Application of X-ray photoelectron spectroscopy to study interfaces for solid-state lithium ion battery

Zhou Yi-Fan; Yang Mu-Zi; She Feng-Quan; Gong Li; Zhang Xiao-Qi; Chen Jian; Song Shu-Qin; Xie Fang-Yan

doi:10.7498/aps.70.20210180

Abstract

Solid-state lithium-ion batteries have attracted much attention due to their high safety, high energy densities and other advantages. However, solid-state lithium-ion batteries cannot realize large-scale commercial use. There are key scientific and technical issues that have not been resolved, especially interface issues, such as high resistance and instability of the interface. The X-ray photoelectron spectroscopy (XPS), as an important surface analysis method, can perform qualitative and semi-quantitative chemical analysis of the interface, which makes XPS can be widely used to study the solid-state lithium-ion battery interfaces. In this paper, we review the recent research progress of solid-state lithium-ion battery interfaces by using XPS, and summarize and review the XPS experimental principle, experimental method, experimental results and their effects on interface performance. The XPS analysis methods for solid-state lithium-ion batteries include ex-situ XPS, in-situ XPS reflecting the real-time changes of the battery interface, and operando XPS based on the actual working conditions of the battery. The ex-situ XPS can study oxide solid electrolyte interfaces, sulfide solid electrolyte interfaces and artificial solid electrolyte interface (SEI) layers to access information about the chemical composition of the interface, predict the performance of the interface, obtain the chemical distribution in space, and evaluate the chemical structure and irregularity of the interface. With ultraviolet photoemission spectroscopy (UPS) the interface work function, energy band bending and energy structure of the full battery can be obtained. In-situ XPS can effectively study the process of chemical reactions between the electrolyte and the electrode. The key prerequisite is the controllable in-situ construction of the electrolyte/electrode interface. In-situ XPS research can directly study the electrochemical changes of the interface. In-situ XPS/UPS can study the energy level alignment of solid-state lithium-ion batteries, indicating that a space charge layer is formed at the solid electrolyte interface, and the energy band bending occurs. The degree of energy band bending is reflected in the binding energy shifts of the related elements at the interface. The change of the energy structure in the deposition process can be determined by the binding energy shifts of the related elements at the interface and the change of the interface work function. Operando XPS performs XPS characterization at the same time under the working condition of the battery. Operando XPS can be combined with electrochemical characterization to observe the effects of interface reaction and solid electrolyte decomposition products on electrochemical performance, thereby determining the main components that affect electrochemical performance. It can also be combined with the ex-situ XPS to study the interface reaction mechanism and influencing factors. The information obtained includes the chemical states of elements after the interface reaction has occurred, the evolution of interface elements in the process of real-time interface reaction, the energy structure change and interface component overpotential, thus having a better understanding of interface composition, interfacial structure change, kinetics of interface reaction, and interfacial ion migration of the solid-state lithium ion batteries.

Keywords:

Authors and contacts

1.
Instrumental Analysis & Research Center, Sun Yat-sen University, Guangzhou 510275, China
2.
School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
3.
School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

Corresponding author: Xie Fang-Yan, xiefy@mail.sysu.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 21576301, 51973244)

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Cited By

图 1 SSLIB中的界面、界面问题和解决策略示意图

Figure 1. Illustration of the interfaces, interface issues, and solving strategies in SSLIB.

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图 2 XPS测量的能级示意图

Figure 2. Schematic diagram of energy level in XPS measurement.

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图 3 (a)立方相Li₇La₃Zr₂O₁₂(c-LLZO)晶体结构示意图^[27]; (b)空气中不同暴露时间的LLZO微米粉体表面的O1s谱图变化

Figure 3. (a) Crystal structure of cubic Li₇La₃Zr₂O₁₂(c-LLZO)^[27]; (b) O1s spectra of LLZO micro particles exposed to air for different times.

