等离子体对石墨烯的功能化改性

赵雯琪; 张岱; 崔明慧; 杜颖; 张树宇; 区琼荣

doi:10.7498/aps.70.20202078

摘要

等离子体态物质富含高反应活性粒子群, 包括电子、离子、自由基、光子等, 是催化或直接参与化学反应的重要因子, 在化学合成与材料改性领域有重要应用价值, 往往可以使热平衡条件下难以发生, 甚至不能发生的化学反应, 在等离子体催化下得以发生和加速. 常规条件下的石墨烯就是低反应活性物质, 往往需要在高温甚至高压和强酸强碱条件下才能发生化学反应, 对于新型石墨烯衍生材料的合成与改性是一个束缚. 而等离子体催化石墨烯反应, 可以在常温常压无腐蚀性条件下, 引发石墨烯的还原、氧化、缺陷修复、掺杂、接枝、外延生长和交联等一系列化学反应, 为石墨烯功能化改性及其新型复合材料合成提供了更多可能性, 值得深入探索. 过去十多年, 等离子体在石墨烯合成与改性方面的研究报道并不鲜见, 特色鲜明, 然而, 较多的报道停留在技术路线的尝试以及结果呈现层面, 化学反应动力学研究鲜有涉及, 本文对这些研究报道进行综合论述, 主要是对部分代表性研究结果的再报告和总结性讨论, 旨在促进相关领域的深入研究.

关键词:

石墨烯 /
等离子体 /
表面改性 /
掺杂 /
催化

Abstract

Plasma contains highly reactive species, including electrons, ions, radicals, photons, etc., which are critical for catalyzing or directly participating in chemical reactions. Plasma is a highly efficient tool in chemical synthesis and material modification, since it can make the chemical reactions that are difficult or even impossible to occur under thermal equilibrium conditions take place and accelerate through its catalysis. The chemical reactivity of graphene under conventional conditions is low, which means that the reaction of graphene requires high temperature, high pressure and/or strong acid or alkali, thereby restricting the synthesis and modification of novel graphene-derived materials. Plasma-assisted graphene reaction can trigger a series of chemical reactions, such as reduction, oxidation, defect repair, doping, grafting, epitaxial growth and cross-linking of graphene, under ambient temperature and pressure without any corrosive conditions. It provides great potentials for the functional modification of graphene and the synthesis of graphene composites, which deserve further exploration. Over the past decade, a number of studies of graphene synthesis and modification by using plasma with distinctive characteristics have been reported. However, most of reports focused on the presentation of technical routes and corresponding results, and the research on chemical reaction kinetics is still far from being fully addressed. In this review, we make a comprehensive discussion about these reports by mainly summarizing and discussing some of the representative results, in order to promote further research in the relevant fields.

Keywords:

作者及机构信息

复旦大学电光源研究所, 工程与应用技术研究院超越照明研究所, 上海　200433

通信作者: 张树宇, zhangshuyu@fudan.edu.cn ; 区琼荣, qrou@fudan.edu.cn

基金项目: 国家自然科学基金 (批准号: 51677031, 11975081)资助的课题

Authors and contacts

Institute of Future Lighting, Academy for Engineering and Technology, Institute for Electric Light Sources, Fudan University, Shanghai 200433, China

Corresponding author: Zhang Shu-Yu, zhangshuyu@fudan.edu.cn ; Ou Qiong-Rong, qrou@fudan.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51677031, 11975081)

