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在光敏性三元聚合物混合物中构造 多尺度有序图案

郭宇琦 潘俊星 张进军 孙敏娜 王宝凤 武海顺

在光敏性三元聚合物混合物中构造 多尺度有序图案

郭宇琦, 潘俊星, 张进军, 孙敏娜, 王宝凤, 武海顺
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导出引用
  • 由多组分聚合物混合物所形成的多尺度有序结构能够展现出许多新奇的物理化学性质, 从而使其在材料工程领域具有十分重要的潜 在应用价值. 本文通过计算机模拟, 在光敏性不相容三元混合物体系中创建了多尺度有序结构. 通过调节光照区域和掩膜形状, 获得了棋盘形、箭靶状等十分独特的形貌, 并且这些结构可以在实验上通过在适当的时间淬火而稳定较长的时间. 详细探讨了组分比、掩膜宽度、间距以及光照强度对体系的影响, 从而为实现多尺度长程序花样薄膜的制备提供了一个简便的途径, 同时也为纳米器件的制备提供了一定的指导.
      通信作者: 潘俊星, panjunxing2007@163.com;zhangjinjun@sxnu.edu.cn ; 张进军, panjunxing2007@163.com;zhangjinjun@sxnu.edu.cn
    • 基金项目: 国家自然科学基金(批准号: 21373131)、教育部高等学校博士点专项基金(批准号: 20121404110004)、山西省自然科学基金(批准号: 2015011004)、山西省人社厅优秀人才专项基金和山西省高校科技创新项目资助的课题.
    [1]

    Sun M N, Zhang J J, Wang B F, Wu H S, Pan J X 2011 Phys. Rev. E 84 011812

    [2]

    Jang S G, Khan A, Dimitriou M D, Kim B J, Lynd N A, Kramer E J, Hawker C J 2011 Soft Matter 7 6255

    [3]

    Parnell A J, Pryke A, Mykhaylyk O O, Howse J R, Adawi A M, Terrill N J, Fairclough J P A 2011 Soft Matter 7 3721

    [4]

    Hong S W, Gu X D, Huh J, Xiao S G, Russell T P 2011 ACS Nano 5 2855

    [5]

    Bates F S, Maurer W, Lodge T P, Schulz MF, Matsen M W, Almdal K, Mortensen K 1995 Phys. Rev. Lett. 75 4429

    [6]

    Zhang J J, Jin G J, Ma Y Q 2006 J. Phys.: Condens. Matter 18 837

    [7]

    Ruokolainen J, Mäkinen R, Torkkeli M, Mäkelä T, Serimaa R, ten Brinke G, Ikkala O 1998 Science 280 557

    [8]

    Ruokolainen J, Saariaho M, Ikkala O 1999 Macromolecules 32 1152

    [9]

    Travasso R D M, Kuksenok O, Balazs A C 2005 Langmuir 21 10912

    [10]

    Kuksenok O, Travasso R D M, Balazs A C 2006 Phys. Rev. E 74 011502

    [11]

    Travasso R D M, Kuksenok O, Balazs A C 2006 Langmuir 22 2620

    [12]

    Puri S, Kumar D 2004 Phys. Rev. E 70 051501

    [13]

    Lakshmi K C, Kumar P B S 2003 Phys. Rev. E 67 011507

    [14]

    Tafa K, Puri S, Kumar D 2001 Phys. Rev. E 64 056139

    [15]

    Ma Y Q 2001 J. Chem. Phys. 114 3734

    [16]

    Huang C, de la Cruz M O, Swift B W 1996 Macromolecules 28 7996

    [17]

    Zhang L C, Sun M N, Pan J X, Wang B F, Zhang J J, Wu H S 2013 Chin. Phys. B 22 096401

    [18]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. B 22 026401

    [19]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. Lett. 30 046401

    [20]

    Pinna M, Hiltl S, Guo X H, Böker A, Zvelindovsky A V 2010 ACS Nano 4 2845

    [21]

