搜索

文章查询

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

钙钛矿太阳能电池近期进展

柴磊 钟敏

钙钛矿太阳能电池近期进展

柴磊, 钟敏
PDF
导出引用
导出核心图
  • 近几年来,基于有机无机金属卤化物钙钛矿(ABX3)的太阳能电池由于其独特的物理化学性质受到了广泛的关注.这种钙钛矿材料具有很高的消光系数、较强的电荷传递能力、长的载流子寿命、长的载流子扩散距离以及特殊的双极性,同时低成本易制作.自2009年至今,钙钛矿太阳能电池的光电转换效率从最初的3.8%增长到了20.8%,使之成为最有可能在未来代替传统单晶硅太阳能电池的新型太阳能电池.同时,由于钙钛矿具有双极性,故钙钛矿太阳能电池的结构也有多种,最常见的结构有介孔结构、平面结构、介观超结构、无空穴传输层结构等.本文主要介绍钙钛矿太阳能电池的发展、电池结构及其对光电池性能的影响、钙钛矿薄膜的制备方法,同时探讨了钙钛矿在电子传输层上的吸附模型和电荷在电池界面中的传输机理以及界面工程,并介绍该类型电池在近期所获得的突破及未来可能的发展方向,以便对钙钛矿太阳能电池有进一步的了解.
      通信作者: 钟敏, zhongmin@cjlu.edu.cn
    • 基金项目: 国家自然科学基金(批准号:21471140,21101143)资助的课题.
    [1]

    Cui J, Yuan H L, Li J P, Xu X B, Shen Y, Lin H, Wang M K 2015 Sci. Technol. Adv. Mater. 16 036004

    [2]

    Green M A, Emery K, Hishikawa Y, Warta W, Dunlop E D 2012 Prog. Photovoltaics 20 12

    [3]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [4]

    Bi D Q, Tress W G, Dar M I, Gao P, Luo J S, Renevier C, Schenk K, Abate A, Giordano F, Baena J P, Decoppe J, Zakeeruddin S M, Nazeeruddin M K, Grötzel M, Hagfeldt A 2016 Sci. Adv. Mater. 2 e1501170

    [5]

    Li Y W, Meng L, Yang Y, Xu G Y, Hong Z, Chen Q, You J B, Li G, Yang Y, Li Y F 2015 Nat. Commun. 7 10214

    [6]

    Gao P, Gratze M, Nazeeruddin M K 2014 Energy Environ. Sci. 7 2448

    [7]

    Burschka J, Pellet N, Moon S J, Baker R H, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316

    [8]

    Zhao Y X, Zhu K 2015 J. Mater. Chem. A 3 9086

    [9]

    Liu M Z, Johnston M B, Snaith H J 2013 Nature 501 395

    [10]

    Chen Q, Zhou H P, Hong Z, Luo S, Duan H S, Wang H H, Liu Y S, Li G, Yang Y 2014 J. Am. Chem. Soc. 136 622

    [11]

    Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088

    [12]

    Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J 2012 Science 338 643

    [13]

    Zhang W, Eperson G E, Snaith H J 2016 Nature Energy 160 48

    [14]

    Hsiao Y C, Wu T, Li M X, Liu Q, Wei Q, Hu B 2015 J. Mater. Chem. A 3 15372

    [15]

    Liu D Y, Kelly T L 2014 Nat. Photonics 8 133

    [16]

    D'Innocenzo V, Grancini G, Alcocer M J, Kandada A R, Stranks S D, Lee M M, Lanzani G, Snaith H J, Petrozza A 2014 Nat. Commun. 5 3586

    [17]

    Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511

    [18]

    Xing G, Mathews N, Sun S, Lim S S, Lam Y M, Gratzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [19]

    Hardin B E, Snaith H J, McGehee M D 2012 Nat. Photonics 6 162

    [20]

    Heo J H, Song D H, Patil B R, Im S H 2015 Isr. J. Chem. 55 966

    [21]

    Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Yum J H, Moser J E, Gratzel M, Park N G 2012 Sci. Rep. 2 591

    [22]

    Heo J H, Im S H, Noh J H, Madal T N, Lim C S, Chang J A, Lee Y H, Kim H J, Sarkar A, Nazeeruddin M K, Gratzel M, Seok S I 2013 Nat. Photonics 7 486

    [23]

    Noh J H, Im S H, Heo J H, Mandal T N, Seok S I 2013 Nano Lett. 13 1764

    [24]

    Yang W S, Noh J H, Jeon N J, Kim Y C, Ryu S, Seo J, Seok S 2015 Science 348 6240

    [25]

    Jeon N J, Noh J H, Kim Y C, Yang W S, Ryu S, Seok S I 2014 Nat. Mater. 13 897

    [26]