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参考文献

[1]	Novoselov K S, Fal'ko V I, Colombo L, Gellert P R, Schwab M G, Kim K 2012 Nature 490 192 Google Scholar
[2]	Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S 2009 Science 324 1312 Google Scholar
[3]	Bae S, Kim H, Lee Y, Xu X, Park J S, Zheng Y, Balakrishnan J, Lei T, Ri Kim H, Song Y I, Kim Y J, Kim K S, Özyilmaz B, Ahn J H, Hong B H, Iijima S 2010 Nat. Nanotechnol. 5 574 Google Scholar
[4]	Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus M S, Kong J 2009 Nano Lett. 9 30 Google Scholar
[5]	Muñoz R, Gómez Aleixandre C 2013 Chem. Vap. Deposition 19 297 Google Scholar
[6]	Chhowalla M, Teo K B K, Ducati C, Rupesinghe N L, Amaratunga G A J, Ferrari A C, Roy D, Robertson J, Milne W I 2001 J. Appl. Phys. 90 5308 Google Scholar
[7]	Wu Y, Qiao P, Chong T, Shen Z 2002 Adv. Mater. 14 64 Google Scholar
[8]	Hiramatsu M, Shiji K, Amano H, Hori M 2004 Appl. Phys. Lett. 84 4708 Google Scholar
[9]	Shiji K, Hiramatsu M, Enomoto A, Nakamura M, Amano H, Hori M 2005 Diamond Relat. Mater. 14 831 Google Scholar
[10]	Tanaike O, Kitada N, Yoshimura H, Hatori H, Kojima K, Tachibana M 2009 Solid State Ionics 180 381 Google Scholar
[11]	Ren Z F, Huang Z P, Xu J W, Wang J H, Bush P, Siegal M P, Provencio P N 1998 Science 282 1105 Google Scholar
[12]	Boskovic B O, Stolojan V, Khan R U A, Haq S, Silva S R P 2002 Nat. Mater. 1 165 Google Scholar
[13]	Qi J L, Zheng W T, Zheng X H, Wang X, Tian H W 2011 Appl. Surf. Sci. 257 6531 Google Scholar
[14]	Peng K J, Wu C L, Lin Y H, Liu Y J, Tsai D P, Pai Y H, Lin G R 2013 J. Mater. Chem. C 1 3862 Google Scholar
[15]	Wang S M, Pei Y H, Wang X, Wang H, Meng Q N, Tian H W, Zheng X L, Zheng W T, Liu Y C 2010 J. Phys. D: Appl. Phys. 43 455402 Google Scholar
[16]	Wang S, Qiao L, Zhao C, Zhang X, Chen J, Tian H, Zheng W, Han Z 2013 New J. Chem. 37 1616 Google Scholar
[17]	Kim Y S, Lee J H, Kim Y D, Jerng S K, Joo K, Kim E, Jung J, Yoon E, Park Y D, Seo S, Chun S H 2013 Nanoscale 5 1221 Google Scholar
[18]	Terasawa T o, Saiki K 2012 Carbon 50 869 Google Scholar
[19]	Kim Y, Song W, Lee S Y, Jeon C, Jung W, Kim M, Park C Y 2011 Appl. Phys. Lett. 98 263106 Google Scholar
[20]	Cai M, Outlaw R A, Quinlan R A, Premathilake D, Butler S M, Miller J R 2014 ACS Nano 8 5873 Google Scholar
[21]	Yu K, Bo Z, Lu G, Mao S, Cui S, Zhu Y, Chen X, Ruoff R S, Chen J 2011 Nanoscale Res. Lett. 6 202 Google Scholar
[22]	Wang J, Zhu M, Outlaw R A, Zhao X, Manos D M, Holloway B C 2004 Carbon 42 2867 Google Scholar
[23]	Malesevic A, Vitchev R, Schouteden K, Volodin A, Zhang L, Tendeloo G V, Vanhulsel A, Haesendonck C V 2008 Nanotechnology 19 305604 Google Scholar
[24]	Tseng W S, Chen Y C, Hsu C C, Lu C H, Wu C I, Yeh N C 2020 Nanotechnology 31 335602 Google Scholar
[25]	Kato T, Hatakeyama R 2012 ACS Nano 6 8508 Google Scholar
[26]	Yang W, He C, Zhang L, Wang Y, Shi Z, Cheng M, Xie G, Wang D, Yang R, Shi D, Zhang G 2012 Small 8 1429 Google Scholar
[27]	Zhao J, Shaygan M, Eckert J, Meyyappan M, Rümmeli M H 2014 Nano Lett. 14 3064 Google Scholar
[28]	Ma Y, Jang H, Kim S J, Pang C, Chae H 2015 Nanoscale Res. Lett. 10 308 Google Scholar
[29]	Zhu M, Wang J, Holloway B C, Outlaw R A, Zhao X, Hou K, Shutthanandan V, Manos D M 2007 Carbon 45 2229 Google Scholar
[30]	Wei D, Lu Y, Han C, Niu T, Chen W, Wee A T S 2013 Angew. Chem. Int. Ed. 52 14121 Google Scholar
[31]	Hussain S, Kovacevic E, Berndt J, Santhosh N M, Pattyn C, Dias A, Strunskus T, Ammar M R, Jagodar A, Gaillard M, Boulmer Leborgne C, Cvelbar U 2020 Nanotechnology 31 395604 Google Scholar
[32]	Mouralova K, Zahradnicek R, Bednar J 2019 Diamond Relat. Mater. 97 107439 Google Scholar
[33]	Wei N, Li Q, Cong S, Ci H, Song Y, Yang Q, Lu C, Li C, Zou G, Sun J, Zhang Y, Liu Z 2019 J. Mater. Chem. A 7 4813 Google Scholar
[34]	Su F, Chen G, Sun J 2019 Tribol. Int. 130 1 Google Scholar
[35]	Zhang H, Wu S, Lu Z, Chen X, Chen Q, Gao P, Yu T, Peng Z, Ye J 2019 Carbon 147 341 Google Scholar
[36]	Chu J, Han Y, Li Y, Jia P, Cui H, Duan S, Feng P, Peng X 2020 J. Phys. D: Appl. Phys. 53 325101 Google Scholar
[37]	Wang X, Zhang Y, Tang M, Han D, Fu E, Xue J, Zhao Z 2015 Carbon 93 230 Google Scholar
[38]	Gutierrez G, Le Normand F, Muller D, Aweke F, Speisser C, Antoni F, Le Gall Y, Lee C S, Cojocaru C S 2014 Carbon 66 1 Google Scholar
