搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

青蒿素降解产物桥酮倍半萜内酯的分子和晶体结构测定

林秀云 张树德 吴伸

引用本文:
Citation:

青蒿素降解产物桥酮倍半萜内酯的分子和晶体结构测定

林秀云, 张树德, 吴伸

THE MOLECULAR AND CRYSTAL STRUCTURE OF DEGRADATION PRODUCT ARTEMISININE-ENDOCYCLIC KETONE SESQUITERPENE LACTONE

Lin Xiu-yun, Zhang Shu-de, Wu Shen
PDF
导出引用
  • 青蒿素降解产物桥酮倍半萜内酯(C14H20O3)晶体属于正交晶系,空间群为P212121,晶胞参数a=16.997?,b=10.298?,c=7.394?,α=β=γ=90°,晶胞内分子数z=4。在PW-1100四圆衍射仪上收集三维衍射强度数据,其结构是用多解法求得,经块对角线矩阵最小二乘法修正,最后偏离因子R=0.084。此化合物的分子结构中的A/B两个六元环为顺式联结。
    This compound is a QINGHAOSU degradation product. The molecule consists of 14 carbon, 20 hydrogen, and 3 oxygen atoms. It crystallizes in the orthorhombic system with space group P21 21 21. There are four molecules in a unit cell, the lattice parameters are a = 16.997?, b = 10.298?, and c = 7.394?.The three-dimensional intensity data were collected by using PW-1100 four-circle diff-ractometer and the number of the independent diffractions amounts to 1377. The crystal structure was solved by direct methods. The positions of 14 atoms were given by E map and the additional carbon atom sites were obtained by cycle of Fourier synthses. The structure was refined by block-diagonal least square method. The final R-factor is 0.084.
计量
  • 文章访问数:  6581
  • PDF下载量:  512
  • 被引次数: 0
出版历程
  • 收稿日期:  1982-06-18
  • 刊出日期:  1983-02-05

/

返回文章
返回