    Malinkiewicz O, Yella A, Lee Y H, Espallargas G M, Gratzel M, Nazeeruddin M K, Bolink H J 2014 Nat. Photonics 8 128

    [27]

    Xiao Z G, Dong Q F, Bi C, Shao Y C, Yuan Y B, Huang J S 2014 Adv. Mater. 26 6503

    [28]

    Im J H, Jang I H, Pellet N, Gratzel M, Park N G 2014 Nat. Nanotechnol. 9 927

    [29]

    Seo J, Park S, Kim Y C, Jeon N J, Noh J H, Yoon S C, Seok S I 2014 Energy Environ. Sci. 7 2642

    [30]

    Zhou H P, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z R, You J B, Liu Y S, Yang Y 2015 Science 345 6196

    [31]

    Ball J M, Lee M M, Hey A, Snaith H J 2013 Energy Environ. Sci. 6 1739

    [32]

    Bi D, Moon S J, Higgman L, Boschloo G, Yang L, Johansson E M J, Nazeeruddin M K, Gratzel M 2013 RSC Adv. 3 18762

    [33]

    Mei A, Li X, Liu L F, Ku Z L, Liu T F, Rong Y G, Xu M, Hu M, Chen J Z, Yang Y, Grätzel M, Han H W 2015 Science 345 6194

    [34]

    Chen J Z, Rong Y G, Mei A Y, Xiong Y L, Liu T F, Sheng Y S, Jiang P, Hong L, Guan Y J, Zhu X T, Hou X M, Duan M, Zhao J Q, Li X, Han H W 2015 Adv. Energy Mater. 15 02009

    [35]

    Etgar L, Gao P, Xue Z, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K, Gratzel M 2012 J. Am. Chem. Soc. 134 17396

    [36]

    Shi J, Dong J, L S, Xu Y, Zhu L, Xiao J, Xu X, Wu H, Li D, Luo Y, Meng Q 2014 Appl. Phys. Lett. 104 063901

    [37]

    Heo J H, Song D H, Im S H 2014 Adv. Mater. 26 8179

    [38]

    Lawrence C J 1988 Phys. Fluids 31 2786

    [39]

    Zhao Y, Zhu K 2014 J. Phys. Chem. C 118 9412

    [40]

    Zuo C, Ding L 2014 Nanoscale 6 9935

    [41]

    Xiao M, Huang F Z, Huang W C, Dkhissi Y, Zhu Y, Etheridge J, G-Weale A, Bach U, Cheng Y B, Spiccia L 2014 Angew. Chem. 126 10056

    [42]

    Sun L C 2015 Nat. Chem. 7 684

    [43]

    Salau A M, Sol 1980 Energy Mater. 2 327

    [44]

    Mitzi D B, Prikas M T, Chondroudis K 1999 Chem. Mater. 11 542

    [45]

    Roldn-Carmona C, Malinkiewicz O, Soriano A, Mnguez Espallargas G, Garcia A, Reinecke P, Kroyer T, Dar M I, Nazeeruddin M K, Bolink H J 2014 Energy Environ. Sci. 7 994

    [46]

    Shao Z P, Pan X, Zhang X H, Ye J J, Zhu L Z, Li Y, Ma Y M, Huang Y, Zhu J, Hu L H, Dai S Y 2015 Acta Chim. Sin. 73 267 (in Chinese)[邵志鹏, 潘旭, 张旭辉, 叶加久, 朱梁正, 李毅, 马艳梅, 黄阳, 朱俊, 胡林华, 孔凡太, 戴松元2015化学学报73 267]

    [47]

    Xue Q F, Sun C, Hu Z C, Huang F, Ye X L, Cao Y 2015 Acta Chim. Sin. 73 179 (in Chinese)[薛启帆, 孙辰, 胡志诚, 黄飞, 叶轩立, 曹镛2015化学学报73 179]

    [48]

    Shi J J, Xu X, Li D M, Meng Q B 2015 Small 2014 03534

    [49]

    Roiati V, Mosconi E, Listorti A, Colella S, Gigli G, Angelis F D 2014 Nano Lett. 14 2168

    [50]

    Geng W, Tong C J, Liu J, Zhu W J, Lau W M, Liu L M 2016 Sci. Rep. 6 20131

    [51]

    Yella A, Heiniger L P, Gao P, Nazeeruddin M K, Grötzel M 2014 Nano Lett. 14 2591

    [52]

    Dong X, Hu H, Lin B, Ding J, Yuan N 2014 Chem. Commun. 50 14405

    [53]

    Snaith H J, Grätzel M 2006 Adv. Mater. 18 1910

    [54]

    Wang L, McCleese C, Kovalsky A, Zhao Y, Burda C 2014 J. Am. Chem. Soc. 136 12205

    [55]