[39]	Mun J H, Lim S K, Cho B J 2012 J. Electrochem. Soc. 159 G89 Google Scholar
[40]	Baraton L, He Z, Lee C S, Maurice J L, Cojocaru C S, Gourgues Lorenzon A F, Lee Y H, Pribat D 2011 Nanotechnology 22 085601 Google Scholar
[41]	Garaj S, Hubbard W, Golovchenko J A 2010 Appl. Phys. Lett. 97 183103 Google Scholar
[42]	Lee J S, Jang C W, Kim J M, Shin D H, Kim S, Choi S H, Belay K, Elliman R G 2014 Carbon 66 267 Google Scholar
[43]	Zhao Y, Han D, Wang X, Hu Z, Chen Y, Chen Y, Zhou D, Li Y, Fu E G, Zhao Z 2019 Carbon 153 776 Google Scholar
[44]	Gallon H J, Tu X, Twigg M V, Whitehead J C 2011 Appl. Catal., B 106 616 Google Scholar
[45]	Wu H, Xu C, Xu J, Lu L, Fan Z, Chen X, Song Y, Li D 2013 Nanotechnology 24 455401 Google Scholar
[46]	Major S, Kumar S, Bhatnagar M, Chopra K L 1986 Appl. Phys. Lett. 49 394 Google Scholar
[47]	Compton O C, Nguyen S T 2010 Small 6 711 Google Scholar
[48]	Gómez Navarro C, Weitz R T, Bittner A M, Scolari M, Mews A, Burghard M, Kern K 2007 Nano Lett. 7 3499 Google Scholar
[49]	Gilje S, Han S, Wang M, Wang K L, Kaner R B 2007 Nano Lett. 7 3394 Google Scholar
[50]	Zhou Q, Zhao Z, Chen Y, Hu H, Qiu J 2012 J. Mater. Chem. 22 6061 Google Scholar
[51]	Eng A Y S, Sofer Z, Šimek P, Kosina J, Pumera M 2013 Chem. Eur. J. 19 15583 Google Scholar
[52]	Muhammad Hafiz S, Ritikos R, Whitcher T J, Md. Razib N, Bien D C S, Chanlek N, Nakajima H, Saisopa T, Songsiriritthigul P, Huang N M, Rahman S A 2014 Sens. Actuators, B 193 692 Google Scholar
[53]	Cardinali M, Valentini L, Fabbri P, Kenny J M 2011 Chem. Phys. Lett. 508 285 Google Scholar
[54]	Yang C, Gong J, Zeng P, Yang X, Liang R, Ou Q, Zhang S 2018 Appl. Surf. Sci. 452 481 Google Scholar
[55]	Xu W, Wang X, Zhou Q, Meng B, Zhao J, Qiu J, Gogotsi Y 2012 J. Mater. Chem. 22 14363 Google Scholar
[56]	Ma Y, Wang Q, Miao Y, Lin Y, Li R 2018 Appl. Surf. Sci. 450 413 Google Scholar
[57]	Yang C, Yu Y, Xie Y, Zhang D, Zeng P, Dong Y, Yang B, Liang R, Ou Q, Zhang S 2019 Appl. Surf. Sci. 473 83 Google Scholar
[58]	Zhang D, Du Y, Yang C, Zeng P, Yu Y, Xie Y, Liang R, Ou Q, Zhang S 2021 J. Mater. Sci. 56 1359
[59]	Yang C, Zhang D, Zhao W, Cui M, Liang R, Ou Q, Zhang S 2020 J. Alloys Compd. 835 155334 Google Scholar
[60]	Liu C J, Zhao Y, Li Y, Zhang D S, Chang Z, Bu X H 2014 ACS Sustainable Chem. Eng. 2 3 Google Scholar
[61]	Goverapet Srinivasan S, van Duin A C T 2011 J. Phys. Chem. A 115 13269 Google Scholar
[62]	Kim K, Park H J, Woo B C, Kim K J, Kim G T, Yun W S 2008 Nano Lett. 8 3092 Google Scholar
[63]	Lu X, Yang X, Tariq M, Li F, Steimecke M, Li J, Varga A, Bron M, Abel B 2020 J. Mater. Chem. A 8 2445 Google Scholar
[64]	Felten A, Eckmann A, Pireaux J J, Krupke R, Casiraghi C 2013 Nanotechnology 24 355705 Google Scholar
[65]	Seah C M, Vigolo B, Chai S P, Mohamed A R 2016 Carbon 105 496 Google Scholar
[66]	Nourbakhsh A, Cantoro M, Vosch T, Pourtois G, Clemente F, van der Veen M H, Hofkens J, Heyns M M, De Gendt S, Sels B F 2010 Nanotechnology 21 435203 Google Scholar
[67]	Xiao N, Dong X, Song L, Liu D, Tay Y, Wu S, Li L J, Zhao Y, Yu T, Zhang H, Huang W, Hng H H, Ajayan P M, Yan Q 2011 ACS Nano 5 2749 Google Scholar
[68]	Gokus T, Nair R R, Bonetti A, Böhmler M, Lombardo A, Novoselov K S, Geim A K, Ferrari A C, Hartschuh A 2009 ACS Nano 3 3963 Google Scholar
[69]	Nourbakhsh A, Cantoro M, Klekachev A V, Pourtois G, Hofkens J, van der Veen M H, Heyns M M, De Gendt S, Sels B F 2011 J. Phys. Chem. C 115 16619 Google Scholar
[70]	Lu N, Yin D, Li Z, Yang J 2011 J. Phys. Chem. C 115 11991 Google Scholar
[71]	Dai Y F, Ni S, Li Z Y, Yang J L 2013 J. Phys. Condens. Matter 25 405301 Google Scholar
[72]	Xiang H J, Wei S H, Gong X G 2010 Phys. Rev. B 82 035416 Google Scholar
[73]	Yan J A, Chou M Y 2010 Phys. Rev. B 82 125403 Google Scholar
[74]	Kutana A, Giapis K P 2009 J. Phys. Chem. C 113 14721 Google Scholar
[75]	Sun T, Fabris S 2012 Nano Lett. 12 17 Google Scholar
[76]	Xu Z, Xue K 2010 Nanotechnology 21 045704 Google Scholar
[77]	Barinov A, Malcioǧlu O B, Fabris S, Sun T, Gregoratti L, Dalmiglio M, Kiskinova M 2009 J. Phys. Chem. C 113 9009 Google Scholar
[78]	Zhao H, Fan S, Chen Y, Feng Z, Zhang H, Pang W, Zhang D, Zhang M 2017 ACS Appl. Mater. Interfaces 9 40774 Google Scholar
[79]	Huang C H, Su C Y, Lai C S, Li Y C, Samukawa S 2014 Carbon 73 244 Google Scholar
