内应力对Mn2NiGa铁磁形状记忆合金的结构、相变和磁性能的影响

宋瑞宁; 朱伟; 刘恩克; 李贵江; 陈京兰; 王文洪; 李祥; 吴光恒

doi:10.7498/aps.61.027501

摘要

通过施加压应力的方法,在铁磁形状记忆合金Mn2NiGa中引入残留内应力,研究了内应力对Mn2NiGa材料的结构、相变和磁性能的影响.研究发现,加压过程使材料发生了塑性形变,在材料内部引入了大量的位错缺陷.卸载后保留的位错缺陷在材料中造成了残留的内应力,导致了马氏体相变温度大幅度提高, 使原本室温下的母相转变成了马氏体相.测量到导致样品转变成马氏体的阈值压应力为1.0 GPa.加压形成的马氏体中的残留内应力将矫顽力从低于50 Oe提高到350 Oe.残留内应力在730 K的热处理中由于位错缺陷的消失而得以消除,样品实现了马氏体逆相变.如此高的逆相变温度使得 Mn2NiGa马氏体的居里温度测量成为可能,获得了530K的数值.

关键词:

Abstract

The structures, the martensitic transformations and the magnetic properties of ferromagnetic shape memory alloy Mn2NiGa with the loading and the unloading of the external compressive stress are investigated. The plastic deformation occurring during the stressing causes a high level of dislocation defects existing in the sample. The residual internal stress results in a significant increase of the reversed transformation temperature. The threshold value of compressive pressure for causing the completely martensitic transformation at room temperature is identified to be 1.0 GPa based on the experimental measurements of XRD and magnetic coercivity. The coercivity of the martensitic phase increases from 50 Oe to 350 Oe due to the application of the external stress up to 2.0 GPa. It is also observed that the reversed martensitic transformation occurrs, when the sample is treated by heating up to about 730 K. This is attributed to the elimination of the dislocation by the annealing effect. Such a high reverse martensitic transformation temperature allows the measurement of the Curie temperature of martensitic phase and the obtained value is 530 K.

Keywords:

作者及机构信息

1.
中国科学院物理研究所磁学国家重点实验室, 北京 100190;

2.
北京理工大学材料科学与工程学院, 北京 100081

基金项目: 国家自然科学基金(批准号:50971055)和国家重点基础研究发展计划(2010CB833102)资助的课题.

Authors and contacts

1.
State Key Laboratory for Magnetism, Institute of Physics, Chinese Academy of Sciences, Bejing 100190, China;

2.
School of Material Sciences & Engineering, Beijing Institute of Technology, Beijng 100081, China

Funds: Project supported by the National Natural Science Foundation of China (Grant No.50971055) and the National Basic Research Program of China (973 Program, 2010CB833102).

