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Studies on the high-lying vibrational energies and molecular dissociation energies for some electronic states of K2 molecule

Liu Yan Ren Wei-Yi Wang A-Shu Liu Song-Hong

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Studies on the high-lying vibrational energies and molecular dissociation energies for some electronic states of K2 molecule

Liu Yan, Ren Wei-Yi, Wang A-Shu, Liu Song-Hong
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  • In view of the importance of the full vibrational spectrum and the molecular dissociation energies of K2 molecule to many studies and applications, this paper uses the SUN and REN's algebraic method (AM) which is based on perturbation theory and the algebraic energy method (AEM) based on the AM to study the vibrational spectroscopic constants, and the full vibrational spectra (Eυ) including the excited high-lying vibrational energies of electronic states X1Σ+g,a3Σ+u,0-g,B1Πu and 33Πg of K2 molecule, and obtain the accurate theoretical values of dissociation energies(De) of these states. The full vibrational spectra, especially the high-lying vibrational energies and dissociation energies, are difficult to determine experimentally, so this study can provides physical data for scientific research.
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  • Abstract views:  7467
  • PDF Downloads:  649
  • Cited By: 0
Publishing process
  • Received Date:  08 June 2007
  • Accepted Date:  08 July 2007
  • Published Online:  20 March 2008

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