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掺铒矾酸钇晶体上转换荧光研究

王金国 张治国 徐积仁 傅盘铭 闫秀丽 吴 星 姜彦岛

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掺铒矾酸钇晶体上转换荧光研究

王金国, 张治国, 徐积仁, 傅盘铭, 闫秀丽, 吴 星, 姜彦岛

STUDY ON UPCONVERSION FLUORESCENCE OF Er3+-DOPED YTTRIUM VANADATE

WANG JIN-GUO, ZHANG ZHI-GUO, XU JI-REN, FU PAN-MING, YAN XIU-LI, WU XING, JIANG YAN-DAO
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  • 使用波长为808和658nm的半导体激光器和染料激光器作为激发源,测量了Er3+:YVO4晶体的波长在553和410nm附近的上转换荧光.对激发过程的分析表明,贡献于上转换荧光的主要激发机制为激发态吸收.在不同浓度下对上转换荧光的寿命测量结果显示,随Er3+浓度的提高,553nm绿光的荧光寿命随浓度的增加而减小,但410nm的荧光寿命随Er3+浓度无明显变化.结合绿光强度随掺杂浓度增加而减小的结果,认为在所测浓度范围内
    Upconversion fluorescence near 553 and 410nm was detected when the Er3+-doped yttrium vanadate (Er3+∶YVO4) crystal was excited with a 808nm-diode laser and a 658nm-dye laser. Analysis of excitation mechanism shows that excited state absorption dominantly contributes to the upconversion emissions. Measurement of lifetimes for different Er3+ concentration indicates that the lifetime of 553nm emission decreases with increasing Er3+ concentration, but no considerable changes of that of 410nm emission have been observed. With the consideration of the fact that the intensity of 553nm band declines with increasing Er3+ concentration, we argue that in the concentration range measured there is an appreciable concentration quenching in the 553nm emission, and a dominant population channel of its upper state (4S3/2) is the nonradiative relaxation from the upper state (2H9/2) of the 410nm band.
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出版历程
  • 收稿日期:  1997-09-10
  • 刊出日期:  1998-05-20

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