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The vibration spectra of complicated molecule are generally divided into group frequency and ridge frequency. The ridge frequency has a certain symmetry in the vibration spectra of some complicated molecules, such as the ridge frequency of malachite green isothiocyanate (MGITC) molecule which is a molecular probe and has a U(5) symmetry. In this article the U(5) symmetry of molecular vibration spectrum is introduced and tested for its fitting to the low excitation spectrum of MGITC, we find that the theoretical value conforms to the experimental results.
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Keywords:
- the molecule vibration spectra /
- U(5) model /
- ridge frequency
[1] Zhao L, Fu J L, Chen B Y 2011 Chin. Phys. B 20 040201
[2] [3] He Y F, Liu Y S, Fu J L 2011 Chin. Phys. B 20 010202
[4] [5] Hou Q B, Li Y C, Wang J, Xia L L 2007 Chin. Phys. 16 1521
[6] Chen X W, Liu C M, Li Y M 2006 Chin. Phys. 15 470
[7] [8] [9] Gao Y J 2006 Chin. Phys. 15 66
[10] Hu C W, Yu L M, Xu Y, Zhu A R 1992 Acta Phys. Sin. 41 1119 (in Chinese) [胡长武, 俞立民, 徐颖, 朱昂如1992 物理学报41 1119]
[11] [12] [13] Qian X, Emory S R, Nie S 2012 J. Am. Chem. Soc. 134 2000
[14] Cecchini M P, Stapountzi M A, McComb D W, Albrecht T, Edel J B 2011 Anal. Chem. 83 1418
[15] [16] [17] Lang W, Vikesland P J 2013 Anal. Chem. 85 1342
[18] Xu C W, Zhu F, Liu L N, Niu D P 2013 Acta Phys. Sin. 62 164102 (in Chinese) [徐长伟, 朱峰, 刘丽娜, 牛大鹏2013 物理学报62 164102]
[19] [20] [21] Yao R X, Lou S Y 2008 Chin. Phys. Lett. 25 1927
[22] [23] Wang L Z, Gou M, Qu C Z 2007 Chin. Phys. Lett. 24 3293
[24] [25] Yang B J, Yang L H 2013 Group Theory and Its Application to Information (Beijing: Chemical Industry Press) p92 (in Chinese) [杨伯君, 杨丽华2013 群论及其在信息领域中的应用(北京: 化学工业出版社) 第92页]
[26] [27] Yang B J 1986 High Energy Physics and Nuclear Physics 10 98
[28] Yang B J, Zhang X G, 1993 J. Phys. D 28 299
[29] [30] [31] Pettinger B, Ren B, Picardi G, Schuster R, Ertl G 2005 J. Raman Spectrosc. 36 541
[32] [33] Guo M R, Cai H X, Chen G, Fan Y, Zhang X H 2011 Spectroscopy and Spectral Analysis 31 1541 (in Chinese)[郭沫然, 蔡红星, 陈高, 范雅, 张喜和2011 光谱学与光谱分析31 1541]
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[1] Zhao L, Fu J L, Chen B Y 2011 Chin. Phys. B 20 040201
[2] [3] He Y F, Liu Y S, Fu J L 2011 Chin. Phys. B 20 010202
[4] [5] Hou Q B, Li Y C, Wang J, Xia L L 2007 Chin. Phys. 16 1521
[6] Chen X W, Liu C M, Li Y M 2006 Chin. Phys. 15 470
[7] [8] [9] Gao Y J 2006 Chin. Phys. 15 66
[10] Hu C W, Yu L M, Xu Y, Zhu A R 1992 Acta Phys. Sin. 41 1119 (in Chinese) [胡长武, 俞立民, 徐颖, 朱昂如1992 物理学报41 1119]
[11] [12] [13] Qian X, Emory S R, Nie S 2012 J. Am. Chem. Soc. 134 2000
[14] Cecchini M P, Stapountzi M A, McComb D W, Albrecht T, Edel J B 2011 Anal. Chem. 83 1418
[15] [16] [17] Lang W, Vikesland P J 2013 Anal. Chem. 85 1342
[18] Xu C W, Zhu F, Liu L N, Niu D P 2013 Acta Phys. Sin. 62 164102 (in Chinese) [徐长伟, 朱峰, 刘丽娜, 牛大鹏2013 物理学报62 164102]
[19] [20] [21] Yao R X, Lou S Y 2008 Chin. Phys. Lett. 25 1927
[22] [23] Wang L Z, Gou M, Qu C Z 2007 Chin. Phys. Lett. 24 3293
[24] [25] Yang B J, Yang L H 2013 Group Theory and Its Application to Information (Beijing: Chemical Industry Press) p92 (in Chinese) [杨伯君, 杨丽华2013 群论及其在信息领域中的应用(北京: 化学工业出版社) 第92页]
[26] [27] Yang B J 1986 High Energy Physics and Nuclear Physics 10 98
[28] Yang B J, Zhang X G, 1993 J. Phys. D 28 299
[29] [30] [31] Pettinger B, Ren B, Picardi G, Schuster R, Ertl G 2005 J. Raman Spectrosc. 36 541
[32] [33] Guo M R, Cai H X, Chen G, Fan Y, Zhang X H 2011 Spectroscopy and Spectral Analysis 31 1541 (in Chinese)[郭沫然, 蔡红星, 陈高, 范雅, 张喜和2011 光谱学与光谱分析31 1541]
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