参考文献

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[2]	Murray S J, Marioni M, Allen S M, O’Handley R C, Lograsso T A 2000 Appl. Phys. Lett. 77 886
[3]	O’Handley R C, Murray S J, Marioni M, Nembach H, Allen S M 2000 J. Appl. Phys. 87 4712
[4]	Meng F B, Guo H J, Liu G D, Liu H Y, Dai X F, Luo H Z, Li Y X, Chen J L, Wu G H 2009 Chin. Phys. B 18 3031
[5]	Xu G L, Chen J D, Chen D, Ma J Z, Yu B H, Shi D H 2009 Chin. Phys. B 18 744
[6]	Murray S J, Farinelli M, Kantner C, Huang J K, Allen S M, O’Handley R C 1998 J. Appl. Phys. 83 7297
[7]	Chernenko V A, L’Vov V, Pons J, Cesari E 2003 J. Appl. Phys. 93 2394
[8]	Mullner P, Chernenko V A, Kostorz G 2003 Scripta Mater. 49 129
[9]	Sutou Y, Kamiya N, Omori T, Kainuma R, Ishida K, Oikawa K 2004 Appl. Phys. Lett. 84 1275
[10]	Manosa L, Moya X, Planes A, Gutfleisch O, Lyubina J, Barrio M, Tamarit J L, Aksoy S, Krenke T, Acet M 2008 Appl. Phys. Lett. 92 012515
[11]	Ma L, Zhu Z Y, Yu S D, Cui Q L, Zhou Q, Chen J L, Wu G H 2009 Acta Phys. Sin. 58 3479(in Chinese) [马丽,朱志永,李敏,于世丹,崔启良,周强,陈京兰,吴光恒 2009 物理学报 58 3497]
[12]	Liu G D, Chen J L, Liu Z H, Dai X F, Wu G H, Zhang B, Zhang X X 2005 Appl. Phys. Lett. 87 262504
[13]	Song R N, Li X, Zhu W, Liu E K, Li G J, Cai J F, Wang W H, Wu G H 2011 Acta Phys. Sin. 60 077501 (in Chinese) [宋瑞宁,李祥,朱伟,刘恩克,李贵江,蔡金芳,王文洪,吴光恒 2011 物理学报 60 077501]
[14]	Cui Z Q, Tan Y C 2007 Metallography & Heat Treatment (Beijing: Engineering Industry Publishing House) p194 (in Chinese) [崔忠圻,谭耀春 2006 金属学与热处理 (北京:机械工业出版社) 第194页]

施引文献

[1]	Ullakko K, Huang J K, Kantner C, Ohandley R C, Kokorin V V 1996 Appl. Phys. Lett. 69 1966
[2]	Murray S J, Marioni M, Allen S M, O’Handley R C, Lograsso T A 2000 Appl. Phys. Lett. 77 886
[3]	O’Handley R C, Murray S J, Marioni M, Nembach H, Allen S M 2000 J. Appl. Phys. 87 4712
[4]	Meng F B, Guo H J, Liu G D, Liu H Y, Dai X F, Luo H Z, Li Y X, Chen J L, Wu G H 2009 Chin. Phys. B 18 3031
[5]	Xu G L, Chen J D, Chen D, Ma J Z, Yu B H, Shi D H 2009 Chin. Phys. B 18 744
[6]	Murray S J, Farinelli M, Kantner C, Huang J K, Allen S M, O’Handley R C 1998 J. Appl. Phys. 83 7297
[7]	Chernenko V A, L’Vov V, Pons J, Cesari E 2003 J. Appl. Phys. 93 2394
[8]	Mullner P, Chernenko V A, Kostorz G 2003 Scripta Mater. 49 129
[9]	Sutou Y, Kamiya N, Omori T, Kainuma R, Ishida K, Oikawa K 2004 Appl. Phys. Lett. 84 1275
[10]	Manosa L, Moya X, Planes A, Gutfleisch O, Lyubina J, Barrio M, Tamarit J L, Aksoy S, Krenke T, Acet M 2008 Appl. Phys. Lett. 92 012515
[11]	Ma L, Zhu Z Y, Yu S D, Cui Q L, Zhou Q, Chen J L, Wu G H 2009 Acta Phys. Sin. 58 3479(in Chinese) [马丽,朱志永,李敏,于世丹,崔启良,周强,陈京兰,吴光恒 2009 物理学报 58 3497]
[12]	Liu G D, Chen J L, Liu Z H, Dai X F, Wu G H, Zhang B, Zhang X X 2005 Appl. Phys. Lett. 87 262504
[13]	Song R N, Li X, Zhu W, Liu E K, Li G J, Cai J F, Wang W H, Wu G H 2011 Acta Phys. Sin. 60 077501 (in Chinese) [宋瑞宁,李祥,朱伟,刘恩克,李贵江,蔡金芳,王文洪,吴光恒 2011 物理学报 60 077501]
[14]	Cui Z Q, Tan Y C 2007 Metallography & Heat Treatment (Beijing: Engineering Industry Publishing House) p194 (in Chinese) [崔忠圻,谭耀春 2006 金属学与热处理 (北京:机械工业出版社) 第194页]

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