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Machine learning empowered electronic structure calculations: Progress, challenges, and prospects
LI Yuting, YANG Jiong, XI Jinyang
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Density functional theory (DFT) serves as the primary method of calculating electronic structures in physics, chemistry, and materials science. However, its practical application is fundamentally limited by a computational cost that scales cubically with system size, making high-precision studies of complex or large-scale materials prohibitively expensive. This review addresses the key challenge by examining the rapidly evolving paradigm of integrating machine learning (ML) with first-principles calculations to significantly accelerate and expand electronic structure prediction. Our primary objective is to provide a comprehensive and critical overview of the methodological advances, physical outcomes, and transformative potential of this interdisciplinary field.The core methodological progress involves a shift from black-box property predictors to symmetry-preserving, transferable models that learn the fundamental Hamiltonian—the central quantity from which diverse electronic properties are derived. We detail this evolution, beginning with pioneering applications in molecular systems by using graph neural networks (e.g., SchNOrb, DimeNet) to predict energies, wavefunctions, and Hamiltonian matrices with meV-level accuracy. This review then focuses on the critical extension to periodic solids, where maintaining symmetries such as E(3)-equivariance and handling vast configurational spaces are of utmost importance. We systematically analyze three leading model families that define the state-of-the-art: the DeepH series, which uses local coordinate message passing and E(3)-equivariant networks to achieve sub-meV accuracy and linear scaling; the HamGNN framework, built on rigorous equivariant tensor decomposition, which excels in modeling systems with spin-orbit coupling and charged defects; and the DeePTB approach, which leverages deep learning for tight-binding Hamiltonian parameterization, enabling quantum-accurate simulations of millions of atoms.These methods yield significant physical results and computational breakthroughs. Key outcomes include: 1) unprecedented accuracy and speed. Models consistently achieve Hamiltonian prediction mean absolute errors (MAE) below 1 meV (e.g., DeepH-E3: ~0.4 meV in graphene; HamGNN: ~1.5 meV in QM9 molecules), along with computational speedups of 3 to 5 orders of magnitude compared with traditional DFT. 2) Scale bridging. Successful applications now range from small molecules to defect-containing supercells with over 10000 atoms (e.g., HamGNN-Q on a 13,824-atom GaAs defect) and even to millions of atoms for optoelectronic property simulations (DeePTB). 3) Expanded application scope. This review highlights how these ML-accelerated tools are revolutionizing research in previously intractable areas: predicting spectroscopic properties of molecules (e.g., DetaNet for NMR/UV-Vis spectra), elucidating electronic structures of topological materials and magnetic moiré systems, computing electron-phonon coupling and carrier mobility with DFT-level accuracy but far greater efficiency (HamEPC framework), and enabling high-throughput screening for materials design.In conclusion, ML-accelerated electronic structure calculation has matured into a powerful paradigm, transitioning from a proof-of-concept to a tool capable of delivering DFT-fidelity results at dramatically reduced cost for systems of realistic scale and complexity. However, challenges remain, including model interpretability (“black-box” nature), transferability to unseen elements, and seamless integration with existing plane-wave DFT databases. Future directions include physics-constrained unsupervised learning (e.g., DeepH-zero), developing more universal and element-agnostic architectures, and creating closed-loop, artificial intelligence (AI)-driven discovery pipelines. By overcoming current limitations, these methods have the potential to fundamentally change the field of materials research, accelerating the process from atomistic simulation to rational material design and discovery.