[80]	Feng T, Xie D, Tian H, Peng P, Zhang D, Fu D, Ren T, Li X, Zhu H, Jing Y 2012 Mater. Lett. 73 187 Google Scholar
[81]	Koizumi K, Boero M, Shigeta Y, Oshiyama A 2013 J. Phys. Chem. Lett. 4 1592 Google Scholar
[82]	Sun T, Fabris S, Baroni S 2011 J. Phys. Chem. C 115 4730 Google Scholar
[83]	Han M Y, Özyilmaz B, Zhang Y, Kim P 2007 Phys. Rev. Lett. 98 206805 Google Scholar
[84]	Ponomarenko L A, Schedin F, Katsnelson M I, Yang R, Hill E W, Novoselov K S, Geim A K 2008 Science 320 356 Google Scholar
[85]	Hui L S, Whiteway E, Hilke M, Turak A 2017 Carbon 125 500 Google Scholar
[86]	Shin Y J, Wang Y, Huang H, Kalon G, Wee A T S, Shen Z, Bhatia C S, Yang H 2010 Langmuir 26 3798 Google Scholar
[87]	Sahoo G, Polaki S R, Ghosh S, Krishna N G, Kamruddin M 2018 J. Power Sources 401 37 Google Scholar
[88]	Surwade S P, Smirnov S N, Vlassiouk I V, Unocic R R, Veith G M, Dai S, Mahurin S M 2015 Nat. Nanotechnol. 10 459 Google Scholar
[89]	Qi H, Li Z, Tao Y, Zhao W, Lin K, Ni Z, Jin C, Zhang Y, Bi K, Chen Y 2018 Nanoscale 10 5350 Google Scholar
[90]	Sugiura H, Kondo H, Higuchi K, Arai S, Hamaji R, Tsutsumi T, Ishikawa K, Hori M 2020 Carbon 170 93 Google Scholar
[91]	Lee B J, Jeong G H 2013 Vacuum 87 200 Google Scholar
[92]	Castro Neto A H, Guinea F, Peres N M R, Novoselov K S, Geim A K 2009 Rev. Mod. Phys. 81 109 Google Scholar
[93]	Liu H, Liu Y, Zhu D 2011 J. Mater. Chem. 21 3335 Google Scholar
[94]	Geim A K, Novoselov K S 2007 Nat. Mater. 6 183 Google Scholar
[95]	Gierz I, Riedl C, Starke U, Ast C R, Kern K 2008 Nano Lett. 8 4603 Google Scholar
[96]	Wei D, Liu Y, Wang Y, Zhang H, Huang L, Yu G 2009 Nano Lett. 9 1752 Google Scholar
[97]	Wang X, Li X, Zhang L, Yoon Y, Weber P K, Wang H, Guo J, Dai H 2009 Science 324 768 Google Scholar
[98]	Li X, Wang H, Robinson J T, Sanchez H, Diankov G, Dai H 2009 J. Am. Chem. Soc. 131 15939 Google Scholar
[99]	Sheng Z H, Shao L, Chen J J, Bao W J, Wang F B, Xia X H 2011 ACS Nano 5 4350 Google Scholar
[100]	Elias D C, Nair R R, Mohiuddin T M G, Morozov S V, Blake P, Halsall M P, Ferrari A C, Boukhvalov D W, Katsnelson M I, Geim A K, Novoselov K S 2009 Science 323 610 Google Scholar
[101]	Wu J, Xie L, Li Y, Wang H, Ouyang Y, Guo J, Dai H 2011 J. Am. Chem. Soc. 133 19668 Google Scholar
[102]	Pham V P, Kim K H, Jeon M H, Lee S H, Kim K N, Yeom G Y 2015 Carbon 95 664 Google Scholar
[103]	Wang Y, Shao Y, Matson D W, Li J, Lin Y 2010 ACS Nano 4 1790 Google Scholar
[104]	Lin Y P, Ksari Y, Aubel D, Hajjar Garreau S, Borvon G, Spiegel Y, Roux L, Simon L, Themlin J M 2016 Carbon 100 337 Google Scholar
[105]	Akada K, Terasawa T o, Imamura G, Obata S, Saiki K 2014 Appl. Phys. Lett. 104 131602 Google Scholar
[106]	Shao Y, Zhang S, Engelhard M H, Li G, Shao G, Wang Y, Liu J, Aksay I A, Lin Y 2010 J. Mater. Chem. 20 7491 Google Scholar
[107]	Baraket M, Stine R, Lee W K, Robinson J T, Tamanaha C R, Sheehan P E, Walton S G 2012 Appl. Phys. Lett. 100 233123 Google Scholar
[108]	Dou S, Tao L, Huo J, Wang S, Dai L 2016 Energy Environ. Sci. 9 1320 Google Scholar
[109]	Ji W, Liu Y, Shan Z, Zhang X, Ding F, Li X 2019 Ceram. Int. 45 7095 Google Scholar
[110]	Elumalai S, Su C Y, Yoshimura M 2019 Front. Mater. 6 216 Google Scholar
[111]	Abdelkader-Fernández V K, Domingo Garcia M, Lopez Garzon F J, Fernandes D M, Freire C, de la Torre M D L, Melguizo M, Godino Salido M L, Perez Mendoza M 2019 Carbon 144 269 Google Scholar
[112]	Wong C H A, Sofer Z, Klímová K, Pumera M 2016 ACS Appl. Mater. Interfaces 8 31849 Google Scholar
[113]	Denis P A 2010 Chem. Phys. Lett. 492 251 Google Scholar
[114]	Denis P A 2013 Comput. Mater. Sci. 67 203 Google Scholar
[115]	Chu K, Wang F, Tian Y, Wei Z 2017 Electrochim. Acta 231 557 Google Scholar
[116]	Chen X J, Bo X, Ren W H, Chen S, Zhao C 2019 Mater. Chem. Front. 3 1433 Google Scholar
[117]	Rybin M, Pereyaslavtsev A, Vasilieva T, Myasnikov V, Sokolov I, Pavlova A, Obraztsova E, Khomich A, Ralchenko V, Obraztsova E 2016 Carbon 96 196 Google Scholar
[118]	Dou S, Tao L, Wang R, El Hankari S, Chen R, Wang S 2018 Adv. Mater. 30 1705850 Google Scholar
[119]	Bazaka K, Baranov O, Cvelbar U, Podgornik B, Wang Y, Huang S, Xu L, Lim J W M, Levchenko I, Xu S 2018 Nanoscale 10 17494 Google Scholar
[120]	Ouyang B, Zhang Y, Xia X, Rawat R S, Fan H J 2018 Mater. Today Nano 3 28 Google Scholar

