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摘要: 基于单占据aiσ表象和电荷涨落机制,应用简并微扰理论推导了非含cu氧化物Ba1-x·KxBiO3的双带Hubbard模型有效哈密顿量.考虑到坐标空间两个相反自旋空穴的次近邻格位配对,得到了格林函数运动方程和超导方程.合理解释了超交换作用和跳跃能对次近邻配对的作用,并且超导窗是由于坐标空间Cooper配对的结果.
Abstract: Based on the singly occupied a-picture and the mechanism of charge fluctuation, the effective Hamiltonian of two-band Hubbard model is derived by using the degeneracy perturbation theory for the non-cuprate comoound Ba1-xKxBiO3. By considering the next neighbour pairing of two opposite spin holes in coordinate space, the Green's function equation of motion and superconductivity equation are obtained. Furthermore, how the superexchange interaction and the hopping energy affect the next neighbour pairing has been explained reasonably, and the superconductivity window is due to the Cooper pairing in coordinate space.