Very-high-frequency magnetic core films for integrated volatage regulators
PENG Chuan, HE Yuhan, BAI Feiming
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With the rise and widespread applications of three-dimensional (3D) heterogeneous integration technology, inductive voltage regulators are becoming increasingly important for mobile terminals and high-computing-power devices, while also offering significant development opportunities for high-frequency soft magnetic films. According to the requirements of on-chip power inductors, we first review the advantages and limitations of three types of magnetic core films: permalloy, Co-based amorphous metal films, and FeCo-based nanogranular composite films, with a focus on the technical requirements and challenges of several μm-thick laminated magnetic core films. Secondly, almost all on-chip inductors are hard-axis excited, which means that the magnetic field of inductors should be parallel to the hard axis of the magnetic core. We thus compare the characteristics of two methods of preparing large-area films, i.e. applying an in-situ magnetic field and oblique sputtering, both of which can effectively induce in-plane uniaxially magnetic anisotropy (IPUMA). Their influences on the static and high-frequency soft magnetic properties are also compared. The influences of film patterning on the domain structures and high-frequency magnetic losses of magnetic cores, as well as corresponding countermeasures, are also briefly analyzed. Furthermore, the temperature stability of magnetic permeability and anisotropy of magnetic core films is discussed from the perspectives of process compatibility and long-term reliability. Although the Curie temperatures and crystallization temperatures of the three types of magnetic core films are relatively high, the upper limits of their actual process temperatures are affected by the thermal effects on the alignment of magnetic atomic pairs, microstructural defects, and grain size. Finally, the current bottlenecks in testing high-frequency and large-signal magnetic losses of magnetic core films are discussed, and potential technical approaches to achieving magnetic core films that meet the future demands of on-chip power inductors for higher saturation current and lower magnetic losses are outlined.
Multi-Plane Light Conversion Coherent Beam Combining for Optical Field Manipulation
Zhou Hongbing, Tao Rumao, Yan Yuefang, Liu Chenxu, Feng Xi, Qin Yu, Li Min, Xu Dangpeng, Lin Honghuan, Peng Zhitao, Wang Jianjun, Yan Lixin, Jing Feng
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Multi-Plane Light Conversion (MPLC) coherent beam combining (CBC) presents a promising approach for flexible optical field manipulation, overcoming the limitations of low energy utilization and poor beam quality in traditional CBC methods. However, its potential for generating diverse structured beams and the underlying design principles remain underexplored. In this work, theoretical model of MPLC-based CBC system was constructed to perform numerical investigation on the property and capability of MPLC optical field manipulation. Localized phase coding and vortex phase coding methods were proposed for mode mapping design to enhance the match between input and output modes. By employing multi-dimensional evaluation metrics including conversion efficiency (η), side-lobe suppression ratio (SSR), and phase matching degree (PMD), the performance of different coding strategies was systematically compared. The results manifested that while random coding yielded an average efficiency of 92% for five multi-focus beams, both localized and vortex coding significantly enhanced output quality, achieving a superior average efficiency of 97.1%. Based on the proposed encoding methods, MPLC successfully produced 5 Laguerre-Gaussian (LG) beams, 5 geometric shapes, and 5 letter patterns with remarkably high average efficiencies, reaching 97.4%, 99.2%, and 96.5%, respectively, accompanied by high SSR (>14 dB) and PMD (>96%). Furthermore, a strategy for arbitrary beam shaping by decomposing the target field into a linear combination of orthogonal modes was proposed and confirmed using a 21-mode MPLC. Simultaneously, its flexibility and the consequential requirement for strong amplitude modulation on the laser array were discussed. Finally, the relationship between the number of supported modes and the required number of phase plates was also analyzed, illustrating that maintaining high efficiency for a larger number of modes necessitates a significant increase in the number of phase plates. This study effectively generated a wide range of structured beams with minimal stray light and high energy utilization, demonstrating that MPLC-based CBC is a powerful and versatile technique for high-efficiency, high-quality optical field manipulation. Future work should focus on optimizing the design to reduce the requisite number of planes, paving the way for practical applications in high-power laser processing, optical communications, and quantum optics.