施引文献

图 1 等离子体技术改性石墨烯的主要物理过程示意图

Fig. 1. A schematic diagram of the main physical processes of graphene modification based on plasma technologies.

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图 2 (a) PECVD方法在Ni基板上生长石墨烯示意图^[14]; (b) PECVD方法在Si/SiO₂基板上生长单层石墨烯示意图^[25]; (c) PECVD方法在Cu催化与非催化条件下生长垂直石墨烯示意图^[28]

Fig. 2. A schematic diagram of (a) growing graphene on a Ni substrate by PECVD^[14], (b) growing monolayer graphene on a Si/SiO₂ substrate by PECVD ^[25] and (c) growing vertical graphene by PECVD with and without Cu catalysis ^[28].

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图 3 (a) DBD等离子体还原GO示意图^[50]; (b) CH₄/Ar等离子体同步还原与修复GO过程^[54]; (c) Ar等离子体一步还原HAuCl₄与GO示意图^[57]; (d)等离子体还原与热还原形核生长过程示意图^[60]

Fig. 3. A schematic diagram of (a) GO reduction using DBD plasma^[50], (b) GO reduction and repair using CH₄/Ar plasma^[54], (c) one-step reduction of HAuCl₄ and GO using Ar plasma^[57], (d) nucleation and growth process using plasma reduction and thermal reduction, respectively^[60].

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图 4 氧等离子体处理对石墨烯的功能化修饰　(a) SLG, BLG, FLG经氧等离子体处理后的光致发光行为及表面原子结构示意图^[67]; (b) GO与氧等离子体处理后的GO (P-GO)表面扫描电子显微镜(scanning electron microscope, SEM)图^[78]; (c) 碳化硅衬底(SiC)、高序热解石墨(highly oriented pyrolytic graphite, HOPG)以及SiC上的SLG和氧等离子体处理后的SLG上的水滴^[86]; (d) 单层纳米多孔石墨烯膜的制备与性能测试示意图^[89]

Fig. 4. Functional modification of graphene by oxygen plasma treatment: (a) Photoluminescence image of SLG, BLG and FLG after exposure to O₂ plasma and a schematic illustration of the atomic structure of graphene after O₂ plasma treatment^[67]; (b) SEM photos of pristine GO and P-GO surfaces^[78]; (c) water droplets on SiC, HOPG, SLG on SiC, and oxygen-plasma-etched graphene on SiC^[86]; (d) a schematic illustration of preparation and characterization of monolayer nanoporous graphene films^[89].

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图 5 (a) 本征石墨烯的能带结构^[92]; (b) 石墨烯狄拉克点位置和费米能级随不同掺杂类型变化原理图^[95]; (c) 石墨烯氮掺杂的三种构型: 吡啶氮、吡咯氮和石墨氮^[103]; (d) 氮掺杂石墨烯催化H₂O₂电化学还原的循环伏安曲线^[103]; (e) 氮掺杂Co₉S₈/graphene的Co 2p轨道分峰谱(左)和N 1s轨道分峰谱(右)^[108]; (f) 硫掺杂石墨烯催化OER反应极化曲线^[112]

Fig. 5. (a) Band structure of pristine graphene^[92]; (b) the position of the Dirac point and the Fermi level as a function of doping type^[95]; (c) bonding configurations for nitrogen atoms in N-graphene^[103]; (d) cyclic voltammograms of H₂O₂ on N-graphene electrode^[103]; (e) Co 2p deconvolution spectra (left) and N 1s deconvolution spectra of N-Co₉S₈/graphene (right)^[108]; (f) linear sweep voltammograms for OER of S-graphene^[112].