    Chen H Y, Peng C J, Sun L, Liu H L, Hu Y 2007 Langmuir 23 11112

    [22]

    Chen H Y, Chen X Q, Ye Z C, Liu H L, Hu Y 2010 Langmuir 26 6663

    [23]

    Hao Q H, Miao B, Song Q G, Niu X H, Liu T J 2014 Polymer 55 4281

    [24]

    Xu Y C, Li W H, Qiu F, Lin Z Q 2014 Nanoscale 6 6844

    [25]

    Li M, Zhu Y J 2008 Acta Phys. Sin. 57 7555 (in Chinese) [李明, 诸跃进 2008 物理学报 57 7555]

    [26]

    Tong H P, Zhang L X 2012 Acta Phys. Sin. 61 058701 (in Chinese) [仝焕平, 章林溪 2012 物理学报 61 058701]

    [27]

    Zhang J J, Jin G J, Ma Y Q 2005 Phys. Rev. E 71 051803

    [28]

    Pinna M, Zvelindovsky A V 2008 Soft Matter 4 316

    [29]

    Xu T, Craig J H, Russell T P 2003 Macromolecules 36 6178

    [30]

    Böker A, Schmidt K, Knoll A, Zettl H, Hansel H, Urban V, Abetz V, Krausch G 2006 Polymer 47 849

    [31]

    Schmidt K, Böker A, Zettl H, Schubert F, Hänsel H, Fischer F, Weiss T M, Abetz V, Zvelindovsky A V, Sevink G J A, Krausch G 2005 Langmuir 21 11974

    [32]

    Hong Y R, Admson D H, Chainkin P M, Register R A 2009 Soft Matter 5 1687

    [33]

    Chen K, Ma Y Q 2002 J. Chem. Phys. 116 7783

    [34]

    Morozov A N, Zvelindovsky A V, Fraaije J G E M 2001 Phys. Rev. E 64 051803

    [35]

    Morozov A N, Fraaije J G E M 2002 Phys. Rev. E 65 031803

    [36]

    You L Y, Chen L J, Qian H J, Lu Z Y 2007 Macromolecules 40 5222

    [37]

    Pan Z Q, He L L, Zhang L X, Liang H J 2011 Polymer 52 2711

    [38]

    Nikoubashman A, Davis R L, Michal B T, Chaikin P M, Register R A, Panagiotopoulos A Z 2014 ACS Nano 8 8015

    [39]

    Nikoubashman A, Register R A, Panagiotopoulos A Z 2013 Soft Matter 9 9960

    [40]

    Guo Y Q, Zhang J J, Wang B F, Wu H S, Sun M N, Pan J X 2015 Condens. Matter Phys. 18 23801

    [41]

    Peng G W, Qiu F, Ginzburg V V, Jasnow D, Balazs A C 2000 Science 288 1802

    [42]

    Deng Z Y, Zhang L X 2015 Acta Phys. Sin. 64 0168201 (in Chinese) [邓真渝, 章林溪 2015 物理学报 64 0168201]

    [43]

    Chen K, Ma Y Q 2002 Phys. Rev. E 65 041501

    [44]

    Zhu Y J, Ma Y Q 2003 Chin. Phys. Lett. 20 703

    [45]

    Zhang J J, Jin G J, Ma Y Q 2005 Eur. Phys. J. E 18 359

    [46]

    Liu Y, Kuksenok O, Balazs A C 2013 Langmuir 29 750

    [47]

    Dayal P, Kuksenok O, Balazs A C 2008 Langmuir 24 1621

    [48]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. Lett. 30 076401

    [49]

    Grzybowski B A, Campbell C J 2007 Mater. Today 10 38

    [50]

    Glotzer S C, Stauffer D, Jan N 1994 Phys. Rev. Lett. 72 4109

    [51]

    Qiu T C, Kawai J J, Endoh K 1999 Chaos 9 298

    [52]

