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本文利用脉冲紫外激光(UV)选择激发氨分子到?1A″2电子激发态的两个最低振动能级ν′2=0和ν′2=1(ν2振动),然后检测新生态H原子的飞行谱(TOF),研究了氨分子的光碎片动力学。光谱证实了最近所测的离解能D00(H-NH2)=4.645eV;绝大多数生成的NH2(X2B1)基处于非振动激发,但是具有围绕a惯性轴的高度转动激发。通过NH3(?)的ν′2=1光离解产生的NH2(X)基具有较高的内部激发,并且显示了在N=Ka转动能级上的反转布居。The photofragnentation dynamics of ammonia molecules following pulsed UV laser excitation of ground state to the two lowest levels ν′2 = 0 and 1 (ν2 vibrational mode) of their ?1(A"2) electronic excited state has been investigated by monitoring thetime-of-flight spectra of the nascent H-atom products. The spectra confirm recent revised estimates of the quantity D00(H-NH2) = 4.645 eV and reveals that the majority of the accompanying NH2 (X2B1) fragments are formed vibrationally unexcited, but with high levels of rotational excitation specifically concentrated about the a-inertial axis. The NH2(X) fragments resulting from photodissociation via the ν′2 = 1 level of NH3(?) carry a higher level of internal excitation and show an inverted population distribution over the N = Ka rotational levels.
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