Mid-infrared pure-state quantum light source based on lithium niobate waveguides
Huang Yu-Hang, Wang Dong-Zhou, Ke Shao-Lin, Jin Rui-Bo
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Mid-infrared quantum light sources hold broad application prospects in fields such as gas sensing and infrared thermal imaging. However, currently used mid-infrared quantum entanglement light sources primarily rely on bulk periodically poled lithium niobate (PPLN) crystals, which suffer from limitations in both brightness and integration. This paper proposes a theoretical scheme based on lithium niobate thin films utilizing a 1556.9 nm pump to generate entangled photon pairs with a central wavelength of 3113.8 nm. Through optimized waveguide structure and periodic polarization design, Type-II phase matching and group velocity matching are achieved. This enables transverse electric (TE)-polarized pump input to downconvert to generate photon pairs with TE and transverse magnetic (TM) polarization. Furthermore, by combining a domain arrangement algorithm for customized design of the PPLN waveguide’s polarization direction, precise phase matching is achieved, yielding a quantum light source with a purity as high as 0.999 and a brightness reaching 6.18 × 106 cps/mW, representing a three-order-of-magnitude enhancement over bulk PPLN crystal sources. This work offers a promising solution for realizing high-brightness, high-purity on-chip quantum light sources in the mid-infrared band.
Polarization-controlled Generation and Superposition of Plasmonic Orbital Angular Momentum States
ZHOU Haoran, YUAN Weiye, CUI Junshuo, ZHANG Yuqin, SONG Hongsheng
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Recent studies on orbital angular momentum (OAM) states in the surface plasmon polariton (SPP) field have primarily focused on the generation of single OAM modes and the evolution of OAM states with various topological charges. However, achieving coherent superposition of two OAM states with well-defined phase relations through precise nanostructure design remains challenging. In this work, we propose a plasmonic nanostructure consisting of paired rectangular slits arranged along circular or segmented Archimedes spiral. The Archimedean spiral of various radii in azimuthal angle provides a geometry-dependent helical phase; coupled with a rotated nanoslit pair, it introduces a geometric phase of twice the rotated angle. By combining chiral spiral with nanoslit pair units, the design both generates plasmonic OAM eigenstates with arbitrary topological charges and enables their coherent superposition. The amplitudes of the two constituent OAM states are continuously tunable through the degree of polarization of the incident light, and their relative phase difference is controlled by the polarization angle, enabling arbitrary superposition of the plasmonic OAM states with continuously variable amplitude ratios and phase differences. Theoretical analysis and numerical simulations demonstrate that circularly polarized illumination produces distinct OAM pure states, whereas linearly polarized light leads to equal-amplitude superposition states with structured field distributions. Moreover, rotating the polarization angle continuously adjusts the relative phase between the eigenstates and produces a predictable rotation of the resultant interference pattern. These results provide a new approach for coherent control of plasmonic OAM states and offer design guidelines for multifunctional on-chip optical field manipulation devices.
Optical quantum storage of cold atomic ensemble mediated by magnetic field
Dong Liang, Chen Linyu, Wang Xingchang, Liang Xinyun, Zuo Ying, Chen Jiefei
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Optical quantum memory plays a critical role in fields such as quantum computing, quantum sensing, and quantum communication. Cold atomic systems, owing to their excellent quantum coherence, controllability, and exceptional capability in handling weak optical fields, have emerged as one of the key platforms for faithful optical quantum state storage. Among these, cigarette-shaped, with up to 2 cm or more, cold atomic ensembles exhibit over 85 % storage effciency due to their optical depth reaching 100 or more. However, further applications are significantly hindered by the limited storage lifetimes caused by inhomogeneous residual magnetic fields along the long atomic cloud. This study analyzes the issue of atomic spin decoherence induced by non-uniform magnetic field with linear gradient, and obtain the result that storage lifetime dramatically decreases with this increasing linear gradient. Further, we demonstrate that in our two-dimensional magneto-optical trap system with a longitudinal atom-light interaction length of 2.7 cm, a DC magnetic field can provide a quantization axis, suppress the effects of inhomogeneous fields,and regulate the cycles of spin dephasing and rephasing. With the proper setting for optical pumping process of magnetic quantum levels, adjusting the pump laser power effectively controls the atomic population distribution, thereby precisely optimizes the light storage effciency at different time bins, as shown in Fig. 7(a). Based on these findings, we propose a scheme for storage of time-bin entangled photon pairs, who are prepared at two different time slots of DLCZ process. A bias magnetic field on the generation MOT (left panel of Fig. 7) induces modulation on the storage time as (a), so that read pulse exerted on rj reads only wj (j= 1, 2). Therefore, the two photonic time bins becomes distingushable and orthogonal. The retrieved photon pairs thus have fully controllable time bins for both photons. Compared to other degrees of freedom, the time encrypted photonic entanglement remains robust in long-distance network.
