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Cu掺杂ZnO磁性能的实验与理论研究

王锋 林闻 王丽兹 葛永明 张小婷 林海容 黄伟伟 黄俊钦 W. Cao

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Citation:

Cu掺杂ZnO磁性能的实验与理论研究

王锋, 林闻, 王丽兹, 葛永明, 张小婷, 林海容, 黄伟伟, 黄俊钦, W. Cao

Magnetic properties of the Cu-doped ZnO:experiments and theory

Wang Feng, Lin Wen, Wang Li-Zi, Ge Yong-Ming, Zhang Xiao-Ting, Lin Hai-Rong, Huang Wei-Wei, Huang Jun-Qin, W. Cao
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  • 采用固相反应法制备了Cu掺杂ZnO样品. 在室温下Cu含量3%的样品在室温下表现为铁磁性. 样品为n型半导体,载流子的浓度为1015cm-3. 利用密度泛函理论(DFT+U)计算了CuZnO体系的Cu2+O2-Cu2+,Cu2+VoCu2+,Cu2+Vo+Cu2+,Cu2+Vo+ +Cu2+磁交换耦合作用,给出了不同束缚电荷的氧空穴Vo与Cu2+离子之间的超交换机理,提出了CuZnO 体系中铁磁性机理为Cu2+Vo++Cu2+束缚磁极化子模型.
    Cux Zn1-xO were synthesized via the solid-state reaction route. Ferromagnetism was detected when the Cu percentage was bigger than 3%. The compounds were found to be the N-type semiconductors with a carrier concentration of 1015 cm-3. The DFT+U method was employed to calculate the magnetic exchange coupling of the Cu2+O2-Cu2+, Cu2+VoCu2+, Cu2+Vo+Cu2+, Cu2+Vo++Cu2+ in the CuZnO system, where Vo denoted the vacancy of oxygen. Different bound charge transfer schemes between the Vo and Cu2+ ions were revealed. The origin of the ferromagnetism was determined within the framework of the Cu2+Vo++Cu2+ bound magnetic polarons.
    • 基金项目: 福建省教育厅A类科技项目(批准号:JA12283)、泉州市科技项目(批准号:2012G11)、泉州市优秀人才培养专项经费(批准号:12A17)、Oulu University Strategic Funding,The grant from Research Council for Natural Sciences and Engineering of the Academy of Finland 资助的课题.
    • Funds: Project supported by the Science and Technology Project of Department of Education, Fujian Province, China (Grant No. JA12283), the Science and Technology Program of Quanzhou, China (Grant No. 2012G11), the Quanzhou Excellent Talents Training Grant, China (Grant No.12A17), the Oulu University Strategic Funding, and the Research Council for Natural Sciences and Engineering of the Academy of Finland.
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    Ran C J, Yang H L, Wang Y K, Hassan F M, Zhou L G, Xu X G, Jiang Y 2013 Chin. Phys. B 22 067503

    [2]
    [3]
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    Ye Y H, Lü, Zhang W G, Huang H W, Ye Zh Zh 2012 Acta. Phys. Sin. 61 036701 (in Chinese) [叶颖惠, 吕斌, 张维广, 黄宏文, 叶志镇 2012 物理学报 61 036701]

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    Wang F, Pan R X, Lin H R 2012 Acta. Phys. Sin. 61 247501 (in Chinese) [王锋, 潘荣萱, 林海容 2012 物理学报 61 247501]

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    Li T J, Li G P, Gao X X, Chen J Sh 2010 Chin. Phys. Lett. 27 087501

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    Xu Q Y, Zheng X H, Gong Y P 2010 Chin. Phys. B 19 077501

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    [16]
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    [20]

    Herng T S, Lau S P, Yu S F, Yang H Y, Ji X H, Chen J S, Yasui N, Inaba H 2006 J. Appl. Phys. 99 086101

    [21]
    [22]

    Chakraborti D, Narayan J, Prater J T 2007 Appl. Phys. Lett. 90 062504

    [23]
    [24]

    Hou D L, Ye X J, Meng H J, Zhou H J, Li X L, Zhen C M, Tang G D 2007 Appl. Phys. Lett. 90 142502

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    Xiao Zh L, Shi L B 2011 Journal of Crystal Growth 40 279 (in Chinese) [肖振林, 史力斌 2011 人工晶体学报 40 279]

    [27]

    Ye L H, Freeman J, Delley B 2006 Phys. Rev. B 73 033203

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    [29]

    Huang L M, Rosa A L, Ahuja R 2006 Phys. Rev. B 74 075206

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    Coey J M D, Venkatesan M, Fitezgerald C B 2005 Nat. Mater. 4 173

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    Wang X F, Xu J B, Cheung W Y, An J, Ke N 2007 Appl. Phys. Lett. 90 212502

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    Pan F, Ding B F, Fa T, Cheng F F, Zhou Sh Q, Yao Sh D 2011 Acta Phys. Sin. 60 108501 (in Chinese) [潘峰, 丁斌峰, 法涛, 成枫锋, 周生强, 姚淑德 2011 物理学报 60 108501]

    [45]

    Dietal T, Ohno H, Matsukura F, Cibert J, Ferrand D 2000 Science 287 1019

    [46]
    [47]
    [48]

    Wang F, Huang W W, Li Sh Y, Lian A Q, Zhang X T, Cao W 2013 J. Magn. and Magn. Mater. 340 5

    [49]
    [50]

    Gopal P, Spaldin N A 2006 Phys Rev B 74 094418

    [51]

    Cohan A F, Ceder G, Morgen D, Van de Walle Chris G 2000 Phys. Rev. B 61 15019

    [52]
    [53]
    [54]

    Schramm L, Behr G, Löser W, Wetzig K 2005 J. Phase Equilib. Diffus 26 605

    [55]

    Sheetz R M, Ponomareva I, Richter E, Andriotisa N, Menon M 2009 Phys. Rev. B 80 195314

    [56]
    [57]
    [58]

    Wang F, Wang Y Y, Huang W W, Zhang X T, Li S Y 2012 Acta. Phys. Sin. 61 157503

    [59]

    Chanier T, Sargolzaei M, Opahle I, Hayn R, Koepernik K 2006 Phys. Rev. B 73 134418

    [60]
    [61]
    [62]

    Anderson P W 1950 Phys. Rev. 79 350

    [63]

    Anderson P W 1950 Phys. Rev. 79 705

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    Tang Y H, Zhang H, Cui L X, Ouyang Ch Y, Shi S Q, Tang W H, Li H, Lee J S, Chen L Q 2010 Phys. Rev. B 82 125104

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出版历程
  • 收稿日期:  2014-03-16
  • 修回日期:  2014-04-16
  • 刊出日期:  2014-08-05

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