    Hu Q, Wu J, Jiang C, Liu T, Que X, Zhu R, Gong Q 2014 ACS Nano 8 10161

    [56]

    Ding X J, Ni L, Ma S B, Ma Y S, Xiao L X, Chen Z J 2015 Acta Phys. Sin. 64 038802 (in Chinese)[丁雄傑, 倪露, 马圣博, 马英壮, 肖立新, 陈志坚2015物理学报64 038802]

    [57]

    Zhu Z, Ma J, Wang Z, Mu C, Fan Z, Du L, Bai Y, Fan L, Yan H, Phillips D L, Yang S 2014 J. Am. Chem. Soc. 136 3760

    [58]

    Wojciechowski K, Stranks S D, Abate A, Sadoughi G, Sadhanala A, Kopidakis N, Rumbles G, Li C, Friend R H, Jen A K Y, Snaith H J 2014 ACS Nano 8 12701

    [59]

    Xiao Y, Han G, Li Y, Li M, Wu J 2014 J. Mater. Chem. A 2 16856

    [60]

    Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grötzel M, Han H 2014 Science 345 295

    [61]

    Eperon G E, Burlakov V M, Goriely A, Snaith H J 2014 ACS Nano 8 591

    [62]

    Nakamura I, Negishi N, Kutsuna S, Ihara T, Sugihara S, Takeuchi E 2000 J. Mol. Catal. A:Chem. 161 205

    [63]

    Wang K, Shi Y T, Dong Q S, Li Y, Wang S F, Yu X F, Wu M Y, Ma T L 2015 J. Phys. Chem. Lett. 6 755

    [64]

    Yang D, Yang R X, Zhang J, Yang Z, Liu S Z, Li C 2015 Energy Environ. Sci. 8 3208

    [65]

    Fu F, Feurer T, Jager T, Avancini E, Bissig B, Yoon S, Buecheler S, Tiwari A N 2015 Nat. Commun. 6 8932

    [66]

    Song Z H, Wang S R, Xiao Y, Li X G 2015 Acta Phys. Sin. 64 033301 (in Chinese)[宋志浩, 王世荣, 肖殷, 李祥高2015物理学报64 033301]

    [67]

    Choi H, Paek S, Lim N, Lee Y, Nazeeruddin M K, Ko J 2014 Chem. Eur. J. 20 10894

    [68]

    Xu B, Bi D Q, Hua Y, Liu P, Cheng M, Grätzel M, Kloo L, Hagfeldt A, Sun L C 2016 Energy Environ. Sci. DOI:10.1039/C6EE00056H

    [69]

    Wang Y K, Yuan Z C, Shi G Z, Li Y X, Li Q, Hui F, Sun B Q, Jiang Z Q, Liao L S 2016 Adv. Funct. Mater. DOI:10.1002/adfm.201504245

    [70]

    Wang J J, Wang S R, Li X G, Zhu L F, Meng Q B, XiaoY, Li D M 2014 Chem. Commun. 50 5829

    [71]

    Lv S T, Han L Y, Xiao J Y, Zhu L F, Shi J J, Wei H Y, Xu Y Z, Dong J, Xu X, Li D M, Wang S R, Luo Y H, Meng Q B, Li X G 2014 Chem. Commun. 50 6931

    [72]

    Krishnamoorthy T, Kunwu F, Boix P P, Li H, Koh T M, Leong W L, Powar S, Grimsdale A, Grötzel M, Mathews N, Mhaisalkar S G 2014 J. Mater. Chem. A 2 6305

    [73]

    Li H R, Fu K, Hagfeldt A, Grötzel M, Mhaisalkar S G, Grimsdale A C 2014 Angew. Chem. Int. Ed. 53 4085

    [74]

    Krishna A, Sabba D, Li H R, Yin J, Boix P P, Soci C, Mhaisalkar S G, Grimsdale A C 2014 Chem. Sci. 5 2702

    [75]

    Xiao J Y, Han L Y, Zhu L F, Lv S T, Shi J J, Wei H Y, Xu Y Z, Dong J, Xu X, Xiao Y, Li D M, Wang S R, Luo Y H, Li X G, Meng Q B 2014 RSC Adv. 4 32918

    [76]

    Jeon N J, Lee J, Noh J H, Nazeeruddin M K, Grötzel M, Seok S I 2013 J. Am. Chem. Soc. 135 19087

    [77]

    Liu J, Wu Y Z, Qin C J, Yang X D, Yasuda T, Islam A, Zhang K, Peng W Q, Chen W, Han L Y 2014 Energy Environ. Sci. 7 2963

    [78]

    Qin P, Paek S, Dar M I, Pellet N, Ko J, Grötzel M, Nazeeruddin M K 2014 J. Am. Chem. Soc. 8 516

