单壁碳纳米管膜及其三聚氰胺甲醛树脂复合材料的光电特性

李振武

doi:10.7498/aps.63.106101

摘要

单壁碳纳米管能够强烈吸收光线，尤其是在近红外区域，并能将光能转换成热能. 同时，单壁碳纳米管还具有相当大的将热能转换成电能的能力. 通过真空过滤方法，将由化学气相沉积生成的单壁碳纳米管阵列制备成单壁碳纳米管膜. 根据研究的需要设计了一个简单的单壁碳纳米管膜光伏性质测试实验装置，并在其两端成功地实现了由红外光转换为电压输出. 通过功能化步骤，制备了单壁碳纳米管/三聚氰胺甲醛树脂复合材料膜，实验结果表明该复合材料能产生符号相反的输出电压. 这预示着单壁碳纳米管及其三聚氰胺甲醛树脂复合材料在光电领域具有良好的应用前景.

关键词:

Abstract

The single-walled carbon nanotube (SWCNT) can strongly absorb light, particularly in the near infrared region, and can convert it into thermal energy, while the SWCNT also has a great capacity of converting thermal energy into electrical energy. In this paper, by means of vacuum filtering, SWCNT film is prepared by SWCNT arrays generated by the chemical vapor deposition. A simple experimental device of SWCNT is designed and the conversion from the infrared light to voltage output is successfully achieved. The SWCNT/melamine formaldehyde resin composite film is prepared by the functional steps. The experimental results show that the composite material can produce an output voltage of opposite sign, which indicates that the SWCNT and melamine formaldehyde resin composite material have good application prospect in the field of photo-electrical applications.

Keywords:

作者及机构信息

李振武

1.
菏泽学院蒋震机电工程学院, 菏泽 274015

基金项目: 山东省自然科学基金（批准号：Y2008A16）资助的课题.

Authors and contacts

Li Zhen-Wu

1.
School of Jiang Zhen Mechanical and Electrical Engineering, Heze University, Heze 274015, China

Funds: Project supported by the Natural Science Foundation of Shandong Province, China (Grant No. Y2008A16).

参考文献

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[15]	Zhang S L, Xia M G, Zhao S M, Xu T , Zhang E H 2003 Phys. Rev. B 68 075415
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施引文献

[1]	Iijima S 1991 Nature 354 56
[2]	Li Z W 2012 Acta Phys. Sin. 61 016103 (in Chinese) [李振武 2012 物理学报 61 016103]
[3]	Li Z W 2013 Acta Phys. Sin. 62 096101 (in Chinese) [李振武 2013 物理学报 62 096101]
[4]	Feng D L, Feng Y H, Chen Y, Li W, Zhang X X 2013 Chin. Phys. B 22 016501
[5]	Karimov K S, Chani M T S, Khalid F A, Khan A, Khan R 2012 Chin. Phys. B 21 016102
[6]	Wu M H, Li X, Pan D, Liu L, Yang X X, Xu Z, Wang W L, Sui Y, Bai X D 2013 Chin. Phys. B 22 086101
[7]	Feng W, Yi W H, Xu Y L, Lian Y Q, Wang X G, Yoshino K 2003 Acta Phys. Sin. 52 1272 (in Chinese) [封伟, 易文辉, 徐友龙, 连彦青, 王晓工, 吉野勝美 2003 物理学报 52 1272]
[8]	Qu J R, Zheng J B, Wang C F, Wu G R, Wang X Y 2013 Acta Phys. Sin. 62 128801 (in Chinese) [屈俊荣, 郑建邦, 王春锋, 吴广荣, 王雪艳 2013 物理学报 62 128801]
[9]	Lai Y H, Lin C Y, Chen H W, Chen J G, Kung C W, Vittal R, Ho K C 2010 J. Mater. Chem. 20 9379
[10]	Zhang X R, Lin Y H, Zhang J F, He D Q, Wang D J 2010 Acta Phys. Chim. Sin. 26 2733 (in Chinese) [张晓茹, 林艳红, 张健夫, 何冬青, 王德军 2010 物理化学学报 26 2733]
[11]	Dai S Y, Kong F T, Hu L H, Shi C W, Fang X Q, Pan X, Wang K J 2005 Acta Phys. Sin. 54 1919 (in Chinese) [戴松元, 孔凡太, 胡林华, 史成武, 方霞琴, 潘旭, 王孔嘉 2005 物理学报 54 1919]
[12]	Itkis M E, Borondics F, Yu A , Haddon R C 2006 Science 312 413
[13]	Chakravarty P, Marches R, Zimmerman N S, Swafford A D E, Bajaj P, Musselman I H, Pantano P, Draper R K, Vitetta E S 2008 Proc. Natl. Acad. Sci. USA 105 8697
[14]	Mizuno K, Ishii J, Kishida H, Hayamizu Y, Yasuda S, Futaba D N, Yumura M, Hata K 2009 Proc. Natl. Acad. Sci. USA 106 6044
[15]	Zhang S L, Xia M G, Zhao S M, Xu T , Zhang E H 2003 Phys. Rev. B 68 075415
[16]	Yu C, Shi L, Yao Z, Li D Y, Majumdar A 2005 Nano Lett. 5 1842
[17]	Barisic N, Gaal R, Kezsmarki I, Mihaly G, Forro L 2002 Phys. Rev. B 65 241403
[18]	Baxendale M, Lim K G, Amaratunga G A J 2000 Phys. Rev. B 61 12705
[19]	Shim M, Javey A, Kam N W S, Dai H J 2001 J. Am. Chem. Soc. 123 11512
[20]	Stokes P, Liu L W, Zou J H, Zhai L, Huo Q, Khondaker S I 2009 Appl. Phys. Lett. 94 042110
[21]	Sarker B K, Arif M, Khondaker S I 2010 Carbon 48 1539
[22]	Pradhan B, Kohlmeyer R R, Setyowati K, Owen H A, Chen J 2009 Carbon 47 1686
[23]	St-Antoine B C, Menard D, Martel R 2009 Nano Lett. 9 3503
[24]	Lien D H, Hsu W K, Zan H W, Tai N H, Tsai C H 2006 Adv. Mater. 18 98
[25]	Zhan G D, Kuntz J D, Mukherjee A K, Zhu P, Koumoto K 2006 Scripta Mater. 54 77
[26]	Levesque I, Gao X, Klug D D, Tse J S, Ratcliffe C I, Leclerc M 2005 React. Funct. Polym. 65 23
[27]	Moniruzzaman M, Winey K I 2006 Macromolecules 39 5194
[28]	Ajayan P M, Terrones M, de la Guardia A, Huc V, Grobert N, Wei B Q, Lezec H, Ramanath G, Ebbesen T W 2002 Science 296 705

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