Al-Ni-RE非晶合金的晶化行为和热稳定性

张章; 熊贤仲; 乙姣姣; 李金富

doi:10.7498/aps.62.136401

摘要

本文制备了一系列Al-Ni-RE (RE=La, Ce, Y) 非晶合金薄带, 利用差示量热扫描仪和X射线衍射仪考察了非晶合金的晶化行为和初生相, 并分析了其与合金成分和原子特性间的关系. 结果表明: 在拓扑不稳定参数λ以有效原子半径修正为λ'后, 每一Al-Ni-RE非晶合金体系可由其两个临界值划分为纳米晶、纳米玻璃和玻璃三类; Al-Ni-RE非晶合金的晶化开始温度和混合焓与λ'成良好的线性关系, 即λ'能很好的表征Al基非晶合金的热稳定性.

关键词:

Abstract

A series of Al-Ni-RE (RE=La, Ce, Y) amorphous ribbons were prepared. The crystallization behavior and primary phases were investigated using X-ray diffraction and differential scanning calorimeter, and their relationships with the alloy composition and atomic features were analyzed. Results show that if the topological instability parameter λ was modified using effective atomic radii, the metallic glasses in an Al-Ni-RE system can be classified into nanocrystalline, nanoglassy and glassy types according to their crystallization behaviors by two critical values of the modified topological instability parameter λ'. Linear relationships of onset temperature of crystallization and mixing enthalpy with λ' are also clearly revealed, indicating that λ' is closely related to the thermal stability of Al-Ni-RE metallic glasses.

Keywords:

作者及机构信息

1.
上海交通大学材料学院, 金属基复合材料国家重点实验室, 上海 200240

基金项目: 上海市教育委员会科研创新项目(批准号: 13ZZ016);国家重点基础研究发展计划(批准号: 2011CB610405)和国家自然科学基金(批准号: 50831003)资助的课题.

Authors and contacts

1.
School of Materials Science and Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

Funds: Project supported by the Innovation Program of Shanghai Municipal Education Commission, China (Grant No. 13ZZ016), the National Basic Research Program of China (Grant No. 2011CB610405), and the National Natural Science Foundation of China (Grant No. 50831003).

参考文献

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[5]	Zhuo L C, Pang S J, Wang H, Zhang H 2009 Chin. Phys. Lett. 26 066402
[6]	Zhong Z C, Jiang X Y, Greer A L 1997 Mater. Sci. Eng. A 226-228 531
[7]	Sa Lisboa R D, Bolfarini C, Botta W J 2005 Appl. Phys. Lett. 86 211904
[8]	Zhang Z, Zhou W, Xiong X Z, Li J F 2012 Intermetallics 24 1
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[10]	Egami T, Waseda Y 1984 J Non-Cryst Solids 64 113
[11]	Ueno S, Waseda Y 1987 J. Mater. Eng. 9 199
[12]	Waseda Y, Chen H S, Jacob K T, Shibata H 2008 Sci. Technol. Adv. Mater. 9 023003
[13]	Inoue A 1998 Prog. Mater. Sci. 43 365
[14]	Liu S C, Davenport J D, Plummer E W 1990 Phys. Rev. B 42 1582
[15]	Hsieh H Y, Toby B H, Egami T 1990 J. Mater. Res. 5 2807
[16]	Huang Z H 2008 Ph. D. Dissertation (Shanghai: Shanghai Jiaotong University) (in Chinese) [黄振华 2008 博士学位论文 (上海: 上海交通大学) ]
[17]	Sanders W S, Warner J S, Miracle D B 2006 Intermetallics 14 348
[18]	Ma C S, Zhang J, Chang X C 2008 Philo. Mag. Lett. 88 917
[19]	Saini S, Zaluska A, Altounian Z 1999 J. Non-Cryst. Solids 250-252 714
[20]	Yang H, Wang J Q, Li Y 2007 Philo. Mag. 87 4211
[21]	Matsubara E, Waseda Y, Inoue A 1989 Z Naturforsch 44a 814
[22]	Yu C Y, Hui X D, Chen X H 2010 Sci. China. Tech. Sci. 53 3175
[23]	Karel S, Pál J, Hermann F 2006 J. Phys.: Condens. Matter. 18 7579
[24]	Pyykkö P, Atsumi M 2009 Chem. Eur. J. 15 122770
[25]	Egry I,.Hennet L, Kehr M 2008 J. Chem. Phys. 129 064508
[26]	Bacewicz R, Antonowicz J 2006 Scripta Mater. 54 1187
[27]	Zalewski W, Antonowicz J, Bacewicz R 2009 J. Alloys Compd. 468 40
[28]	Ahn K, Louca D, Poon S J 2004 Phys. Rev. B 70 224103
[29]	Li X L, Bian X F, Hu L N 2010 Phys. Lett. A 374 3784
[30]	Boer F R, Perrifor 1988 Cohension in metals (Netherlands, Elsevier Science Publishers)
[31]	Takeuchi A, Inoue A 2001 Mater. Sci. Eng. A 304-306 446
[32]	Buschow K H J, Beekman N M 1980 Solid State Commun. 35 233
[33]	Xia M X, Zhang S G, Li J G 2006 Appl. Phys. Lett. 88 261913
[34]	Li X L, Bian X F, Hu L N 2007 J. Appl. Phys. 101 103540