    Colvin V L, Larson R G, Harris A L, Schilling M L 1997 J. Appl. Phys. 81 5913

    [53]

    Kellogg G J, Walton D G, Mayes A M 1996 Phys. Rev. Lett. 76 2503

    [54]

    Christensen J J, Elder K, Fogedby H C 1996 Phys. Rev. E 54 R2212

    [55]

    Glotzer S C, Marzio E A Di, Muthukumar M 1995 Phys. Rev. Lett. 74 2034

    [56]

    Purit S, Frisch H L 1994 J. Phys. A: Math. Gen. 27 6027

    [57]

    Tran C Q, Kawai J J, Nishikawa Y, Jinnai H 1999 Phys. Rev. E 60 R1150

    [58]

    Nishioka H, Kida K, Yano O, Tran C Q 2000 Macromolecules 33 4301

    [59]

    Liu B, Tong C H, Yang Y L 2001 J. Phys. Chem.B 105 10091

    [60]

    Tong C H, Yang Y L 2002 J. Chem. Phys. 116 1519

    [61]

    Tong C H, Zhang H D, Yang Y L 2002 J. Phys. Chem. B 106 7869

    [62]

    Zhu Y J, Ma Y Q 2003 Phys. Rev. E 67 021804

    [63]

    Okuzono T, Ohta T 2003 Phys. Rev. E 67 056211

    [64]

    Good K, Kuksenok O, Buxton G A, Ginzburg V V, Balazs A C 2004 J. Chem. Phys. 121 6052

    [65]

    Nakanishi H, Satoh M, Norisuye T, Tran C Q 2004 Macromolecules 37 8495

    [66]

    Oono Y, Puri S 1987 Phys. Rev. Lett. 58 836

    [67]

    Puri S, Oono Y 1988 Phys. Rev. A 38 1542

    [68]

    Oono Y, Puri S 1988 Phys. Rev. A 38 434

    [69]

    Travasso R D M, Buxton G A, Kuksenok O, Good K, Balazs A C 2005 J. Chem. Phys. 122 194906 ten Brinke G, Ikkala O 1998 Science 280 557

  • [1]

    Sun M N, Zhang J J, Wang B F, Wu H S, Pan J X 2011 Phys. Rev. E 84 011812

    [2]

    Jang S G, Khan A, Dimitriou M D, Kim B J, Lynd N A, Kramer E J, Hawker C J 2011 Soft Matter 7 6255

    [3]

    Parnell A J, Pryke A, Mykhaylyk O O, Howse J R, Adawi A M, Terrill N J, Fairclough J P A 2011 Soft Matter 7 3721

    [4]

    Hong S W, Gu X D, Huh J, Xiao S G, Russell T P 2011 ACS Nano 5 2855

    [5]

    Bates F S, Maurer W, Lodge T P, Schulz MF, Matsen M W, Almdal K, Mortensen K 1995 Phys. Rev. Lett. 75 4429

    [6]

    Zhang J J, Jin G J, Ma Y Q 2006 J. Phys.: Condens. Matter 18 837

    [7]

    Ruokolainen J, Mäkinen R, Torkkeli M, Mäkelä T, Serimaa R, ten Brinke G, Ikkala O 1998 Science 280 557

    [8]

    Ruokolainen J, Saariaho M, Ikkala O 1999 Macromolecules 32 1152

    [9]

    Travasso R D M, Kuksenok O, Balazs A C 2005 Langmuir 21 10912

    [10]

    Kuksenok O, Travasso R D M, Balazs A C 2006 Phys. Rev. E 74 011502

    [11]

    Travasso R D M, Kuksenok O, Balazs A C 2006 Langmuir 22 2620

    [12]

    Puri S, Kumar D 2004 Phys. Rev. E 70 051501

    [13]

    Lakshmi K C, Kumar P B S 2003 Phys. Rev. E 67 011507

    [14]

    Tafa K, Puri S, Kumar D 2001 Phys. Rev. E 64 056139

    [15]