    [79]

    Habisreutinger S N, Leijtens T, Eperon G E, Stranks S D, Nicholas R J, Snaith H J 2014 Nano Lett. 14 5561

    [80]

    Chiang C H, Tseng Z L, Wu C G 2014 J. Mater. Chem. A 2 15897

    [81]

    Kwon Y S, Lim J, Yun H J, Kim Y H, Park T 2014 Energy Environ. Sci. 7 1454

    [82]

    Yan W B, Li Y L, Sun W H, Peng H T, Ye S Y, Liu Z W, Bian Z Q, Huang C H 2014 RSC Adv. 4 33039

    [83]

    Ryu S, Noh J H, Jeon N J, Kim Y C, Yang W S, Seo J W, Seok S I 2014 Energy Environ. Sci. 7 2614

    [84]

    Qin P, Tanaka S, Ito S, Tetreault N, Manabe K, Nishino H, Nazeeruddin M K, Grötzel M 2014 Nat. Commun. 5 3834

    [85]

    Wang K C, Jeng J Y, Shen P S, Chang Y C, Diau E W G, Tsai C H, Chao T Y, Hsu H C, Lin P Y, Chen P, Guo T F, Wen T C 2014 Sci. Rep. 4 4756

    [86]

    Feng H, Stoumpos C, Cao D H, Chang P H, Kanatzidis M G 2014 Nat. Photonics 8 489

    [87]

    Chen W, Wu Y Z, Yue Y F, Liu J, Zhang W J, Yang X D, Chen H, Bi E, Ashraful I, Grötzel M, Han L Y 2015 Science 350 6263

    [88]

    McMeekin D P, Sadoughi G, Rehman W, Eperon G E, Saliba M, Hörantner T M, Haghighirad A, Sakai N, Korte L, Rech B, Johnston B M, Herz M L, Snaith H J 2016 Science 351 6269

  • [1]

    Cui J, Yuan H L, Li J P, Xu X B, Shen Y, Lin H, Wang M K 2015 Sci. Technol. Adv. Mater. 16 036004

    [2]

    Green M A, Emery K, Hishikawa Y, Warta W, Dunlop E D 2012 Prog. Photovoltaics 20 12

    [3]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [4]

    Bi D Q, Tress W G, Dar M I, Gao P, Luo J S, Renevier C, Schenk K, Abate A, Giordano F, Baena J P, Decoppe J, Zakeeruddin S M, Nazeeruddin M K, Grötzel M, Hagfeldt A 2016 Sci. Adv. Mater. 2 e1501170

    [5]

    Li Y W, Meng L, Yang Y, Xu G Y, Hong Z, Chen Q, You J B, Li G, Yang Y, Li Y F 2015 Nat. Commun. 7 10214

    [6]

    Gao P, Gratze M, Nazeeruddin M K 2014 Energy Environ. Sci. 7 2448

    [7]

    Burschka J, Pellet N, Moon S J, Baker R H, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316

    [8]

    Zhao Y X, Zhu K 2015 J. Mater. Chem. A 3 9086

    [9]

    Liu M Z, Johnston M B, Snaith H J 2013 Nature 501 395

    [10]

    Chen Q, Zhou H P, Hong Z, Luo S, Duan H S, Wang H H, Liu Y S, Li G, Yang Y 2014 J. Am. Chem. Soc. 136 622

    [11]

    Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088

    [12]

    Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J 2012 Science 338 643

    [13]

    Zhang W, Eperson G E, Snaith H J 2016 Nature Energy 160 48

    [14]

    Hsiao Y C, Wu T, Li M X, Liu Q, Wei Q, Hu B 2015 J. Mater. Chem. A 3 15372

    [15]

    Liu D Y, Kelly T L 2014 Nat. Photonics 8 133

    [16]

    D'Innocenzo V, Grancini G, Alcocer M J, Kandada A R, Stranks S D, Lee M M, Lanzani G, Snaith H J, Petrozza A 2014 Nat. Commun. 5 3586

    [17]

    Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511

    [18]

    Xing G, Mathews N, Sun S, Lim S S, Lam Y M, Gratzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [19]

    Hardin B E, Snaith H J, McGehee M D 2012 Nat. Photonics 6 162

    [20]

    Heo J H, Song D H, Patil B R, Im S H 2015 Isr. J. Chem. 55 966

    [21]

    Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Yum J H, Moser J E, Gratzel M, Park N G 2012 Sci. Rep. 2 591

    [22]

    Heo J H, Im S H, Noh J H, Madal T N, Lim C S, Chang J A, Lee Y H, Kim H J, Sarkar A, Nazeeruddin M K, Gratzel M, Seok S I 2013 Nat. Photonics 7 486

    [23]

