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采用高温固相法制备了SrZn2(PO4)2:Sn2+(SZ2P:Sn2+), SrZn2(PO4)2:Mn2+(SZ2P:Mn2+), SrZn2 (PO4)2:Sn2+, Mn2+(SZ2P:Sn2+, Mn2+) 荧光粉. 通过X射线衍射、激发和发射光谱详细研究了荧光粉的物相和发光性质. 在SrZn2(PO4)2 基质中, Sn2+离子发射光谱是峰值位于461 nm宽带谱, 归属于Sn2+离子的3P1→1S0能级跃迁, SZ2P:Mn2+激发光谱由基质吸收带(200–300 nm)和位于352, 373, 419, 431和466 nm的一系列激发峰组成, 分别对应Mn2+离子的6A1(6S)→4E(4D), 6A1(6S)→4T2(4D), 6A1(6S)→[4A1(4G), 4E(4G)], 6A1(6S)→4T2(4G)和6A1(6S)→4T1(4G)能级跃迁, 因此, SZ2P:Sn2+ 的发射光谱与SZ2P:Mn2+的激发光谱有较大范围的重叠. 结果表明Sn2+对Mn2+发光有明显的敏化作用. 基于Dexter电多极相互作用能量传递公式和Reisfeld近似原理分析, 荧光粉SZ2P:Sn2+, Mn2+中Sn2+-Mn2+离子之间的能量传递机理属于电四极-电四极相互作用引起的共振能量传递, 并计算出Sn2+-Mn2+离子之间能量传递临界距离Rc ≈ 1.78 nm. 通过改变Sn2+, Mn2+离子掺杂浓度, 实现了荧光粉发光颜色的调节, 在254 nm短波紫外激发下荧光粉发出较强的蓝白光. 研究结果表明SZ2P:Sn2+, Mn2+荧光粉有望应用于紧凑型节能灯照明领域, 随着半导体紫外芯片技术的发展, 有潜力应用于未来的白光发光二极管照明领域.In this paper, SrZn2(PO4)2:Sn2+ (SZ2P:Sn2+), SrZn2(PO4)2:Mn2+ (SZ2P:Mn2+), SrZn2(PO4)2:Sn2+, and Mn2+ (SZ2P:Sn2+, Mn2+) phosphors are prepared by high temperature solid state reaction. The X-ray diffraction patterns and photoluminescence spectra of the phosphors are investigated in detail. The emission spectrum of SZ2P:Sn2+ is a wide band peaking at 461 nm due to 3P1 →1S0 transition of Sn2+, and overlaps effectively with the excitation spectrum of SZ2P:Mn2+, which shows that the absorption of SrZn2(PO4)2 host, and a series of peaks at 352, 373, 419, 431, and 466 nm, corresponding to 6A1(6S)→4E(4D), 6A1(6S)→4T2(4D), 6A1(6S)→[4A1(4G), 4E(4G)], 6A1(6S)→4T2(4G) and 6A1(6S) →4T1(4G) transition, respectively, are assigned to a wide band ranging from 200 nm to 300 nm. Therefore, luminescence intensity of Mn2+ is enhanced significantly by co-doping Sn2+ in SrZn2(PO4)2 host. According to the Dexter's energy transfer formula of multipolar interaction and Reisfeld's approximation, it is demonstrated that the energy transfer between Sn2+ and Mn2+ is due to the quadripole-quadripole interaction of the resonance transfer. The critical distance (Rc) of energy transfer is calculated to be about 1.78 nm. The tunable color is achieved by changing the doping concentrations of Sn2+ and Mn2+. The SZ2P:Sn2+, Mn2+ phosphor could emit strong blue-white light under the excitation of 254 nm ultraviolet (UV) light. The result shows that the SZ2P:Sn2+, Mn2+ is a promising phosphor for compact fluorescent lamp, and with the development of short wave UV semiconductor chip, this phosphor has potential applications in white light emitting diodes in the near future.