    Ma Y Q 2001 J. Chem. Phys. 114 3734

    [16]

    Huang C, de la Cruz M O, Swift B W 1996 Macromolecules 28 7996

    [17]

    Zhang L C, Sun M N, Pan J X, Wang B F, Zhang J J, Wu H S 2013 Chin. Phys. B 22 096401

    [18]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. B 22 026401

    [19]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. Lett. 30 046401

    [20]

    Pinna M, Hiltl S, Guo X H, Böker A, Zvelindovsky A V 2010 ACS Nano 4 2845

    [21]

    Chen H Y, Peng C J, Sun L, Liu H L, Hu Y 2007 Langmuir 23 11112

    [22]

    Chen H Y, Chen X Q, Ye Z C, Liu H L, Hu Y 2010 Langmuir 26 6663

    [23]

    Hao Q H, Miao B, Song Q G, Niu X H, Liu T J 2014 Polymer 55 4281

    [24]

    Xu Y C, Li W H, Qiu F, Lin Z Q 2014 Nanoscale 6 6844

    [25]

    Li M, Zhu Y J 2008 Acta Phys. Sin. 57 7555 (in Chinese) [李明, 诸跃进 2008 物理学报 57 7555]

    [26]

    Tong H P, Zhang L X 2012 Acta Phys. Sin. 61 058701 (in Chinese) [仝焕平, 章林溪 2012 物理学报 61 058701]

    [27]

    Zhang J J, Jin G J, Ma Y Q 2005 Phys. Rev. E 71 051803

    [28]

    Pinna M, Zvelindovsky A V 2008 Soft Matter 4 316

    [29]

    Xu T, Craig J H, Russell T P 2003 Macromolecules 36 6178

    [30]

    Böker A, Schmidt K, Knoll A, Zettl H, Hansel H, Urban V, Abetz V, Krausch G 2006 Polymer 47 849

    [31]

    Schmidt K, Böker A, Zettl H, Schubert F, Hänsel H, Fischer F, Weiss T M, Abetz V, Zvelindovsky A V, Sevink G J A, Krausch G 2005 Langmuir 21 11974

    [32]

    Hong Y R, Admson D H, Chainkin P M, Register R A 2009 Soft Matter 5 1687

    [33]

    Chen K, Ma Y Q 2002 J. Chem. Phys. 116 7783

    [34]

    Morozov A N, Zvelindovsky A V, Fraaije J G E M 2001 Phys. Rev. E 64 051803

    [35]

    Morozov A N, Fraaije J G E M 2002 Phys. Rev. E 65 031803

    [36]

    You L Y, Chen L J, Qian H J, Lu Z Y 2007 Macromolecules 40 5222

    [37]

    Pan Z Q, He L L, Zhang L X, Liang H J 2011 Polymer 52 2711

    [38]

    Nikoubashman A, Davis R L, Michal B T, Chaikin P M, Register R A, Panagiotopoulos A Z 2014 ACS Nano 8 8015

    [39]

    Nikoubashman A, Register R A, Panagiotopoulos A Z 2013 Soft Matter 9 9960

    [40]

    Guo Y Q, Zhang J J, Wang B F, Wu H S, Sun M N, Pan J X 2015 Condens. Matter Phys. 18 23801

    [41]

    Peng G W, Qiu F, Ginzburg V V, Jasnow D, Balazs A C 2000 Science 288 1802

    [42]

    Deng Z Y, Zhang L X 2015 Acta Phys. Sin. 64 0168201 (in Chinese) [邓真渝, 章林溪 2015 物理学报 64 0168201]

    [43]

    Chen K, Ma Y Q 2002 Phys. Rev. E 65 041501

    [44]

    Zhu Y J, Ma Y Q 2003 Chin. Phys. Lett. 20 703

    [45]

    Zhang J J, Jin G J, Ma Y Q 2005 Eur. Phys. J. E 18 359

    [46]

    Liu Y, Kuksenok O, Balazs A C 2013 Langmuir 29 750

    [47]