    Noh J H, Im S H, Heo J H, Mandal T N, Seok S I 2013 Nano Lett. 13 1764

    [24]

    Yang W S, Noh J H, Jeon N J, Kim Y C, Ryu S, Seo J, Seok S 2015 Science 348 6240

    [25]

    Jeon N J, Noh J H, Kim Y C, Yang W S, Ryu S, Seok S I 2014 Nat. Mater. 13 897

    [26]

    Malinkiewicz O, Yella A, Lee Y H, Espallargas G M, Gratzel M, Nazeeruddin M K, Bolink H J 2014 Nat. Photonics 8 128

    [27]

    Xiao Z G, Dong Q F, Bi C, Shao Y C, Yuan Y B, Huang J S 2014 Adv. Mater. 26 6503

    [28]

    Im J H, Jang I H, Pellet N, Gratzel M, Park N G 2014 Nat. Nanotechnol. 9 927

    [29]

    Seo J, Park S, Kim Y C, Jeon N J, Noh J H, Yoon S C, Seok S I 2014 Energy Environ. Sci. 7 2642

    [30]

    Zhou H P, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z R, You J B, Liu Y S, Yang Y 2015 Science 345 6196

    [31]

    Ball J M, Lee M M, Hey A, Snaith H J 2013 Energy Environ. Sci. 6 1739

    [32]

    Bi D, Moon S J, Higgman L, Boschloo G, Yang L, Johansson E M J, Nazeeruddin M K, Gratzel M 2013 RSC Adv. 3 18762

    [33]

    Mei A, Li X, Liu L F, Ku Z L, Liu T F, Rong Y G, Xu M, Hu M, Chen J Z, Yang Y, Grätzel M, Han H W 2015 Science 345 6194

    [34]

    Chen J Z, Rong Y G, Mei A Y, Xiong Y L, Liu T F, Sheng Y S, Jiang P, Hong L, Guan Y J, Zhu X T, Hou X M, Duan M, Zhao J Q, Li X, Han H W 2015 Adv. Energy Mater. 15 02009

    [35]

    Etgar L, Gao P, Xue Z, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K, Gratzel M 2012 J. Am. Chem. Soc. 134 17396

    [36]

    Shi J, Dong J, L S, Xu Y, Zhu L, Xiao J, Xu X, Wu H, Li D, Luo Y, Meng Q 2014 Appl. Phys. Lett. 104 063901

    [37]

    Heo J H, Song D H, Im S H 2014 Adv. Mater. 26 8179

    [38]

    Lawrence C J 1988 Phys. Fluids 31 2786

    [39]

    Zhao Y, Zhu K 2014 J. Phys. Chem. C 118 9412

    [40]

    Zuo C, Ding L 2014 Nanoscale 6 9935

    [41]

    Xiao M, Huang F Z, Huang W C, Dkhissi Y, Zhu Y, Etheridge J, G-Weale A, Bach U, Cheng Y B, Spiccia L 2014 Angew. Chem. 126 10056

    [42]

    Sun L C 2015 Nat. Chem. 7 684

    [43]

    Salau A M, Sol 1980 Energy Mater. 2 327

    [44]

    Mitzi D B, Prikas M T, Chondroudis K 1999 Chem. Mater. 11 542

    [45]

    Roldn-Carmona C, Malinkiewicz O, Soriano A, Mnguez Espallargas G, Garcia A, Reinecke P, Kroyer T, Dar M I, Nazeeruddin M K, Bolink H J 2014 Energy Environ. Sci. 7 994

    [46]

    Shao Z P, Pan X, Zhang X H, Ye J J, Zhu L Z, Li Y, Ma Y M, Huang Y, Zhu J, Hu L H, Dai S Y 2015 Acta Chim. Sin. 73 267 (in Chinese)[邵志鹏, 潘旭, 张旭辉, 叶加久, 朱梁正, 李毅, 马艳梅, 黄阳, 朱俊, 胡林华, 孔凡太, 戴松元2015化学学报73 267]

    [47]

    Xue Q F, Sun C, Hu Z C, Huang F, Ye X L, Cao Y 2015 Acta Chim. Sin. 73 179 (in Chinese)[薛启帆, 孙辰, 胡志诚, 黄飞, 叶轩立, 曹镛2015化学学报73 179]

    [48]

    Shi J J, Xu X, Li D M, Meng Q B 2015 Small 2014 03534

    [49]

    Roiati V, Mosconi E, Listorti A, Colella S, Gigli G, Angelis F D 2014 Nano Lett. 14 2168

    [50]

    Geng W, Tong C J, Liu J, Zhu W J, Lau W M, Liu L M 2016 Sci. Rep. 6 20131

    [51]