Research progress of Al1–xScxN ferroelectric thin films
ZHAO Yongsong, ZHOU Dayu, TONG Yi, WANG Xinpeng, QIN Haiming
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Al1–xScxN, as a new generation of wurtzite-type ferroelectric material, has become a focal point in ferroelectric materials research in recent years, due to its high remnant polarization, nearly ideal rectangular polarization-electric field hysteresis loops, inherent compatibility with back-end-of-line (BEOL) CMOS processes, and stable ferroelectric phase structure. The systematic and in-depth studies on the preparation, property modulation, and device applications of this material have been conducted. This paper provides a comprehensive review of the research progress of Al1–xScxN ferroelectric thin films. Regarding the factors influencing ferroelectric properties, it emphasizes the regulatory effects of Sc doping concentration on phase transition and coercive field, explores the influences of substrate (such as Si and Al2O3) and bottom electrode (such as Pt, Mo, and HfN0.4) on thin-film orientation, stress, and interface quality, and systematically summarizes the influences of deposition conditions, film thickness, testing frequency, and temperature on ferroelectric performance. At the level of physical mechanisms governing polarization switching, this review elaborates on the domain structure, domain wall motion dynamics, nucleation sites and growth mechanisms in the Al1–xScxN switching process, revealing its microscopic response behavior under external electric fields and the mechanisms underlying fatigue failure. In terms of application prospects, Al1–xScxN thin films show significant advantages in memory devices such as ferroelectric random-access memory (FeRAM), ferroelectric field-effect transistors (FeFETs), and ferroelectric tunnel junctions (FTJs). Their high performance and integration compatibility provide strong technical support for developing next-generation, high-density, low-power ferroelectric memory and nanoelectronic devices.
Numerical simulation of magnetism and magnetocaloric effect of Mn-Rich Ni-Mn-Ga alloy
WANG Bo, ZHANG Yufen, SHAO Hui, ZHANG Zeyu, HU Yong
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This work investigates the magnetocaloric effect-based green magnetic refrigeration technology, with a focus on Ni-Mn-Ga Heusler alloy as a promising magnetic refrigerant candidate. To elucidate the role of Mn-rich composition in regulating the magnetic and magnetocaloric properties, a multi-scale computational approach integrating first-principles calculations and Monte Carlo simulations is adopted. This method enables a detailed analysis of how Mn atoms occupying Ni and Ga sites influence the microstructure, atomic magnetic moments, exchange interactions, and macroscopic magnetocaloric response of the alloy. The results indicate that Mn site occupancy critically affects the magnetic performance: the occupation of Ni sites reduces the total magnetic moment and Curie temperature, thereby reducing the magnetic entropy change; in contrast, Mn occupying Ga sites significantly enhances both the total magnetic moment and the magnetic entropy change. Notably, the Ni8Mn7Ga1 alloy achieves a maximum magnetic entropy change of 2.32 J·kg–1·K–1 under a 2 T magnetic field, which significantly exceeds that of the stoichiometric Ni8Mn4Ga4 alloy. Further electronic structure analysis reveals that Mn content variation modulates the density of states near the Fermi level and optimizes orbital hybridization and ferromagnetic exchange interactions, thus adjusting the magnetic phase transition behavior. Critical exponent analysis confirms that the magnetic interactions are inherently long-range and tend toward mean-field behavior with compositional changes. By establishing a clear “composition-structure-magnetism-magnetocaloric performance” relationship on an atomic scale, this work provides theoretical foundations for designing high-performance, low-hysteresis magnetic refrigeration materials.