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[1]	Novoselov K S, Fal'ko V I, Colombo L, Gellert P R, Schwab M G, Kim K 2012 Nature 490 192 Google Scholar
[2]	Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S 2009 Science 324 1312 Google Scholar
[3]	Bae S, Kim H, Lee Y, Xu X, Park J S, Zheng Y, Balakrishnan J, Lei T, Ri Kim H, Song Y I, Kim Y J, Kim K S, Özyilmaz B, Ahn J H, Hong B H, Iijima S 2010 Nat. Nanotechnol. 5 574 Google Scholar
[4]	Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus M S, Kong J 2009 Nano Lett. 9 30 Google Scholar
[5]	Muñoz R, Gómez Aleixandre C 2013 Chem. Vap. Deposition 19 297 Google Scholar
[6]	Chhowalla M, Teo K B K, Ducati C, Rupesinghe N L, Amaratunga G A J, Ferrari A C, Roy D, Robertson J, Milne W I 2001 J. Appl. Phys. 90 5308 Google Scholar
[7]	Wu Y, Qiao P, Chong T, Shen Z 2002 Adv. Mater. 14 64 Google Scholar
[8]	Hiramatsu M, Shiji K, Amano H, Hori M 2004 Appl. Phys. Lett. 84 4708 Google Scholar
[9]	Shiji K, Hiramatsu M, Enomoto A, Nakamura M, Amano H, Hori M 2005 Diamond Relat. Mater. 14 831 Google Scholar
[10]	Tanaike O, Kitada N, Yoshimura H, Hatori H, Kojima K, Tachibana M 2009 Solid State Ionics 180 381 Google Scholar
[11]	Ren Z F, Huang Z P, Xu J W, Wang J H, Bush P, Siegal M P, Provencio P N 1998 Science 282 1105 Google Scholar
[12]	Boskovic B O, Stolojan V, Khan R U A, Haq S, Silva S R P 2002 Nat. Mater. 1 165 Google Scholar
[13]	Qi J L, Zheng W T, Zheng X H, Wang X, Tian H W 2011 Appl. Surf. Sci. 257 6531 Google Scholar
[14]	Peng K J, Wu C L, Lin Y H, Liu Y J, Tsai D P, Pai Y H, Lin G R 2013 J. Mater. Chem. C 1 3862 Google Scholar
[15]	Wang S M, Pei Y H, Wang X, Wang H, Meng Q N, Tian H W, Zheng X L, Zheng W T, Liu Y C 2010 J. Phys. D: Appl. Phys. 43 455402 Google Scholar
[16]	Wang S, Qiao L, Zhao C, Zhang X, Chen J, Tian H, Zheng W, Han Z 2013 New J. Chem. 37 1616 Google Scholar
[17]	Kim Y S, Lee J H, Kim Y D, Jerng S K, Joo K, Kim E, Jung J, Yoon E, Park Y D, Seo S, Chun S H 2013 Nanoscale 5 1221 Google Scholar
[18]	Terasawa T o, Saiki K 2012 Carbon 50 869 Google Scholar
[19]	Kim Y, Song W, Lee S Y, Jeon C, Jung W, Kim M, Park C Y 2011 Appl. Phys. Lett. 98 263106 Google Scholar
[20]	Cai M, Outlaw R A, Quinlan R A, Premathilake D, Butler S M, Miller J R 2014 ACS Nano 8 5873 Google Scholar
[21]	Yu K, Bo Z, Lu G, Mao S, Cui S, Zhu Y, Chen X, Ruoff R S, Chen J 2011 Nanoscale Res. Lett. 6 202 Google Scholar
[22]	Wang J, Zhu M, Outlaw R A, Zhao X, Manos D M, Holloway B C 2004 Carbon 42 2867 Google Scholar
[23]	Malesevic A, Vitchev R, Schouteden K, Volodin A, Zhang L, Tendeloo G V, Vanhulsel A, Haesendonck C V 2008 Nanotechnology 19 305604 Google Scholar
[24]	Tseng W S, Chen Y C, Hsu C C, Lu C H, Wu C I, Yeh N C 2020 Nanotechnology 31 335602 Google Scholar
[25]	Kato T, Hatakeyama R 2012 ACS Nano 6 8508 Google Scholar
[26]	Yang W, He C, Zhang L, Wang Y, Shi Z, Cheng M, Xie G, Wang D, Yang R, Shi D, Zhang G 2012 Small 8 1429 Google Scholar
[27]	Zhao J, Shaygan M, Eckert J, Meyyappan M, Rümmeli M H 2014 Nano Lett. 14 3064 Google Scholar
[28]	Ma Y, Jang H, Kim S J, Pang C, Chae H 2015 Nanoscale Res. Lett. 10 308 Google Scholar
[29]	Zhu M, Wang J, Holloway B C, Outlaw R A, Zhao X, Hou K, Shutthanandan V, Manos D M 2007 Carbon 45 2229 Google Scholar
[30]	Wei D, Lu Y, Han C, Niu T, Chen W, Wee A T S 2013 Angew. Chem. Int. Ed. 52 14121 Google Scholar
[31]	Hussain S, Kovacevic E, Berndt J, Santhosh N M, Pattyn C, Dias A, Strunskus T, Ammar M R, Jagodar A, Gaillard M, Boulmer Leborgne C, Cvelbar U 2020 Nanotechnology 31 395604 Google Scholar
[32]	Mouralova K, Zahradnicek R, Bednar J 2019 Diamond Relat. Mater. 97 107439 Google Scholar
[33]	Wei N, Li Q, Cong S, Ci H, Song Y, Yang Q, Lu C, Li C, Zou G, Sun J, Zhang Y, Liu Z 2019 J. Mater. Chem. A 7 4813 Google Scholar
[34]	Su F, Chen G, Sun J 2019 Tribol. Int. 130 1 Google Scholar
[35]	Zhang H, Wu S, Lu Z, Chen X, Chen Q, Gao P, Yu T, Peng Z, Ye J 2019 Carbon 147 341 Google Scholar
[36]	Chu J, Han Y, Li Y, Jia P, Cui H, Duan S, Feng P, Peng X 2020 J. Phys. D: Appl. Phys. 53 325101 Google Scholar
[37]	Wang X, Zhang Y, Tang M, Han D, Fu E, Xue J, Zhao Z 2015 Carbon 93 230 Google Scholar
[38]	Gutierrez G, Le Normand F, Muller D, Aweke F, Speisser C, Antoni F, Le Gall Y, Lee C S, Cojocaru C S 2014 Carbon 66 1 Google Scholar