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图 4 (a) 原始和放电后的Li₇La₃Zr₂O₁₂(LLZO)表面的Zr 3d分峰拟合结果^[31]; (b)原始Li_1.3Al_0.3Ti_1.7(PO₄)₃(LATP)、化学失效LATP、电化学失效LATP的Ti 2p谱图^[35]; LiCoO₂衬底上LLZO薄膜不同刻蚀深度的(c)Co 2p峰以及(d)Li 1s和Co 3p峰的XPS深度剖析谱图^[41]

Figure 4. (a) Peak deconvolution of Zr 3d spectra of fresh and discharged Li₇La₃Zr₂O₁₂ (LLZO)^[31]; (b) Ti 2p XPS spectra of the Li_1.3Al_0.3Ti_1.7(PO₄)₃ (LATP)-pristine, chem-LATP(chemical failure), and EC-LATP(electrochemical failure) surface^[35]; XPS depth profiles of (c) Co 2p spectra, (d) Li 1s and Co 3p spectra of LLZO thin film on LiCoO₂ at different depth^[41].

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图 5 (a) Li₁₀GeP₂S₁₂的晶体结构示意图^[47]; (b) Li₂S-P₂S₅体系中不同成分的部分材料的晶体结构示意图^[48]

Figure 5. (a) Crystal structure of Li₁₀GeP₂S₁₂^[47]; (b) crystal structures of some materials within Li₂S-P₂S₅ binary system^[48].

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图 6 (a) 循环后的Li/Li₁₀GeP₂S₁₂界面的XPS深度剖析谱图, S 2p, Ge 3d, P 2p, Li 1s^[58]; (b) 在不同截止电压(4.0—5.0 V)循环25次后的集流体/正极界面随时间变化的S 2p深度剖析谱图^[59]

Figure 6. (a) XPS depth profiles of cycled Li/Li₁₀GeP₂S₁₂ interface: XPS spectra of S 2p, Ge 3d, P 2p, Li 1s^[58]; (b) S 2p XPS depth profiles after 25 cycles for different upper cut-off voltage (4.0–5.0 V) as a function of different etching time^[59].

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图 7 (a) 循环后LiFSI修饰的Li₃PS₄的F 1s和P 2p(右)谱图, 循环后未处理的Li₃PS₄的P 2p(左)谱图^[64]; (b) Li/Li_2.9B_0.9S_0.1O_3.1对称电池恒流充放电循环前后的阻抗图^[66]; (c)刻蚀得到的Li/Li_2.9B_0.9S_0.1O_3.1区域表面/界面/体相的B 1s, S 2p, O 1s, Li 1s谱图^[66]

Figure 7. (a) F 1s and P 2p (right) spectra of LiFSI-treated Li₃PS₄ from cycled cell, P 2p (left) spectra of untreated Li₃PS₄ from cycled cell^[64]; (b) impedance plots of the Li/ Li_2.9B_0.9S_0.1O_3.1 symmetric cell before and after the galvanostatic test for cycles^[66]; (c) XPS spectra of B 1s, S 2p, O 1s, Li 1s for the outermost surface, interface, and electrolyte bulk regions uncovered by etching of Li/Li_2.9B_0.9S_0.1O_3.1 interface area^[66].

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图 8 (a) DAISY-BAT系统的示意图^[69]; (b)利用离子枪溅射金属靶材构筑界面以实现原位XPS的过程示意图^[70]

Figure 8. (a) Scheme of the DAISY-BAT system^[69]; (b) scheme of performing in situ XPS using ion gun to sputter the fixed metal target to build the interface^[70].