Lattice-induced dual transparency in terahertz hybrid metasurfaces
HOU Yunfei, WANG Wenxian, ZHANG Yigong, XIONG Lei
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Electromagnetically induced transparency (EIT)-like phenomenon in terahertz (THz) metasurfaces facilitates flexible manipulation of electromagnetic wave transmission windows and enables light deceleration, rendering this phenomenon suitable for applications such as modulators, absorbers, slow light devices, and more. Traditional design methods focus on the coupling between bright-dark modes and bright-bright modes within the unit cell by leveraging interference cancellation effects to regulate electromagnetic wave transmission. Notably, the periodicity of the array structure also plays a pivotal role in adjusting the amplitude and resonance intensity of the transparent window, a phenomenon known as lattice-induced transparency (LIT). In this work, we introduce a gold nanorod structure and an S-shaped gold split-ring resonator supported on a vanadium dioxide (VO2) thin film to investigate LIT. Unlike traditional structures that solely consider single bright-bright or bright-dark mode coupling, our proposed structure integrates both bright-bright and bright-dark modes coupling. Furthermore, the dark mode in our structure is not a traditional multipolar mode but rather a surface lattice resonance (SLR) arising from the coupling between lattice modes and the local surface plasmon resonance (LSPR) of the structure itself.Through the analysis of simulated transmission spectra for the individual gold nanorod and S-shaped split-ring structures, we observe that the gold nanorod exhibits LSPR at 0.985 THz, whereas the S-shaped split-ring structure demonstrates LSPR at 0.51 THz and SLR at 1.025 THz. When combined together, these structures form transparent windows with transmission rates of 66.03% at 0.643 THz and and 59.4% at 1.01 THz due to the interplay of bright-bright and bright-dark mode coupling. Upon examining the electric field distribution in the x-y plane, we find that the electric field energy is predominantly concentrated on the S-shaped split-ring.To gain deeper insights into each resonance mode, we employ multipolar decomposition to quantify resonance scattering energy. Our findings show that both transparent windows are predominantly governed by electric dipole scattering energy. Further investigations indicate that as the array structure’s period varies from 60 μm to 95 μm, the lattice mode progressively couples into the high frequency transmission valley (1.031 THz), giving rise to a high frequency hybrid mode (HFHM). The Q value of this mode initially increases and then decreases, peaking at 27 when the period is 84 μm. Similarly, as the period continues to increase, the lattice mode couples into the low frequency resonance valley (0.76 THz), forming a low frequency hybrid mode (LFHM) with a Q value that reaches a maximum of 51 at 115 μm—approximately one order of magnitude higher than that at a period of 60 μm. Additionally, as the periodicity increases, the near field coupling effect between adjacent units diminishes, leading to the gradual disappearance of the two transparent windows.To achieve active control over these transparent windows, we vary the conductivity of VO2 from 20 S/m to 30000 S/m, resulting in a decrease in the transmission amplitudes of the two transparent windows to 37.58% and 3.39%, respectively. Finally, we investigate the slow light effect of the two transparent windows and compare their maximum group delays, which are found to be 8.1 ps for each window. The terahertz metasurface proposed in this study paves the way for the design of future dynamically tunable sensing and slow light devices.
Dual-paramter-scanning-based quantum- memory- assisted measurement-device-independent quantum key distribution protocol
LIU Chang, SUN Mingshuo, LUO Yizhen, DONG Shuyan, ZHANG Chunhui, WANG Qin
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Measurement-device-independent quantum key distribution (MDI-QKD) protocol can effectively resist all possible attacks targeting the measurement devices in a quantum key distribution (QKD) system, thus exhibiting high security. However, due to the protocol’s high sensitivity to channel attenuation, its key generation rate and transmission distance are significantly limited in practical applications.To improve the performance of MDI-QKD, researchers have proposed quantum-memory (QM)-assisted MDI-QKD protocol, which has enhanced the protocol's performance to a certain extent. Nevertheless, under finite-size conditions where the total number of transmitted pulses is limited, accurately estimating the relevant statistical parameters is still a challenge. As a result, existing QM-assisted MDI-QKD schemes still encounters issues such as low key rates and limited secure transmission distances.To solve these problems, this work proposes a novel improved finite-size QM-assisted MDI-QKD protocol. By utilizing quantum memories to temporarily store early-arriving pulses and release them synchronously, the protocol effectively reduces the influence caused by channel asymmetry. Additionally, the protocol introduces a four-intensity decoy-state method to improve the estimation accuracy of single-photon components. Meanwhile, to mitigate the influence of finite-length effects on QM schemes, the proposed protocol combines a collective constraint model and a double-scanning algorithm to jointly estimate scanning error counts and vacuum-related counts. This approach enhances the estimation accuracy of the single-photon detection rate and phase error rate under finite-size conditions, thereby significantly improving the secure key rate of the MDI-QKD system.Simulation results show that under the same experimental conditions, compared with the existing QM-assisted three-intensity decoy-state MDI-QKD protocol and the four-intensity decoy-state MDI-QKD protocol based on Heralded Single-photon Source (HSPS), the proposed protocol extends the secure transmission distance by more than 30 km and 100 km, respectively. This proves that under the same parameter settings, the proposed scheme exhibits significant advantages in both key rate and secure transmission distance. Therefore, this research provides important theoretical references and valuable benchmarks for developing long-distance, high-security quantum communication networks.