[39]	Mun J H, Lim S K, Cho B J 2012 J. Electrochem. Soc. 159 G89 Google Scholar
[40]	Baraton L, He Z, Lee C S, Maurice J L, Cojocaru C S, Gourgues Lorenzon A F, Lee Y H, Pribat D 2011 Nanotechnology 22 085601 Google Scholar
[41]	Garaj S, Hubbard W, Golovchenko J A 2010 Appl. Phys. Lett. 97 183103 Google Scholar
[42]	Lee J S, Jang C W, Kim J M, Shin D H, Kim S, Choi S H, Belay K, Elliman R G 2014 Carbon 66 267 Google Scholar
[43]	Zhao Y, Han D, Wang X, Hu Z, Chen Y, Chen Y, Zhou D, Li Y, Fu E G, Zhao Z 2019 Carbon 153 776 Google Scholar
[44]	Gallon H J, Tu X, Twigg M V, Whitehead J C 2011 Appl. Catal., B 106 616 Google Scholar
[45]	Wu H, Xu C, Xu J, Lu L, Fan Z, Chen X, Song Y, Li D 2013 Nanotechnology 24 455401 Google Scholar
[46]	Major S, Kumar S, Bhatnagar M, Chopra K L 1986 Appl. Phys. Lett. 49 394 Google Scholar
[47]	Compton O C, Nguyen S T 2010 Small 6 711 Google Scholar
[48]	Gómez Navarro C, Weitz R T, Bittner A M, Scolari M, Mews A, Burghard M, Kern K 2007 Nano Lett. 7 3499 Google Scholar
[49]	Gilje S, Han S, Wang M, Wang K L, Kaner R B 2007 Nano Lett. 7 3394 Google Scholar
[50]	Zhou Q, Zhao Z, Chen Y, Hu H, Qiu J 2012 J. Mater. Chem. 22 6061 Google Scholar
[51]	Eng A Y S, Sofer Z, Šimek P, Kosina J, Pumera M 2013 Chem. Eur. J. 19 15583 Google Scholar
[52]	Muhammad Hafiz S, Ritikos R, Whitcher T J, Md. Razib N, Bien D C S, Chanlek N, Nakajima H, Saisopa T, Songsiriritthigul P, Huang N M, Rahman S A 2014 Sens. Actuators, B 193 692 Google Scholar
[53]	Cardinali M, Valentini L, Fabbri P, Kenny J M 2011 Chem. Phys. Lett. 508 285 Google Scholar
[54]	Yang C, Gong J, Zeng P, Yang X, Liang R, Ou Q, Zhang S 2018 Appl. Surf. Sci. 452 481 Google Scholar
[55]	Xu W, Wang X, Zhou Q, Meng B, Zhao J, Qiu J, Gogotsi Y 2012 J. Mater. Chem. 22 14363 Google Scholar
[56]	Ma Y, Wang Q, Miao Y, Lin Y, Li R 2018 Appl. Surf. Sci. 450 413 Google Scholar
[57]	Yang C, Yu Y, Xie Y, Zhang D, Zeng P, Dong Y, Yang B, Liang R, Ou Q, Zhang S 2019 Appl. Surf. Sci. 473 83 Google Scholar
[58]	Zhang D, Du Y, Yang C, Zeng P, Yu Y, Xie Y, Liang R, Ou Q, Zhang S 2021 J. Mater. Sci. 56 1359
[59]	Yang C, Zhang D, Zhao W, Cui M, Liang R, Ou Q, Zhang S 2020 J. Alloys Compd. 835 155334 Google Scholar
[60]	Liu C J, Zhao Y, Li Y, Zhang D S, Chang Z, Bu X H 2014 ACS Sustainable Chem. Eng. 2 3 Google Scholar
[61]	Goverapet Srinivasan S, van Duin A C T 2011 J. Phys. Chem. A 115 13269 Google Scholar
[62]	Kim K, Park H J, Woo B C, Kim K J, Kim G T, Yun W S 2008 Nano Lett. 8 3092 Google Scholar
[63]	Lu X, Yang X, Tariq M, Li F, Steimecke M, Li J, Varga A, Bron M, Abel B 2020 J. Mater. Chem. A 8 2445 Google Scholar
[64]	Felten A, Eckmann A, Pireaux J J, Krupke R, Casiraghi C 2013 Nanotechnology 24 355705 Google Scholar
[65]	Seah C M, Vigolo B, Chai S P, Mohamed A R 2016 Carbon 105 496 Google Scholar
[66]	Nourbakhsh A, Cantoro M, Vosch T, Pourtois G, Clemente F, van der Veen M H, Hofkens J, Heyns M M, De Gendt S, Sels B F 2010 Nanotechnology 21 435203 Google Scholar
[67]	Xiao N, Dong X, Song L, Liu D, Tay Y, Wu S, Li L J, Zhao Y, Yu T, Zhang H, Huang W, Hng H H, Ajayan P M, Yan Q 2011 ACS Nano 5 2749 Google Scholar
[68]	Gokus T, Nair R R, Bonetti A, Böhmler M, Lombardo A, Novoselov K S, Geim A K, Ferrari A C, Hartschuh A 2009 ACS Nano 3 3963 Google Scholar
[69]	Nourbakhsh A, Cantoro M, Klekachev A V, Pourtois G, Hofkens J, van der Veen M H, Heyns M M, De Gendt S, Sels B F 2011 J. Phys. Chem. C 115 16619 Google Scholar
[70]	Lu N, Yin D, Li Z, Yang J 2011 J. Phys. Chem. C 115 11991 Google Scholar
[71]	Dai Y F, Ni S, Li Z Y, Yang J L 2013 J. Phys. Condens. Matter 25 405301 Google Scholar
[72]	Xiang H J, Wei S H, Gong X G 2010 Phys. Rev. B 82 035416 Google Scholar
[73]	Yan J A, Chou M Y 2010 Phys. Rev. B 82 125403 Google Scholar
[74]	Kutana A, Giapis K P 2009 J. Phys. Chem. C 113 14721 Google Scholar
[75]	Sun T, Fabris S 2012 Nano Lett. 12 17 Google Scholar
[76]	Xu Z, Xue K 2010 Nanotechnology 21 045704 Google Scholar
[77]	Barinov A, Malcioǧlu O B, Fabris S, Sun T, Gregoratti L, Dalmiglio M, Kiskinova M 2009 J. Phys. Chem. C 113 9009 Google Scholar
[78]	Zhao H, Fan S, Chen Y, Feng Z, Zhang H, Pang W, Zhang D, Zhang M 2017 ACS Appl. Mater. Interfaces 9 40774 Google Scholar
[79]	Huang C H, Su C Y, Lai C S, Li Y C, Samukawa S 2014 Carbon 73 244 Google Scholar