    Dayal P, Kuksenok O, Balazs A C 2008 Langmuir 24 1621

    [48]

    Pan J X, Zhang J J, Wang B F, Wu H S, Sun M N 2013 Chin. Phys. Lett. 30 076401

    [49]

    Grzybowski B A, Campbell C J 2007 Mater. Today 10 38

    [50]

    Glotzer S C, Stauffer D, Jan N 1994 Phys. Rev. Lett. 72 4109

    [51]

    Qiu T C, Kawai J J, Endoh K 1999 Chaos 9 298

    [52]

    Colvin V L, Larson R G, Harris A L, Schilling M L 1997 J. Appl. Phys. 81 5913

    [53]

    Kellogg G J, Walton D G, Mayes A M 1996 Phys. Rev. Lett. 76 2503

    [54]

    Christensen J J, Elder K, Fogedby H C 1996 Phys. Rev. E 54 R2212

    [55]

    Glotzer S C, Marzio E A Di, Muthukumar M 1995 Phys. Rev. Lett. 74 2034

    [56]

    Purit S, Frisch H L 1994 J. Phys. A: Math. Gen. 27 6027

    [57]

    Tran C Q, Kawai J J, Nishikawa Y, Jinnai H 1999 Phys. Rev. E 60 R1150

    [58]

    Nishioka H, Kida K, Yano O, Tran C Q 2000 Macromolecules 33 4301

    [59]

    Liu B, Tong C H, Yang Y L 2001 J. Phys. Chem.B 105 10091

    [60]

    Tong C H, Yang Y L 2002 J. Chem. Phys. 116 1519

    [61]

    Tong C H, Zhang H D, Yang Y L 2002 J. Phys. Chem. B 106 7869

    [62]

    Zhu Y J, Ma Y Q 2003 Phys. Rev. E 67 021804

    [63]

    Okuzono T, Ohta T 2003 Phys. Rev. E 67 056211

    [64]

    Good K, Kuksenok O, Buxton G A, Ginzburg V V, Balazs A C 2004 J. Chem. Phys. 121 6052

    [65]

    Nakanishi H, Satoh M, Norisuye T, Tran C Q 2004 Macromolecules 37 8495

    [66]

    Oono Y, Puri S 1987 Phys. Rev. Lett. 58 836

    [67]

    Puri S, Oono Y 1988 Phys. Rev. A 38 1542

    [68]

    Oono Y, Puri S 1988 Phys. Rev. A 38 434

    [69]

    Travasso R D M, Buxton G A, Kuksenok O, Good K, Balazs A C 2005 J. Chem. Phys. 122 194906 ten Brinke G, Ikkala O 1998 Science 280 557

  • 引用本文:
    Citation:
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出版历程
  • 收稿日期:  2015-09-28
  • 修回日期:  2015-12-21
  • 刊出日期:  2016-03-05

在光敏性三元聚合物混合物中构造 多尺度有序图案

    基金项目: 

    国家自然科学基金(批准号: 21373131)、教育部高等学校博士点专项基金(批准号: 20121404110004)、山西省自然科学基金(批准号: 2015011004)、山西省人社厅优秀人才专项基金和山西省高校科技创新项目资助的课题.

摘要: 由多组分聚合物混合物所形成的多尺度有序结构能够展现出许多新奇的物理化学性质, 从而使其在材料工程领域具有十分重要的潜 在应用价值. 本文通过计算机模拟, 在光敏性不相容三元混合物体系中创建了多尺度有序结构. 通过调节光照区域和掩膜形状, 获得了棋盘形、箭靶状等十分独特的形貌, 并且这些结构可以在实验上通过在适当的时间淬火而稳定较长的时间. 详细探讨了组分比、掩膜宽度、间距以及光照强度对体系的影响, 从而为实现多尺度长程序花样薄膜的制备提供了一个简便的途径, 同时也为纳米器件的制备提供了一定的指导.

English Abstract

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