    Yella A, Heiniger L P, Gao P, Nazeeruddin M K, Grötzel M 2014 Nano Lett. 14 2591

    [52]

    Dong X, Hu H, Lin B, Ding J, Yuan N 2014 Chem. Commun. 50 14405

    [53]

    Snaith H J, Grätzel M 2006 Adv. Mater. 18 1910

    [54]

    Wang L, McCleese C, Kovalsky A, Zhao Y, Burda C 2014 J. Am. Chem. Soc. 136 12205

    [55]

    Hu Q, Wu J, Jiang C, Liu T, Que X, Zhu R, Gong Q 2014 ACS Nano 8 10161

    [56]

    Ding X J, Ni L, Ma S B, Ma Y S, Xiao L X, Chen Z J 2015 Acta Phys. Sin. 64 038802 (in Chinese)[丁雄傑, 倪露, 马圣博, 马英壮, 肖立新, 陈志坚2015物理学报64 038802]

    [57]

    Zhu Z, Ma J, Wang Z, Mu C, Fan Z, Du L, Bai Y, Fan L, Yan H, Phillips D L, Yang S 2014 J. Am. Chem. Soc. 136 3760

    [58]

    Wojciechowski K, Stranks S D, Abate A, Sadoughi G, Sadhanala A, Kopidakis N, Rumbles G, Li C, Friend R H, Jen A K Y, Snaith H J 2014 ACS Nano 8 12701

    [59]

    Xiao Y, Han G, Li Y, Li M, Wu J 2014 J. Mater. Chem. A 2 16856

    [60]

    Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grötzel M, Han H 2014 Science 345 295

    [61]

    Eperon G E, Burlakov V M, Goriely A, Snaith H J 2014 ACS Nano 8 591

    [62]

    Nakamura I, Negishi N, Kutsuna S, Ihara T, Sugihara S, Takeuchi E 2000 J. Mol. Catal. A:Chem. 161 205

    [63]

    Wang K, Shi Y T, Dong Q S, Li Y, Wang S F, Yu X F, Wu M Y, Ma T L 2015 J. Phys. Chem. Lett. 6 755

    [64]

    Yang D, Yang R X, Zhang J, Yang Z, Liu S Z, Li C 2015 Energy Environ. Sci. 8 3208

    [65]

    Fu F, Feurer T, Jager T, Avancini E, Bissig B, Yoon S, Buecheler S, Tiwari A N 2015 Nat. Commun. 6 8932

    [66]

    Song Z H, Wang S R, Xiao Y, Li X G 2015 Acta Phys. Sin. 64 033301 (in Chinese)[宋志浩, 王世荣, 肖殷, 李祥高2015物理学报64 033301]

    [67]

    Choi H, Paek S, Lim N, Lee Y, Nazeeruddin M K, Ko J 2014 Chem. Eur. J. 20 10894

    [68]

    Xu B, Bi D Q, Hua Y, Liu P, Cheng M, Grätzel M, Kloo L, Hagfeldt A, Sun L C 2016 Energy Environ. Sci. DOI:10.1039/C6EE00056H

    [69]

    Wang Y K, Yuan Z C, Shi G Z, Li Y X, Li Q, Hui F, Sun B Q, Jiang Z Q, Liao L S 2016 Adv. Funct. Mater. DOI:10.1002/adfm.201504245

    [70]

    Wang J J, Wang S R, Li X G, Zhu L F, Meng Q B, XiaoY, Li D M 2014 Chem. Commun. 50 5829

    [71]

    Lv S T, Han L Y, Xiao J Y, Zhu L F, Shi J J, Wei H Y, Xu Y Z, Dong J, Xu X, Li D M, Wang S R, Luo Y H, Meng Q B, Li X G 2014 Chem. Commun. 50 6931

    [72]

    Krishnamoorthy T, Kunwu F, Boix P P, Li H, Koh T M, Leong W L, Powar S, Grimsdale A, Grötzel M, Mathews N, Mhaisalkar S G 2014 J. Mater. Chem. A 2 6305

    [73]

    Li H R, Fu K, Hagfeldt A, Grötzel M, Mhaisalkar S G, Grimsdale A C 2014 Angew. Chem. Int. Ed. 53 4085

    [74]

    Krishna A, Sabba D, Li H R, Yin J, Boix P P, Soci C, Mhaisalkar S G, Grimsdale A C 2014 Chem. Sci. 5 2702

    [75]

    Xiao J Y, Han L Y, Zhu L F, Lv S T, Shi J J, Wei H Y, Xu Y Z, Dong J, Xu X, Xiao Y, Li D M, Wang S R, Luo Y H, Li X G, Meng Q B 2014 RSC Adv. 4 32918

    [76]

    Jeon N J, Lee J, Noh J H, Nazeeruddin M K, Grötzel M, Seok S I 2013 J. Am. Chem. Soc. 135 19087