[80]	Feng T, Xie D, Tian H, Peng P, Zhang D, Fu D, Ren T, Li X, Zhu H, Jing Y 2012 Mater. Lett. 73 187 Google Scholar
[81]	Koizumi K, Boero M, Shigeta Y, Oshiyama A 2013 J. Phys. Chem. Lett. 4 1592 Google Scholar
[82]	Sun T, Fabris S, Baroni S 2011 J. Phys. Chem. C 115 4730 Google Scholar
[83]	Han M Y, Özyilmaz B, Zhang Y, Kim P 2007 Phys. Rev. Lett. 98 206805 Google Scholar
[84]	Ponomarenko L A, Schedin F, Katsnelson M I, Yang R, Hill E W, Novoselov K S, Geim A K 2008 Science 320 356 Google Scholar
[85]	Hui L S, Whiteway E, Hilke M, Turak A 2017 Carbon 125 500 Google Scholar
[86]	Shin Y J, Wang Y, Huang H, Kalon G, Wee A T S, Shen Z, Bhatia C S, Yang H 2010 Langmuir 26 3798 Google Scholar
[87]	Sahoo G, Polaki S R, Ghosh S, Krishna N G, Kamruddin M 2018 J. Power Sources 401 37 Google Scholar
[88]	Surwade S P, Smirnov S N, Vlassiouk I V, Unocic R R, Veith G M, Dai S, Mahurin S M 2015 Nat. Nanotechnol. 10 459 Google Scholar
[89]	Qi H, Li Z, Tao Y, Zhao W, Lin K, Ni Z, Jin C, Zhang Y, Bi K, Chen Y 2018 Nanoscale 10 5350 Google Scholar
[90]	Sugiura H, Kondo H, Higuchi K, Arai S, Hamaji R, Tsutsumi T, Ishikawa K, Hori M 2020 Carbon 170 93 Google Scholar
[91]	Lee B J, Jeong G H 2013 Vacuum 87 200 Google Scholar
[92]	Castro Neto A H, Guinea F, Peres N M R, Novoselov K S, Geim A K 2009 Rev. Mod. Phys. 81 109 Google Scholar
[93]	Liu H, Liu Y, Zhu D 2011 J. Mater. Chem. 21 3335 Google Scholar
[94]	Geim A K, Novoselov K S 2007 Nat. Mater. 6 183 Google Scholar
[95]	Gierz I, Riedl C, Starke U, Ast C R, Kern K 2008 Nano Lett. 8 4603 Google Scholar
[96]	Wei D, Liu Y, Wang Y, Zhang H, Huang L, Yu G 2009 Nano Lett. 9 1752 Google Scholar
[97]	Wang X, Li X, Zhang L, Yoon Y, Weber P K, Wang H, Guo J, Dai H 2009 Science 324 768 Google Scholar
[98]	Li X, Wang H, Robinson J T, Sanchez H, Diankov G, Dai H 2009 J. Am. Chem. Soc. 131 15939 Google Scholar
[99]	Sheng Z H, Shao L, Chen J J, Bao W J, Wang F B, Xia X H 2011 ACS Nano 5 4350 Google Scholar
[100]	Elias D C, Nair R R, Mohiuddin T M G, Morozov S V, Blake P, Halsall M P, Ferrari A C, Boukhvalov D W, Katsnelson M I, Geim A K, Novoselov K S 2009 Science 323 610 Google Scholar
[101]	Wu J, Xie L, Li Y, Wang H, Ouyang Y, Guo J, Dai H 2011 J. Am. Chem. Soc. 133 19668 Google Scholar
[102]	Pham V P, Kim K H, Jeon M H, Lee S H, Kim K N, Yeom G Y 2015 Carbon 95 664 Google Scholar
[103]	Wang Y, Shao Y, Matson D W, Li J, Lin Y 2010 ACS Nano 4 1790 Google Scholar
[104]	Lin Y P, Ksari Y, Aubel D, Hajjar Garreau S, Borvon G, Spiegel Y, Roux L, Simon L, Themlin J M 2016 Carbon 100 337 Google Scholar
[105]	Akada K, Terasawa T o, Imamura G, Obata S, Saiki K 2014 Appl. Phys. Lett. 104 131602 Google Scholar
[106]	Shao Y, Zhang S, Engelhard M H, Li G, Shao G, Wang Y, Liu J, Aksay I A, Lin Y 2010 J. Mater. Chem. 20 7491 Google Scholar
[107]	Baraket M, Stine R, Lee W K, Robinson J T, Tamanaha C R, Sheehan P E, Walton S G 2012 Appl. Phys. Lett. 100 233123 Google Scholar
[108]	Dou S, Tao L, Huo J, Wang S, Dai L 2016 Energy Environ. Sci. 9 1320 Google Scholar
[109]	Ji W, Liu Y, Shan Z, Zhang X, Ding F, Li X 2019 Ceram. Int. 45 7095 Google Scholar
[110]	Elumalai S, Su C Y, Yoshimura M 2019 Front. Mater. 6 216 Google Scholar
[111]	Abdelkader-Fernández V K, Domingo Garcia M, Lopez Garzon F J, Fernandes D M, Freire C, de la Torre M D L, Melguizo M, Godino Salido M L, Perez Mendoza M 2019 Carbon 144 269 Google Scholar
[112]	Wong C H A, Sofer Z, Klímová K, Pumera M 2016 ACS Appl. Mater. Interfaces 8 31849 Google Scholar
[113]	Denis P A 2010 Chem. Phys. Lett. 492 251 Google Scholar
[114]	Denis P A 2013 Comput. Mater. Sci. 67 203 Google Scholar
[115]	Chu K, Wang F, Tian Y, Wei Z 2017 Electrochim. Acta 231 557 Google Scholar
[116]	Chen X J, Bo X, Ren W H, Chen S, Zhao C 2019 Mater. Chem. Front. 3 1433 Google Scholar
[117]	Rybin M, Pereyaslavtsev A, Vasilieva T, Myasnikov V, Sokolov I, Pavlova A, Obraztsova E, Khomich A, Ralchenko V, Obraztsova E 2016 Carbon 96 196 Google Scholar
[118]	Dou S, Tao L, Wang R, El Hankari S, Chen R, Wang S 2018 Adv. Mater. 30 1705850 Google Scholar
[119]	Bazaka K, Baranov O, Cvelbar U, Podgornik B, Wang Y, Huang S, Xu L, Lim J W M, Levchenko I, Xu S 2018 Nanoscale 10 17494 Google Scholar
[120]	Ouyang B, Zhang Y, Xia X, Rawat R S, Fan H J 2018 Mater. Today Nano 3 28 Google Scholar

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