Zero resistance and strange metal behavior of high-temperature superconducting material La3Ni2O7
YE Kaixin, ZHANG Yanan, JIAO Lin, YUAN Huiqiu
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In 2023, signatures of pressure-induced high-temperature superconductivity with an onset transition at 80 K were observed in La3Ni2O7. However, the absence of zero resistance cast doubts on its superconductivity. By using a recently developed quasi-hydrostatic pressure technique based on a diamond anvil cell, our group successfully observe a sharp superconducting transition with a zero resistance below 40 K, providing a crucial evidence for establishing the existence of high-temperature superconductivity in La3Ni2O7. Furthermore, a pronounced linear-temperature dependent resistivity is observed above its superconducting transition, suggesting an nontraditional nature of its superconducting pairing state.In addition to the discovery of zero resistance, our transport study also revises the pressure-temperature phase diagram of La3Ni2O7. It is found that La3Ni2O7 remains metallic under pressure and there is no evidence for a metal-insulator transition if the samples are properly handled during preparations. Upon increasing pressure, the density wave transition, observed near 130 K at ambient pressure, is quickly suppressed. At approximately 13.7 GPa, evidence for a pressure-induced structural phase transition is observed near 250 K, followed by a superconducting transition with an onset temperature at $ T_{\mathrm{c}}^{\text{onset}}\approx $ 37.5 K. $ {T}_{\mathrm{c}} $ initially increases with the increase of pressure, reaching a maximum value of $ T_{\mathrm{c}}^{\text{onset}}\approx $ 66 K at 20.5 GPa. On the other hand, the slope $ {A}^{'} $ of the T-linear resistivity above $ {T}_{\mathrm{c}} $ monotonically decreases with the increase of pressure, showing a relation of $ {T}_{\mathrm{c}}\propto \sqrt{{A}^{'}} $ above 20.5 GPa, which is similar to those recently observed in the cuprate oxides. Furthermore, the inverse Hall coefficient 1/RH, derived from the Hall resistance measurements, reveals a notable increase at pressures above 15 GPa upon entering the high pressure phase, suggesting a substantial increase of the carrier concentration in the superconducting regime, which is further supported by band structure calculations.In this work, we present a brief summary of our research advances, and compare them with those observed in other nickelate superconductors.