    [77]

    Liu J, Wu Y Z, Qin C J, Yang X D, Yasuda T, Islam A, Zhang K, Peng W Q, Chen W, Han L Y 2014 Energy Environ. Sci. 7 2963

    [78]

    Qin P, Paek S, Dar M I, Pellet N, Ko J, Grötzel M, Nazeeruddin M K 2014 J. Am. Chem. Soc. 8 516

    [79]

    Habisreutinger S N, Leijtens T, Eperon G E, Stranks S D, Nicholas R J, Snaith H J 2014 Nano Lett. 14 5561

    [80]

    Chiang C H, Tseng Z L, Wu C G 2014 J. Mater. Chem. A 2 15897

    [81]

    Kwon Y S, Lim J, Yun H J, Kim Y H, Park T 2014 Energy Environ. Sci. 7 1454

    [82]

    Yan W B, Li Y L, Sun W H, Peng H T, Ye S Y, Liu Z W, Bian Z Q, Huang C H 2014 RSC Adv. 4 33039

    [83]

    Ryu S, Noh J H, Jeon N J, Kim Y C, Yang W S, Seo J W, Seok S I 2014 Energy Environ. Sci. 7 2614

    [84]

    Qin P, Tanaka S, Ito S, Tetreault N, Manabe K, Nishino H, Nazeeruddin M K, Grötzel M 2014 Nat. Commun. 5 3834

    [85]

    Wang K C, Jeng J Y, Shen P S, Chang Y C, Diau E W G, Tsai C H, Chao T Y, Hsu H C, Lin P Y, Chen P, Guo T F, Wen T C 2014 Sci. Rep. 4 4756

    [86]

    Feng H, Stoumpos C, Cao D H, Chang P H, Kanatzidis M G 2014 Nat. Photonics 8 489

    [87]

    Chen W, Wu Y Z, Yue Y F, Liu J, Zhang W J, Yang X D, Chen H, Bi E, Ashraful I, Grötzel M, Han L Y 2015 Science 350 6263

    [88]

    McMeekin D P, Sadoughi G, Rehman W, Eperon G E, Saliba M, Hörantner T M, Haghighirad A, Sakai N, Korte L, Rech B, Johnston B M, Herz M L, Snaith H J 2016 Science 351 6269

