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摘要: 本文根据空穴扩散促使有序化的观点导出决定恒温有序化几率的一个公式。这个公式中包括扩散系数,柯诺库夫温度及其他实验都可以直接测定的数量。引用了现有的这些数量的实验数据,证明所提出的有序化几率公式和实验结果是符合的。
Abstract: It is shown that the probability of an disordered atom to be ordered in unit time can be correlated to the coefficient of diffusion by the relation a=9/4 d/a2 (m2/m1)1/2 (△S2-△S1)/k(Tc/T-1) where a=the probability of ordering, D=the coefficient of diffusion, a =the lattice constant of AuCu3,m1 and m2 the mass of an atom of gold and copper respectively,△S1, △S2 being respectively the entropy change when a gold and a copper atom jumps to a neighboring vacancy, k, the Boltzmann constant, Tc, T, the critical temperature and the absolute temperature under consideration.This relation has been verified with experimental data. With experimental value of a and D0, it gives an activation energy of 2.10 eV which is equal to the activation energy of self-diffusion of copper within the limits of experimental accuracy. This expression explains the existance of a temperature at which the rate of ordering is maximum both qualitatively and quantitatively.