施引文献

[1]	Greer A L 1995 Science 267 1947
[2]	Kim Y H, Inoue A, Masumoto T 1990 Mater. Trans. JIM 31 747
[3]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 331
[4]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 599
[5]	Zhuo L C, Pang S J, Wang H, Zhang H 2009 Chin. Phys. Lett. 26 066402
[6]	Zhong Z C, Jiang X Y, Greer A L 1997 Mater. Sci. Eng. A 226-228 531
[7]	Sa Lisboa R D, Bolfarini C, Botta W J 2005 Appl. Phys. Lett. 86 211904
[8]	Zhang Z, Zhou W, Xiong X Z, Li J F 2012 Intermetallics 24 1
[9]	Huang Z H, Li J F, Rao Q L, Zhou Y H 2007 Intermetallics 15 1139
[10]	Egami T, Waseda Y 1984 J Non-Cryst Solids 64 113
[11]	Ueno S, Waseda Y 1987 J. Mater. Eng. 9 199
[12]	Waseda Y, Chen H S, Jacob K T, Shibata H 2008 Sci. Technol. Adv. Mater. 9 023003
[13]	Inoue A 1998 Prog. Mater. Sci. 43 365
[14]	Liu S C, Davenport J D, Plummer E W 1990 Phys. Rev. B 42 1582
[15]	Hsieh H Y, Toby B H, Egami T 1990 J. Mater. Res. 5 2807
[16]	Huang Z H 2008 Ph. D. Dissertation (Shanghai: Shanghai Jiaotong University) (in Chinese) [黄振华 2008 博士学位论文 (上海: 上海交通大学) ]
[17]	Sanders W S, Warner J S, Miracle D B 2006 Intermetallics 14 348
[18]	Ma C S, Zhang J, Chang X C 2008 Philo. Mag. Lett. 88 917
[19]	Saini S, Zaluska A, Altounian Z 1999 J. Non-Cryst. Solids 250-252 714
[20]	Yang H, Wang J Q, Li Y 2007 Philo. Mag. 87 4211
[21]	Matsubara E, Waseda Y, Inoue A 1989 Z Naturforsch 44a 814
[22]	Yu C Y, Hui X D, Chen X H 2010 Sci. China. Tech. Sci. 53 3175
[23]	Karel S, Pál J, Hermann F 2006 J. Phys.: Condens. Matter. 18 7579
[24]	Pyykkö P, Atsumi M 2009 Chem. Eur. J. 15 122770
[25]	Egry I,.Hennet L, Kehr M 2008 J. Chem. Phys. 129 064508
[26]	Bacewicz R, Antonowicz J 2006 Scripta Mater. 54 1187
[27]	Zalewski W, Antonowicz J, Bacewicz R 2009 J. Alloys Compd. 468 40
[28]	Ahn K, Louca D, Poon S J 2004 Phys. Rev. B 70 224103
[29]	Li X L, Bian X F, Hu L N 2010 Phys. Lett. A 374 3784
[30]	Boer F R, Perrifor 1988 Cohension in metals (Netherlands, Elsevier Science Publishers)
[31]	Takeuchi A, Inoue A 2001 Mater. Sci. Eng. A 304-306 446
[32]	Buschow K H J, Beekman N M 1980 Solid State Commun. 35 233
[33]	Xia M X, Zhang S G, Li J G 2006 Appl. Phys. Lett. 88 261913
[34]	Li X L, Bian X F, Hu L N 2007 J. Appl. Phys. 101 103540

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