  • [1] 范伟利, 杨宗林, 张振雲, 齐俊杰. 高效无空穴传输层碳基钙钛矿太阳能电池的制备与性能研究. 物理学报, 2018, 67(22): 228801. doi: 10.7498/aps.67.20181457
    [2] 李晓果, 张欣, 施则骄, 张海娟, 朱成军, 詹义强. n-i-p结构钙钛矿太阳能电池界面钝化的研究进展. 物理学报, 2019, 68(15): 158803. doi: 10.7498/aps.68.20190468
    [3] 黄林泉, 周玲玉, 于为, 杨栋, 张坚, 李灿. 石墨烯衍生物作为有机太阳能电池界面材料的研究进展. 物理学报, 2015, 64(3): 038103. doi: 10.7498/aps.64.038103
    [4] 杨迎国, 阴广志, 冯尚蕾, 李萌, 季庚午, 宋飞, 文闻, 高兴宇. 湿度环境下钙钛矿太阳能电池薄膜微结构演化的同步辐射原位实时研究. 物理学报, 2017, 66(1): 018401. doi: 10.7498/aps.66.018401
    [5] 丁雄傑, 倪露, 马圣博, 马英壮, 肖立新, 陈志坚. 钙钛矿太阳能电池中电子传输材料的研究进展. 物理学报, 2015, 64(3): 038802. doi: 10.7498/aps.64.038802
    [6] 石将建, 卫会云, 朱立峰, 许信, 徐余颛, 吕松涛, 吴会觉, 罗艳红, 李冬梅, 孟庆波. 钙钛矿太阳能电池中S形伏安特性研究. 物理学报, 2015, 64(3): 038402. doi: 10.7498/aps.64.038402
    [7] 王言博, 崔丹钰, 张才益, 韩礼元, 杨旭东. 钙钛矿太阳能电池研究进展: 空间电势与光电转换机制. 物理学报, 2019, 68(15): 158401. doi: 10.7498/aps.68.20190569
    [8] 宋志浩, 王世荣, 肖殷, 李祥高. 新型空穴传输材料在钙钛矿太阳能电池中的研究进展. 物理学报, 2015, 64(3): 033301. doi: 10.7498/aps.64.033301
    [9] 曹汝楠, 徐飞, 朱佳斌, 葛升, 王文贞, 徐海涛, 徐闰, 吴杨琳, 马忠权, 洪峰, 蒋最敏. 平面型钙钛矿太阳能电池温度相关的光伏性能时间响应特性. 物理学报, 2016, 65(18): 188801. doi: 10.7498/aps.65.188801
    [10] 刘毅, 徐征, 赵谡玲, 乔泊, 李杨, 秦梓伦, 朱友勤. 双添加剂处理电子传输层富勒烯衍生物[6,6]-苯基-C61丁酸甲酯对钙钛矿太阳能电池性能的影响. 物理学报, 2017, 66(11): 118801. doi: 10.7498/aps.66.118801
    [11] 余柏林, 唐新峰, 祁 琼, 张清杰. CoSb3纳米热电材料的制备及热传输特性. 物理学报, 2004, 53(9): 3130-3135. doi: 10.7498/aps.53.3130
    [12] 王基铭, 陈科, 谢伟广, 时婷婷, 刘彭义, 郑毅帆, 朱瑞. 溶液法制备全无机钙钛矿太阳能电池的研究进展. 物理学报, 2019, 68(15): 158806. doi: 10.7498/aps.68.20190355
    [13] 王栋, 朱慧敏, 周忠敏, 王在伟, 吕思刘, 逄淑平, 崔光磊. 溶剂对钙钛矿薄膜形貌和结晶性的影响研究. 物理学报, 2015, 64(3): 038403. doi: 10.7498/aps.64.038403
    [14] 刘晓敏, 李亦回, 王兴涛, 赵一新. 有机铵盐表面稳定化CsPbI2Br全无机钙钛矿. 物理学报, 2019, 68(15): 158805. doi: 10.7498/aps.68.20190303
    [15] 夏祥, 刘喜哲. CH3NH3I在制备CH3NH3PbI(3-x)Clx钙钛矿太阳能电池中的作用. 物理学报, 2015, 64(3): 038104. doi: 10.7498/aps.64.038104
    [16] 刘浩, 薛玉明, 乔在祥, 李微, 张超, 尹富红, 冯少君. 铜锌锡硫薄膜材料及其器件应用研究进展. 物理学报, 2015, 64(6): 068801. doi: 10.7498/aps.64.068801
    [17] 兰林锋, 张鹏, 彭俊彪. 氧化物薄膜晶体管研究进展. 物理学报, 2016, 65(12): 128504. doi: 10.7498/aps.65.128504
    [18] 付鹏飞, 虞丹妮, 彭子健, 龚晋慷, 宁志军. 扭曲二维结构钝化的钙钛矿太阳能电池. 物理学报, 2019, 68(15): 158802. doi: 10.7498/aps.68.20190306
    [19] 夏俊民, 梁超, 邢贵川. 喷墨打印钙钛矿太阳能电池研究进展与展望. 物理学报, 2019, 68(15): 158807. doi: 10.7498/aps.68.20190302
    [20] 张翱, 陈云琳, 闫君, 张春秀. 有机阳离子对卤素钙钛矿太阳能电池性能的影响. 物理学报, 2018, 67(10): 106701. doi: 10.7498/aps.67.20180236
  • 引用本文:
    Citation:
计量
  • 文章访问数:  1789
  • PDF下载量:  1342
  • 被引次数: 0
出版历程
  • 收稿日期:  2016-03-15
  • 修回日期:  2016-09-07
  • 刊出日期:  2016-12-05

钙钛矿太阳能电池近期进展

  • 1. 中国计量大学材料科学与工程学院, 杭州 310018
  • 通信作者: 钟敏, zhongmin@cjlu.edu.cn
    基金项目: 

    国家自然科学基金(批准号:21471140,21101143)资助的课题.

摘要: 近几年来,基于有机无机金属卤化物钙钛矿(ABX3)的太阳能电池由于其独特的物理化学性质受到了广泛的关注.这种钙钛矿材料具有很高的消光系数、较强的电荷传递能力、长的载流子寿命、长的载流子扩散距离以及特殊的双极性,同时低成本易制作.自2009年至今,钙钛矿太阳能电池的光电转换效率从最初的3.8%增长到了20.8%,使之成为最有可能在未来代替传统单晶硅太阳能电池的新型太阳能电池.同时,由于钙钛矿具有双极性,故钙钛矿太阳能电池的结构也有多种,最常见的结构有介孔结构、平面结构、介观超结构、无空穴传输层结构等.本文主要介绍钙钛矿太阳能电池的发展、电池结构及其对光电池性能的影响、钙钛矿薄膜的制备方法,同时探讨了钙钛矿在电子传输层上的吸附模型和电荷在电池界面中的传输机理以及界面工程,并介绍该类型电池在近期所获得的突破及未来可能的发展方向,以便对钙钛矿太阳能电池有进一步的了解.

English Abstract

参考文献 (88)

目录

    /

    返回文章
    返回