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Keywords:
- phosphate /
- Sn2+ /
- Mn2+ /
- energy transfer
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[1] Shinde K N, Singh R, Dhoble S J 2014 J. Lumin. 146 91
[2] Kong L, Gan S C, Hong G Y, Zhang J L 2007 J. Rare Earth. 25 692
[3] Wu L Q, Zhang J B, Zhang J F, Qiu G X 1998 Chin. J. Lumin. 19 251 (in Chinese) [吴乐琦, 张建兵, 张锦芳, 裘国兴 1998 发光学报 19 251]
[4] Yang Z P, Zhao F L, Li X N, Zhao J X, Lu Y J 2008 Chin. J. Lumin. 29 941
[5] Wang Z L, Liang H B, Gong M L, Su Q 2007 J. Alloys Compd. 432 308
[6] Li P L, Wang Z J, Yang Z P, Guo Q L 2010 J. Rare Earth. 28 523
[7] Guo Q F, Liao L B, Mei L F, Liu H K 2015 J. Solid State Chem. 232 102
[8] Liu B, Wang T, Liu S J, Yang S S, Liu Q L 2015 Mater. Res. Bull. 64 279
[9] Ropp R C, Mooney R W 1960 J. Electrochem. Soc. 107 15
[10] Zhang X M, Jiang W, Pan Q, Yuan G M, Seo H J 2014 Mater. Lett. 128 89
[11] Muõz F A, Rubio O J 1988 Phys. Rev. B 38 9980
[12] Masai H, Hino Y, Yanagida T, Fujimoto Y, Tokuda Y 2015 Opt. Mater. Express 5 617
[13] Jimenez J A 2014 J. Electron. Mater. 43 3588
[14] Jimenez J A 2014 J. Non-Cryst. Solids 387 124
[15] Masai H, Yamada Y, Suzuki Y, Teramura K, Kanemitsu Y, Yoko T 2013 Sci. Rep. 3 3541
[16] Xiong X B, Yuan X M, Liu J C, Song J Q 2015 Acta Phys. Sin. 64 017801 (in Chinese) [熊晓波, 袁曦明, 刘金存, 宋江齐 2015 物理学报 64 017801]
[17] Yi L H, Zhou L Y, Gong F Z, Lan Y H, Tong Z F, Sun J H 2010 Mater. Sci. Eng. B 172 132
[18] Yang W J, Chen T M 2006 Appl. Phys. Lett. 88 101903
[19] Sarver J F, Hoffman M V, Hummel F A 1961 J. Electrochem. Soc. 108 1103
[20] Mendez A, Ramos F, Guerrero R, Camarillo E, Garcia U C 1998 J. Lumin. 79 269
[21] Aceves R, Caldino U G, Rubio J, Camarillo E 1995 J. Lumin. 65 113
[22] Kondo M, Adachi S 2013 ECS J. Solid State Sc. 2 9
[23] Yang Z P, Yang G W, Wang S L, Tian J, Li P L, Li X 2008 Acta Phys. Sin. 57 581 (in Chinese) [杨志平, 杨广伟, 王少丽, 田晶, 李盼来, 李旭 2008 物理学报 57 581]
[24] Xu S H, Zhu W Q 2011 Luminescence of Solid (Beijing: Tsinghua University Press) p85 (in Chinese) [许少鸿, 朱文清 2011 固体发光(北京:清华大学出版社) 第85页]
[25] van Uitert L G 1971 J. Lumin. 4 1
[26] Cui Y P, Hu Z F, Ye D H, Zhang W, Sheng X, Luo L, Wang Y H 2014 Chin. J. Quantum Electron. 31 641 (in Chinese) [崔跃鹏, 胡正发, 叶定华, 张伟, 盛霞, 罗莉, 王银海 2014 量子电子学报 31 641]
[27] Paulose P I, Jose G, Thomas V, Unnikrishnan N V, Warrier M K R 2003 J. Phys. Chem. Solids 64 841
[28] Jiao H, Liao F H, Tian S J, Jing X P 2003 J. Electrochem. Soc. 150 H220
[29] Zhai Y Q, Li R F, Li X, Li J H, Zheng Q 2014 J. Chin. Ceram. Soc. 42 314 (in Chinese) [翟永清, 李瑞方, 李璇, 李金航, 郑强 2014 硅酸盐学报 42 314]
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