Multiple diagnostic techniques measured neutral gas temperatures in N2 plasma and Ar-N2 mixed plasma
AN Yanlin, ZHAO Mingliang, LUO Qian, GAO Fei, WANG Younian
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Low-temperature inductively coupled radio-frequency plasma is a key plasma source in semiconductor fabrication, where the neutral gas temperature (Tg) is one of the critical parameters influencing chemical reactions and plasma characteristics. Precise control of Tg significantly influences processes such as thin-film deposition and reactive ion etching, with its synergistic interaction with plasma parameters (ne, Te) often determining process outcomes. Consequently, a thorough understanding of the evolution of Tg and its correlation with discharge parameters has become a critical issue for optimizing semiconductor manufacturing processes. To achieve more accurate measurements of neutral gas temperature, this work employs three temperature measurement techniques: spectroscopy, Bragg grating, and fiber optic sensing. These methods are used to systematically investigate the variation patterns of neutral gas temperature (Tg) in nitrogen plasma and nitrogen-argon mixed plasma under different radio-frequency power, gas pressure, and gas composition conditions. To elucidate the gas heating mechanism, this work combines Langmuir probe measurements of electron density, electron temperature, electron energy probability distribution with a global model simulation. The results show that as the RF power increases, the energy coupled to the plasma increases, the ionization reaction is enhanced, and the collision process and energy transfer between electrons and neutral particles increase, resulting in a monotonically increasing trend of Tg. When gas pressure initially increases, both electron density and background gas density rise together, enhancing heating efficiency and driving rapid Tg growth. However, beyond 3 Pa, electron mean free path shortens and electron density declines. In contrast, background gas density continues to increase, leading to slower Tg growth. In nitrogen/argon mixed system discharges, increasing the argon proportion significantly enhances the rate of Tg increase. This occurs because a higher argon ratio elevates the proportion of high-energy electrons and electron density, thereby strengthening ionization and neutral gas heating. At the same time, argon metastable atoms enhance the density of excited nitrogen particles through the Penning process, which promotes nitrogen molecular excitation to higher energy levels and further heats the gas. Additionally, we observe that the radial temperature distribution in pure nitrogen plasma shifts from parabolic to saddle-type with axial height increasing, due to intensified electron collision excitation near the coil under electromagnetic field effects. In this study, it is also found that the glass transition temperature at the radial edge remains virtually unchanged as atmospheric pressure increases. This is because, as pressure continues to rise, electrons beneath the coil struggle to migrate to the radial edge to collide with neutral particles, thereby limiting the heating of edge neutral particles.
Research progress of robust magnetic resonance wireless power transfer based on topological physics
WU Xian, HUANG Youtao, LI Hui, YANG Yaping, CHEN Hong, GUO Zhiwei
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Magnetic resonance wireless power transfer (WPT) has gradually become a popular research topic of near-field regulation in recent years, with wide applications in the fields of mobile phones, implantable medical devices, electric vehicles, and many other fields. However, several challenges remain to be addressed: near-field coupling, which induces multiple frequency splits and prevents the system from maintaining a fixed operating frequency; coupled arrays, which are susceptible to structural errors and parameter perturbations; current research, which primarily focuses on single-load transmission and has resulted in undeveloped multi-load transmission systems; the direction of transmission, which is difficult to control flexibly. In recent years, photonic artificial microstructures have provided a flexible platform for studying topological physics, arousing significant research interest in their fundamental topological characteristics. The most prominent features of topological structures are their nonzero topological invariant and the robust edge states determined by the bulk-edge correspondence: these features can overcome disturbances caused by defects and disorders. Moreover, by modulating the wave function distribution of topological states, energy can be precisely localized, enabling directional WPT. Therefore, implementing topological modes in WPT systems are of significant scientific importance.This review summarizes recent researches on topological models for robust WPT, which are divided into three main parts. The first part introduces one-dimensional periodic topological structures, focusing primarily on the significant improvements in transmission efficiency and robustness achieved by utilizing topological edge states in the Su-Schrieffer-Heeger (SSH) model for WPT. Moreover, a composite chain formed by two SSH chains is constructed to realize a higher-order parity-time (PT) symmetric topological model. This approach solves the frequency splitting caused by coupled edge states and exhibits lower power losses in standby mode. The second part discusses several types of aperiodic one-dimensional topological chains. By introducing topological defect states at the interface between two different dimer chains, robust multi-load WPT is achieved. Furthermore, based on the integration of artificial intelligence algorithms, the SSH-like topological model enables more efficient and robust WPT than traditional SSH model. The asymmetric edge states in quasi-periodic Harper chain provide a solution for directional transmission in WPT applications. By introducing nonlinear circuits, this model enables active control of the transfer direction. The third part presents the application of high-order topological corner states in multi-load robust WPT, demonstrating the selective excitation of both symmetric and asymmetric corner modes.Finally, the application prospects of topological modes in WPT systems are discussed. With the development of new physics, the integration of non-Hermitian physics and topological physics holds great promise for achieving simultaneous energy-information transfer, and is expected to achieve compatible WPT, wireless communication, and wireless sensing within a single system. Such a fusion technology will provide breakthroughs in efficiency, robustness, and multifunctionality for next-generation wireless systems.