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图 9 (a) LLTO表面不同锂沉积时间的Ti 2p, La 3d, O 1s谱以及Ti 2p瀑布图^[70]; (b) 31 nm金属锂沉积过程中Li₁₀GeP₂S₁₂表面的S 2p, Ge 3d和P 2p-Ge 3p谱图^[53]; (c) Li_2.94PO_3.5N_0.31的结构和磷酸盐结构中N的结合情况示意图^[73,74]; (d)金属锂沉积过程中LiPON表面的O 1s, N 1s, P 2p, Li 1s和价带图^[76]

Figure 9. (a) Ti 2p, La 3d, O 1s detail spectra and Ti 2p waterfall plot for different Li metal deposition times on LLTO surface^[70]; (b) S 2p, Ge 3d, and P 2p-Ge 3p detail spectra during 31 nm Li metal deposition on Li₁₀GeP₂S₁₂ surface^[53]; (c) scheme of Li_2.94PO_3.5N_0.31 structure and possible N configurations in phosphate structures^[73,74]; (d) O 1s, N 1s, P 2p, Li 1s, and valence band spectra of LiPON surface during Li metal deposition^[76].

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图 10 (a)电化学电池的负极界面原位XPS测试示意图; (b)不同电势下Li/Ga-LLZO界面的O 1s, Li 1s, La 4d, Zr 3d谱图^[71]; (c)原位XPS装置示意图; (d)电化学极化中混合正极的S 2p谱图^[59]

Figure 10. (a) Scheme of the configuration of the anode surface of electrochemical cell for in situ XPS; (b) in situ XPS spectra of O 1s, Li 1s, La 4d, and Zr 3d at the Li/Ga-doped LLZO interphase as a function of potential^[71]; (c) scheme of the measurement setup for in situ XPS; (d) S 2p spectra of composite cathode during electrochemical polarization^[59].

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图 11 (a) LiPON沉积过程中LiCoO₂表面的Co 2p, O 1s, P 2p和价带谱图; (b) LiCoO₂内层电子结合能, LiPON P 2p电子结合能和表面功函数在沉积过程中的变化; (c)金属锂沉积过程中LiPON内层电子结合能的变化; (d)Li/LiPON/LiCoO₂ SSLIB的能带图^[12]

Figure 11. (a) Co 2p, O 1s, P 2p and valence band spectra of LiCoO₂ surface during the deposition of LiPON; (b) evolution of the core level binding energies of the LiCoO₂ substrate and the P 2p binding energy of the covering LiPON layer as a function of deposition time; (c) evolution of the binding energies during the stepwise evaporation of lithium on top of LiPON; (d) energy band diagram of Li/LiPON/LiCoO₂ SSLIB^[12].

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图 12 (a)全固态operando XPS电池的结构示意图^[83]; (b) Operando XPS电池和标准电池工作电极的循环伏安测试结果^[83]; (c) S 2p, P 2p, Co 3p-Li 1s-Fe 3p谱图在operando XPS测试过程中的变化^[83]

Figure 12. (a) An operando XPS cell design for all-solid-state batteries^[83]; (b) cyclic voltammetry measurements of the work electrodes of the operando XPS cell and a standard test cell^[83]; (c) evolution of S 2p, P 2p, and Co 3p-Li 1s-Fe 3p core level spectra recorded during the operando XPS measurements^[83].

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图 13 (a)虚拟电极法实现operando XPS测试的原理图和原始、充电、放电状态下Li₂S-P₂S₅表面的Li 1s谱图变化^[85]; (b)各XPS谱图及拟合结果在operando XPS过程中的变化^[85]

Figure 13. (a) Schematic of operando XPS measurements via virtual electrode cycling and the evolution of Li 1s spectra on Li₂S-P₂S₅ surface during the cycling process^[85]; (b) evolution of XPS spectra showing peak deconvolution during operando XPS measurements^[85].

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图 14 (a) SEI各组分充电过程中结合能的位移^[85]; (b) SEI各组分的过电位及得到的SEI结构示意图^[85]

Figure 14. (a) Binding energy shifts of each SEI phase composition during charging process^[85]; (b) overpotential of each SEI phase composition during charging process and scheme of SEI structure after charging based on the overpotential^[85].

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