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A major issue in organic photovoltaics (OPVs) is the poor mobility and recombination of the photogenerated charge carriers. The active layer has to be kept thin to facilitate charge transport and minimize recombination losses. However, optical losses due to inefficient light absorption in the thin active layers can be considerable in OPVs. Therefore, light trapping schemes are critically important for efficient OPVs. In this paper, high efficient OPVs are demonstrated by introducing randomly nanostructured front electrodes, which are fabricated using commercially available ZnO:Al (AZO) films by means of a wet etching method. The etched AZO front electrode induces strong diffusion and scattering of the incident light, leading to the efficient light trapping within the device and enhancement of light absorption in the active layer. Such a nanostructured electrode can achieve an improved device performance by maintaining simultaneously high open-circuit voltage and fill factor values, while providing excellent short-circuit current enhancement through efficient light trapping. The best device obtained based on the textured electrode shows a 11.29% improvement in short current density and a 8.17% improvement in power conversion efficiency, as compared with the device with a flat electrode. The improvement in PCE is directly correlated with the enhancement of light absorption in the active layer due to the light scattering and trapping effect induced by the randomly nanotextured electrodes, which is confirmed by a haze factor measurement and an external quantum efficiency characterization. The well-established contact interfaces between the etched electrodes and active layers are made, and thus reduce the impact on the open-circuit voltage and fill factor values in OPVs. We thus conclude that the method of light manipulation developed in this paper will provide a promising and practical approach to fabricate high-performance and low-cost OPVs.
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Keywords:
- organic photovoltaics /
- textured electrodes /
- ZnO:Al /
- wet etching
[1] Yang Y, Chen W, Dou L, Chang W H, Duan H S, Bob B, Li G, Yang Y 2015 Nat. Photonics 9 190
[2] He Z C, Xiao B, Liu F, Wu H B, Yang Y L, Xiao S, Wang C, Russell T P, Cao Y 2015 Nat. Photonics 9 174
[3] Lin Y Z, Wang J Y, Zhang Z G, Bai H T, Li Y F, Zhu D B, Zhan X W 2015 Adv. Mater. 27 1170
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[7] Sefunc M A, Okyay A K, Volkan D H 2011 Appl. Phys. Lett. 98 3117
[8] Shen H H, Maes B 2011 Opt. Express 19 A1202
[9] Abass A, Shen H H, Bienstman P 2011 J. Appl. Phys. 109 3111
[10] Ferry V E, Sweatlock L A, Pacifici D 2008 Nano Lett. 8 4391
[11] Ko D H, Tumbleston J R, Zhang L 2009 Nano Lett. 9 2742
[12] Chen J Y, Yu M H 2014 Appl. Mater. Interfaces 6 6164
[13] Lee J H, Kim D W, Jang H, Choi J K, Geng J X, Jung J W, Yoon S C, Jung H T 2009 Small 19 2139
[14] Chao Y C, Zhan F M, Li H D 2014 RSC Adv. 4 30881
[15] Chou C H, Chen F C 2014 Nanoscale 6 8444
[16] Yu X M, Zhao J, Hou G F, Zhang J J, Zhang X D, Zhao Y 2013 Acta Phys. Sin. 62 120101 (in Chinese) [于晓明赵静, 侯国付, 张建军, 张晓丹, 赵颖 2013 物理学报 62 120101]
[17] Hou G F, Xue J M, Yuan Y J, Zhang X D, Sun J, Chen X L, Geng X H, Zhao Y 2012 Acta Phys. Sin. 61 058403 (in Chinese) [侯国付, 薛俊明, 袁育杰, 张晓丹, 孙建, 陈新亮, 耿新华, 赵颖 2012 物理学报 61 058403]
[18] Wang Y, Zhang X, Bai L, Huang Q, Wei C, Zhao Y 2012 Appl. Phys. Lett. 100 263508
[19] Hu Z Y, Zhang J J, Zhao Y 2012 J. Appl. Phys. 111 104516
[20] Niggemann M, Glatthaar M, Gombert A, Hinsch A, Wittwer V 2004 Thin Solid Films 619 451
[21] Niggemann M, Glatthaar M, Lewer P, Muller C, Wagner J, Gombert A 2006 Thin Solid Films 628 511
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[1] Yang Y, Chen W, Dou L, Chang W H, Duan H S, Bob B, Li G, Yang Y 2015 Nat. Photonics 9 190
[2] He Z C, Xiao B, Liu F, Wu H B, Yang Y L, Xiao S, Wang C, Russell T P, Cao Y 2015 Nat. Photonics 9 174
[3] Lin Y Z, Wang J Y, Zhang Z G, Bai H T, Li Y F, Zhu D B, Zhan X W 2015 Adv. Mater. 27 1170
[4] Zilio S D, Tvingstedt K, Inganas O 2009 Microelectron. Eng. 86 1150
[5] Lindquist N C, Luhman W A, Oh S H 2008 Appl. Phys. Lett. 93 3308
[6] Atwater H A, Polman A 2010 Nat. Mater. 9 205
[7] Sefunc M A, Okyay A K, Volkan D H 2011 Appl. Phys. Lett. 98 3117
[8] Shen H H, Maes B 2011 Opt. Express 19 A1202
[9] Abass A, Shen H H, Bienstman P 2011 J. Appl. Phys. 109 3111
[10] Ferry V E, Sweatlock L A, Pacifici D 2008 Nano Lett. 8 4391
[11] Ko D H, Tumbleston J R, Zhang L 2009 Nano Lett. 9 2742
[12] Chen J Y, Yu M H 2014 Appl. Mater. Interfaces 6 6164
[13] Lee J H, Kim D W, Jang H, Choi J K, Geng J X, Jung J W, Yoon S C, Jung H T 2009 Small 19 2139
[14] Chao Y C, Zhan F M, Li H D 2014 RSC Adv. 4 30881
[15] Chou C H, Chen F C 2014 Nanoscale 6 8444
[16] Yu X M, Zhao J, Hou G F, Zhang J J, Zhang X D, Zhao Y 2013 Acta Phys. Sin. 62 120101 (in Chinese) [于晓明赵静, 侯国付, 张建军, 张晓丹, 赵颖 2013 物理学报 62 120101]
[17] Hou G F, Xue J M, Yuan Y J, Zhang X D, Sun J, Chen X L, Geng X H, Zhao Y 2012 Acta Phys. Sin. 61 058403 (in Chinese) [侯国付, 薛俊明, 袁育杰, 张晓丹, 孙建, 陈新亮, 耿新华, 赵颖 2012 物理学报 61 058403]
[18] Wang Y, Zhang X, Bai L, Huang Q, Wei C, Zhao Y 2012 Appl. Phys. Lett. 100 263508
[19] Hu Z Y, Zhang J J, Zhao Y 2012 J. Appl. Phys. 111 104516
[20] Niggemann M, Glatthaar M, Gombert A, Hinsch A, Wittwer V 2004 Thin Solid Films 619 451
[21] Niggemann M, Glatthaar M, Lewer P, Muller C, Wagner J, Gombert A 2006 Thin Solid Films 628 511
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