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本文采用红外吸收光谱法、X射线散射法和EXAFS方法研究了LiO-Nb2O-SiO2系统非晶态离子导体的结构,认为Nb5+在非晶结构网络中主要是以[NbO6]形式存在。非晶结构随Nb2O5含量的多少而变化。低Nb2O5含量时,[NbO6]相互间以边相连,并与[SiO4]组成多元环后,形成非晶网络结构。高Nb2O5含量时,非晶网络结构主要是以角顶相连的[NbO6]所组成。根据电导测试结果,讨论了结构与电学性能的关系,认为Li2O含量在0.45左右,Nb2O5,含量在0.3左右组成的非晶材料有最高的电导率。IR, WAXS and EXAFS arn used to study the structure of the non-crystalline io nic conductors in the Li2O-Nb2O5-SiO2 system. From the analysis, it is known that Nb5+ ions exist mainly as (NbO6) in the non-crystalline network. The non-crystalline structure varies with Nb2O5 content, it consists of polycyclics formed by shared side (NbO6) and (SiO4) when Nb2O5 content is. low, and shared of apex (NbO6) when Nb2O5 content is higher. The results of conductivity measurement are used to study the relations of the structure and electrial properties. The non-crystalline material with about Li2O 0.45 and Nb2O5 0.3 has the highest conductivity.
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