Ultrafast Scintillator Detector Based on Rare Earth Doped Perovskite Enables Sub nanosecond Temporal Resolution and gigahertz Rate Detection
LU Yanyu, CHEN Zhenhua, ZHANG Zengyan, GUO Zhi, ZOU Ying, LIU Haigang, YANG Fan, DING Dongzhou, WANG Yong, TAI Renzhong
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This work successfully developed a novel high-performance detector based on rare-earth-doped cesium lead chloride (CsPbCl3) inorganic scintillation crystals, targeting the critical demand for GHz-rate capabilities in ultrafast radiation detection at advanced light sources. The Ba2+-doped CsPbCl3 crystals, grown via the vertical Bridgman method, exhibit sub-nanosecond fluorescence rise times, with the pure crystal measuring ~209.6 ps and optimized doped crystals achieving ~50-75 ps. The crystals also feature nanosecond-scale decay times and enhanced light yield through defect engineering. By integrating this core scintillator with a microchannel plate photomultiplier tube (MCP-PMT) featuring sub-nanosecond transit time and a self-developed 2.5 GHz high-speed acquisition system, a complete ultrafast detection system was constructed. Rigorous testing using an optically generated equivalent GHz pulse train demonstrated that the system can clearly resolve consecutive fluorescence pulses with an average peak interval of only 0.79 ns, successfully achieving a high-repetition-rate detection capability of 1.26 GHz. Field application at the Shanghai Synchrotron Radiation Facility's soft X-ray free-electron laser (SXFEL) showed that its X-ray pulse response width is narrower than 4 ns, far superior to the >24 ns response of a reference LYSO:Ce crystal. These results validate the detector's exceptional sub-nanosecond time resolution and GHz-rate pulse discrimination, providing a reliable technical solution for ultrafast time-resolved diagnostics and photon beam loss monitoring in next-generation scientific facilities.
Stability of Σ5{310}[001]Grain Boundary in (HfNbTaTiZr)C High-Entropy Carbide and Its Implications for Mechanical Performance
Li Chuanying, Fu Tao, Peng Xianghe
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The characteristics of grain boundaries (GBs) and their mechanical responses under external loading are pivotal in governing the strength and plasticity of polycrystalline ceramics. In this study, first-principles calculations were employed to investigate the stability of Σ5 {310}[001] GBs in (HfNbTaTiZr)C high-entropy carbide ceramic (HECCs) and its constituent binary transition-metal carbides (TMCs), as well as their mechanical behavior under shear and tensile deformation. The results showed that the Σ5{310}[001] GBs in all systems were classified into "Open GB" and "Compact GB" based on their morphologies, with the Open GB exhibiting lower GB formation energy and thus greater structural stability. Under shear deformation, all carbides display shear-coupled GB migration, except for the Open GBs in group IVB TMCs, where the formation of C-C bonds induces supercell failure through the rupture of TM-C bonds. Furthermore, the initial migration stress of Open GB in the HECC is higher than that in binary TMCs, highlighting the strengthening effect introduced by multicomponent GBs. Under tensile deformation, binary TMCs containing Compact GB primarily fail through graphitization, whereas the HECC exhibits both graphitization and intergranular fracture. For Open GB, group IVB TMCs yield due to increased excess volume of GB, while group VB TMCs undergo intergranular fracture; both failure mechanisms coexist in the HECC. Notably, the HECC containing Compact GBs exhibits yield strength comparable to the peak strength of binary TMCs, surpassing the "weakest-link" limit typically associated with ideal condition (0 K and defect-free). Overall, this work elucidates the synergistic roles of GB and multicomponent effects in governing mechanical responses in HECC, suggesting that the interplay between multicomponent effects and defects may underlie the exceptional mechanical performance of high-entropy materials. These findings provide theoretical guidance for GB engineering and mechanical optimization in HECCs, and they offer insights into exploring their mechanical behavior under complex defect interactions.
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