系统研究. 物理学报, 2015, 64(16): 164207. doi: 10.7498/aps.64.164207
[10]	窦志远, 田金荣, 李克轩, 于振华, 胡梦婷, 霍明超, 宋晏蓉. 高重复频率全光纤被动锁模掺铒光纤激光器. 物理学报, 2015, 64(6): 064206. doi: 10.7498/aps.64.064206
[11]	连富强, 樊仲维, 白振岙, 余锦, 林蔚然, 张晓雷, 刘迪, 赵天卓. 基于1064 nm光纤皮秒种子源的Nd：YAG再生放大器. 物理学报, 2014, 63(13): 134207. doi: 10.7498/aps.63.134207
[12]	冯德军, 黄文育, 姜守振, 季伟, 贾东方. 基于少数层石墨烯可饱和吸收的锁模光纤激光器. 物理学报, 2013, 62(5): 054202. doi: 10.7498/aps.62.054202
[13]	曹士英, 朱月, 柴路, 王清月, 张志刚. 半导体可饱和吸收镜锁模的钒酸盐混晶Nd:Gd0.1Y0.9VO4激光器. 物理学报, 2009, 58(9): 6269-6272. doi: 10.7498/aps.58.6269
[14]	柴路, 颜石, 薛迎红, 刘庆文, 葛文琦, 王清月, 苏良碧, 徐晓东, 赵广军, 徐军. 镱、钠共掺的氟化钙晶体在1050nm的可饱和吸收作用. 物理学报, 2008, 57(5): 2966-2970. doi: 10.7498/aps.57.2966
[15]	林宏奂, 卢振华, 王建军, 张颖, 王凤蕊, 许党朋, 张锐, 李明中, 邓青华, 罗亦鸣, 唐军, 丁磊. 正色散激光器中的增益导引孤子. 物理学报, 2008, 57(9): 5646-5650. doi: 10.7498/aps.57.5646
[16]	宋有建, 胡明列, 刘庆文, 李进延, 陈伟, 柴路, 王清月. 掺Yb3+双包层大模场面积光纤锁模激光器. 物理学报, 2008, 57(8): 5045-5048. doi: 10.7498/aps.57.5045
[17]	柴路, 王清月, 张志刚, 赵江山, 王勇, 张伟力, 邢歧荣. 用腔内半导体可饱和吸收镜钛宝石激光器中自锁模状态的实验研究. 物理学报, 2001, 50(1): 68-72. doi: 10.7498/aps.50.68
[18]	柴路, 王清月, 赵江山, 邢歧荣, 张志刚. 半导体可饱和吸收镜启动克尔透镜锁模机理的实验研究. 物理学报, 2001, 50(7): 1298-1301. doi: 10.7498/aps.50.1298
[19]	黄志坚, 孙军强, 黄德修. 快速与慢速饱和吸收体被动锁模掺铒光纤激光器的理论分析. 物理学报, 1998, 47(1): 9-18. doi: 10.7498/aps.47.9
[20]	李世忱. LiNbO3晶体压电应变光束调制器及激光锁模器解析. 物理学报, 1993, 42(6): 1020-1026. doi: 10.7498/aps.42.1020

计量

文章访问数: 12725
PDF下载量: 338
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板

MnPS₃可饱和吸收体被动锁模掺铒光纤激光器双波长激光